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Processing technology of polyurethane foam for fireproof insulation board

一种聚氨酯泡沫、防火保温板的技术,应用在聚氨酯泡沫领域,能够解决泡沫体发脆、泡沫绝热性能不好、力学性能不佳等问题

Inactive Publication Date: 2020-09-25
朱晶晶
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are the following defects in practical application: the gas-phase thermal conductivity of CO2 is as high as 16.3mW / m·k, and the thermal insulation performance of the prepared foam is not good; the CO2 gas in the foam diffuses outwards too fast, and the dimensional stability of the foam decreases; The fluidity of the water foaming system is not good, the consumption of isocyanate increases the production cost, the prepared foam is brittle, and the mechanical properties are not good, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0058] A polyurethane foam for fire-proof insulation board based on biomass raw materials, including the following raw materials in parts by weight: 50 parts of biomass liquefaction products, 70 parts of isocyanate, 30 parts of water, 3 parts of triethylenediamine, 0.5 parts of silicone oil, 0.08 parts Catalyst, 10 parts of modified mixed biomass scraps, 20 parts of enzymatic chitosan liquid, 0.2 parts of castor oil, 8 parts of isoamyl acetate, and 20 parts of modified graphene oxide.

[0059] The isocyanate is toluene diisocyanate.

[0060] The catalyst is stannous octoate.

[0061] A specific processing process of polyurethane foam for fireproof insulation board based on biomass raw materials is as follows:

[0062] (1) In terms of parts by weight, take 20 parts of rice straw, 20 parts of rapeseed stalk, and 20 parts of corn stalk in turn, place the rice straw, rapeseed stalk, and corn stalk in an oven at a temperature of 110°C, Mix and dry for 60 minutes to obtain dry mat...

example 2

[0072] A polyurethane foam for fire-proof insulation board based on biomass raw materials, including the following raw materials in parts by weight: 50 parts of biomass liquefaction products, 70 parts of isocyanate, 30 parts of water, 3 parts of triethylenediamine, 0.5 parts of silicone oil, 0.08 parts Catalyst, 20 parts of enzymatic chitosan liquid, 0.2 parts of castor oil, 8 parts of isoamyl acetate, 20 parts of modified graphene oxide.

[0073] The isocyanate is toluene diisocyanate.

[0074] The catalyst is stannous octoate.

[0075] A specific processing process of polyurethane foam for fireproof insulation board based on biomass raw materials is as follows:

[0076] (1) In parts by weight, take 30 parts of wood flour, 2 parts of glucose solution, 60 parts of water, 0.2 parts of biogas slurry, 8 parts of ferric nitrate solution, wood powder, 0.3% glucose solution, water , the biogas slurry was placed in the No. 2 fermentation tank, and the temperature was 35°C, and the ...

example 3

[0084] A polyurethane foam for fire-proof insulation board based on biomass raw materials, including the following raw materials in parts by weight: 50 parts of biomass liquefaction products, 70 parts of isocyanate, 30 parts of water, 3 parts of triethylenediamine, 0.5 parts of silicone oil, 0.08 parts Catalyst, 10 parts of modified mixed biomass scraps, 20 parts of enzymatic chitosan liquid, 0.2 parts of castor oil, and 8 parts of isoamyl acetate.

[0085] The isocyanate is toluene diisocyanate.

[0086] The catalyst is stannous octoate.

[0087] A specific processing process of polyurethane foam for fireproof insulation board based on biomass raw materials is as follows:

[0088] (1) In terms of parts by weight, take 20 parts of rice straw, 20 parts of rapeseed stalk, and 20 parts of corn stalk in turn, place the rice straw, rapeseed stalk, and corn stalk in an oven at a temperature of 110°C, Mix and dry for 60 minutes to obtain dry material, then place the dried material in...

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PUM

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Abstract

The invention discloses a processing technology of polyurethane foam for a fireproof insulation board, and belongs to the technical field of chemical engineering. The processing technology comprises following steps: stirring and mixing a biomass liquefied product, water, triethylene diamine, silicone oil and catalyst, then adding the modified mixed biomass crushed materials and enzymatic chitosanliquid; performing a stirring reaction, then adding castor oil, isoamyl acetate and modified graphene oxide are added, and performing a heating reaction; sequentially carrying out injection molding, foaming, curing and demolding to prepare the polyurethane foam based on the biomass raw material. In the preparation process, calcium oxide deposited in the modified mixed biomass crushed aggregates reacts with water, so that calcium ions are fused into the system, and the calcium ions can promote cross-linking of the enzymed chitosan to form a three-dimensional network, so that deposited aluminumoxide and iron oxide of the system are fixed, and the mechanical property of the system is improved. The polyurethane foam based on the biomass raw material provided by the invention has excellent mechanical properties and thermal insulation properties.

Description

technical field [0001] The invention belongs to the technical field of polyurethane foam, and in particular relates to a processing technology of polyurethane foam used for a fireproof insulation board. Background technique [0002] Due to its good physical and chemical properties, polyurethane materials are widely used in the fields of automobiles, furniture, construction and packaging. Polyurethane has developed very rapidly since its industrialization, and the current annual output has exceeded 10 million tons. However, traditional polyurethane materials are difficult to degrade. A large amount of polyurethane will form "white pollution" after being discarded, which will put a huge pressure on the environment. Moreover, the main raw material for making polyurethane, polyether or polyester polyol, mainly comes from petrochemical raw materials. The shortage of petroleum resources and the high price of petroleum have seriously restricted the development of polyurethane mate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/65C08G18/64C08G18/36C08K9/04C08K3/04C08G101/00
CPCC08G18/36C08G18/6484C08G18/6492C08G18/6547C08J2375/04C08K9/04C08K3/042
Inventor 朱晶晶
Owner 朱晶晶
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