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Forming process for low-temperature NOx rapid alternate adsorption-regeneration catalyst

A technology for regenerating catalyst and molding process, which is applied in catalyst regeneration/reactivation, physical/chemical process catalyst, organic compound/hydride/coordination complex catalyst, etc., which can solve the problem that the denitration process cannot be carried out continuously and NO adsorption capacity is weak. , low NOx adsorption efficiency, etc., to achieve good NOx adsorption performance, promote nitrogen oxides, and improve adsorption efficiency.

Pending Publication Date: 2020-12-25
QILU UNIV OF TECH +1
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  • Claims
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AI Technical Summary

Problems solved by technology

[0003] As a technology with great development potential, NOx adsorption method has been widely used in the treatment of tail gas produced by nitric acid. However, the proportion of NO in flue gas in coal-fired power stations and metallurgical industries is very high, often above 90%, while NO 2 The proportion is very low. Due to the weak adsorption capacity of common adsorbents / catalysts for NO, they are far from meeting the requirements of flue gas NOx emission standards. The regeneration of adsorbents after adsorbing NOx is difficult, and the adsorption and regeneration of adsorbents / catalysts requires Two sets of equipment, resulting in the denitrification process can not be carried out continuously
[0004] Traditional granular bed catalysts have high NOx adsorption efficiency, but they are severely worn during use, resulting in short catalyst life, while honeycomb catalysts, plate catalysts, etc. have long life and mature preparation processes, but the NOx adsorption efficiency very low

Method used

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  • Forming process for low-temperature NOx rapid alternate adsorption-regeneration catalyst
  • Forming process for low-temperature NOx rapid alternate adsorption-regeneration catalyst

Examples

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Embodiment

[0038] (1) Dissolve 2g of copper nitrate, 10g of cerium nitrate, 10g of manganese nitrate, 10ml of citric acid, and 0.5g of alumina in water, stir well, add an appropriate amount of hydrogen peroxide to make the pH of the solution 4.5, and then dry at 110°C for 12 hours. The solid obtained after drying was extruded at 2.5MPa, crushed, sieved to obtain catalyst particles of 20-40 mesh, and finally calcined at 200°C and 550°C for 3 hours respectively;

[0039] (2) Extrude the glass fiber paper into a wave shape at 500°C, wherein the distance between the two peaks of the wave-shaped corrugated paper is 0.25cm, and the peak height is 0.15cm, and coat the glass fiber paper with a concentration of 30% Aluminum sol, and quickly dried at 300°C;

[0040] (3) Disperse the catalyst obtained in step (1) into 50% aluminum sol, the molar ratio of composite metal oxide catalyst to aluminum sol is 3.5:8.5, and brush it on the surface of glass fiber paper in step (2);

[0041](4) The corrugat...

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Abstract

The invention relates to a catalyst forming technology for removing nitric oxide in flue gas, and particularly discloses a forming process for a low-temperature NOx rapid alternate adsorption-regeneration catalyst. The forming process comprises the following steps: dissolving soluble copper salt or / and cobalt salt, soluble cerium salt, other metal salt, citric acid or / and propylene glycol and a pore-forming agent in water, fully stirring, drying, carrying out extrusion forming, crushing to obtain raw catalyst particles, and roasting to prepare a composite metal oxide catalyst; extruding the fiber paper into a wave shape, coating the fiber paper with alumina sol or silica gel, and drying; dispersing the catalyst into the aluminum sol, and brushing the catalyst onto the surface of the fiberpaper; and stacking the fiber paper at intervals to form multiple layers of corrugations, and drying to obtain the product. According to the forming process, the good permeability of the porous catalyst is utilized to prevent flue gas from blocking catalyst pore channels when the flue gas flows through the catalyst, the catalyst can be effectively promoted to adsorb NOx in the flue gas, and the NOx adsorption efficiency of the catalyst is improved.

Description

technical field [0001] The invention relates to a catalyst molding technology for removing nitrogen oxides in flue gas, in particular to a molding technology for low-temperature NOx rapid alternate adsorption-regeneration catalyst. Background technique [0002] With the development of my country's economy and the improvement of people's quality of life, the pressure brought by environmental pollution is increasing. As one of the main pollutants of current air pollution, nitrogen oxides are closely related to the quality of my country's atmospheric environment. Coal-fired power plants are the main pollution source of concentrated emissions of nitrogen oxides. The reduction of nitrogen oxides in the flue gas emitted by them has become an important goal of governance today. Flue gas denitrification has also become an essential environmental protection facility for coal-fired power plants. This facility usually uses NH 3 -SCR (ammonia selective catalytic reduction) denitrificat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J38/02B01J31/06B01D53/86B01D53/56
CPCB01J38/02B01J31/06B01D53/8628
Inventor 张兴宇王鲁元程星星王志强
Owner QILU UNIV OF TECH
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