Super-absorbent fiber material for processing disposable medical glove liner and manufacturing method thereof
A technology of superabsorbent fibers and manufacturing methods, which is applied in the fields of cellulose/protein conjugated rayon, fiber treatment, rayon manufacturing, etc., and can solve the problems of affecting the wearing comfort of gloves, poor water vapor permeability, and water vapor formed by gloves , to achieve the effects of biodegradability, pollution reduction, and improvement of wearing comfort
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Embodiment 1
[0041] (1) Add 2.62g of tris(2-hydroxyethyl)isocyanurate and 4.83g of 3-aminoadipic acid to 50mL of ethanol, and dropwise add 0.35g of 98% concentrated sulfuric acid, heat to 65°C and stir for 3h After the reaction, the ethanol is recovered through distillation, and the distillation residue is the product; through infrared spectrum detection, it is found that there are isocyanurate, ester group, amino group and carboxyl group in the product, ESI-MS: m / z=691.27 [M+1 ] + ;
[0042] (2) Add 5 g of the product obtained in step (1) and 5 g of sodium carboxymethyl cellulose to 30 mL of water, heat to 70 ° C, stir for 30 min, and vacuumize for 3 h to obtain the core spinning stock solution;
[0043] (3) Add 5g of polyvinyl alcohol, 0.25g of diisopropyl xanthate disulfide and 5g of water-soluble porogen (sodium bicarbonate and ethanol at a mass ratio of 1:2) to 30mL of water, and heat to 70°C Stir for 30 minutes, vacuumize and defoam for 3 hours to obtain the cortex spinning stock s...
Embodiment 2
[0046] The difference between embodiment 2 and embodiment 1 is the preparation of step (1) product, and all the other are the same as embodiment 1.
[0047](1) Add 2.62g of tris(2-hydroxyethyl)isocyanurate and 2.94g of maleic anhydride to 50mL of ethanol, and dropwise add 0.35g of 98% concentrated sulfuric acid, heat to 65°C and stir for 3h, esterification After the reaction, add 0.50 g of azobisisoheptanonitrile dropwise, continue heating to 65°C and stir for 5 hours. After the polymerization reaction, ethanol is recovered by distillation, and the distillation residue is the product, and the degree of polymerization is 2000; the product is found by infrared spectrum detection There are isocyanurate, ester and carboxyl groups in
[0048] (2) Add 5 g of the product obtained in step (1) and 5 g of sodium carboxymethyl cellulose to 30 mL of water, heat to 70 ° C, stir for 30 min, and vacuumize for 3 h to obtain the core spinning stock solution;
[0049] (3) Add 5g of polyvinyl a...
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