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PVP-based amphiphilic anti-icing coating and preparation method thereof

A technology of amphiphilic and amphiphilic polymers, which is applied in the field of organic materials, can solve the problems of poor durability, passive anti-icing methods cannot achieve anti-icing performance, and anti-icing materials do not have sufficient durability. Easy to operate, enhance the effect of anti-icing and reduce the effect of ice shear strength

Active Publication Date: 2021-09-17
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the lubricating layer in SLIPS is easily carried away by water droplets or replaced by ice, resulting in significantly reduced anti-icing performance and poor durability after several icing / deicing cycles
Moreover, the preparation process of the above anti-icing coating is complicated and the cost is high, which restricts its large-scale application
[0004] Therefore, the field of coating anti-icing still faces many challenges, such as: (1) During the process of ice formation on a solid surface, the physical process of ice nucleation and the thermodynamics of phase transition are very complex and need further study; (2) The passive Anti-icing methods cannot achieve optimal anti-icing performance; (3) the relationship between surface wettability transitions and external environmental conditions needs further study; (4) anti-deicing materials do not have sufficient durability for practical applications

Method used

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  • PVP-based amphiphilic anti-icing coating and preparation method thereof
  • PVP-based amphiphilic anti-icing coating and preparation method thereof
  • PVP-based amphiphilic anti-icing coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Embodiment 1: Take 3.7g CTA-PDMS-CTA (0.625mmol), 11.11g NVP (100mmol), 16.4mg 2,2-azobisisobutyronitrile AIBN (1.0mmol) is dissolved in 8mL 1,4-diox Add it to a dry round-bottomed flask, and deoxygenate the solution by bubbling nitrogen gas at room temperature for 30 minutes, then immerse the flask in an oil bath preheated to 75°C, react under stirring for 24 hours, and then use ice-water mixture Quenched. The reacted solution was concentrated and precipitated at least three times in ten volumes of cold ether, the solid was collected after filtration, and then vacuum-dried at 40°C overnight to obtain the amphiphilic polymer PVP-PDMS-PVP.

[0038] Dissolve 5.0g PDMS (molecular weight: 26000), 0.25g PVP-PDMS-PVP in a mixed solution of 3mL dichloromethane and 5mL tetrahydrofuran, mix well, add 0.1g cross-linking agent METES and 50mg catalyst DBTDL, and spread the solution evenly Overlay clean 20×20mm 2 On the surface of the steel sheet, the amphiphilic polymer anti-icin...

Embodiment 2

[0040] Embodiment 2: get 7.4g CTA-PDMS-CTA (1.25mmol), 22.22g NVP (200mmol), 32.8mg AIBN (2.0mmol) are dissolved in 16mL 1,4-dioxane, add it to dry circular In the bottom flask, the solution was deoxygenated by bubbling argon gas at room temperature for 30 min, then the flask was immersed in an oil bath preheated to 75 °C, and reacted for 24 h under stirring, and then quenched with ice-water mixture. The reacted solution was concentrated and precipitated at least three times in ten volumes of cold ether, the solid was collected after filtration, and then vacuum-dried at 40°C overnight to obtain the amphiphilic polymer PVP-PDMS-PVP.

[0041] 8.0g PDMS (molecular weight is 26000), 0.4g PVP-PDMS-PVP and 0.4g carbon fiber are dissolved in the mixed solution of 6mL dichloromethane and 8mL tetrahydrofuran, after mixing, add 0.24g cross-linking agent METES and 120mg catalyst DBTDL, Spread the solution evenly on a clean 40×40mm 2 On the surface of the steel sheet, the amphiphilic pol...

Embodiment 3

[0043] Embodiment 3: get 5.62g CTA-PDMS-CTA (0.95mmol), 22.22g NVP (200mmol), 4.21g FA (5.7mmol), 8.2mg AIBN (0.5mmol) are dissolved in 12mL 1,4-dioxane , was added to a dry round-bottomed flask, deoxygenated by bubbling nitrogen gas at room temperature for 30 min, then the flask was immersed in an oil bath preheated to 75 °C, reacted for 24 h under stirring, and then quenched with ice-water mixture . The reacted solution was concentrated and precipitated at least three times in ten volumes of cold ether, the solid was collected after filtration, and then dried in vacuum at 40°C overnight to obtain the amphiphilic polymer FA-PVP-PDMS-PVP-FA.

[0044] Dissolve 5.0g of PDMS (molecular weight: 320000), 0.5g of FA-PVP-PDMS-PVP-FA in a mixed solution of 3mL of dichloromethane and 5mL of tetrahydrofuran, mix well and add 0.125g of crosslinking agent METES and 50mg of catalyst DBTDL, Spread the solution evenly on a clean 20×20mm 2 On the surface of the steel sheet, the amphiphilic ...

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Abstract

The invention belongs to the field of organic materials, in particular to a PVP-based amphiphilic anti-icing coating and a preparation method thereof. The amphiphilic anti-icing coating based on PVP includes the following components by mass: 100 parts of PDMS; 5-15 parts of amphiphilic polymer based on PVP; 0-15 parts of photothermal material; 2-5 parts of crosslinking agent 1-2 parts of catalyst; in the present invention, PDMS is a hydrophobic segment in the amphiphilic polymer, and PVP is a hydrophilic segment. After cross-linking with the PDMS matrix to form a coating, the surface will produce a microphase separation structure, and at the same time The fluorine-containing FA segment has the characteristics of low surface energy, which greatly reduces the ice shear strength; most preferably, the addition of photothermal materials can efficiently absorb sunlight and convert it into heat energy, so the introduction of photothermal materials into amphiphilic polymer coatings The layer can use its photothermal effect to rapidly heat up under the light, which further improves the anti-deicing effect of the coating.

Description

technical field [0001] The invention belongs to the field of organic materials, in particular to a PVP-based amphiphilic anti-icing coating and a preparation method thereof. Background technique [0002] Icing on equipment operating in the air will seriously affect the operation safety of the equipment, resulting in huge economic losses. For example, icing on transmission lines will pose a serious threat to the normal operation of electric power, railways, and network communication systems; icing on the surface of aircraft will increase flight resistance and fuel consumption, and can reduce performance by up to 50%, and even cause devastating damage. air crash. In order to prevent ice damage, many anti-icing or deicing methods have been developed. Traditional deicing methods include chemical methods, mechanical removal methods, surface electric heating methods, etc. The disadvantages of these methods are high economic cost and large energy consumption. , destroy the surfac...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/04C09D151/08C08F283/12C08F226/10C08F220/28
CPCC08F283/12C09D183/04C08F226/10C08L51/085
Inventor 张雷杨静陈鹏光郭洪爽
Owner TIANJIN UNIV
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