Method for preparing lactate

A lactate, titanium-silicon molecular sieve technology, applied in the preparation of carboxylates, carbon-based compounds, chemical instruments and methods, etc., can solve the problem that lactic acid cannot be produced and applied on a large scale, atmospheric environmental pollution, large solid waste, etc. problem, to achieve the effect of suitable for large-scale industrial production application, high conversion rate of acetaldehyde, high lactate yield

Active Publication Date: 2020-06-09
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The process has a long reaction route, high production cost and produces a large amount of solid waste, which makes it impossible to realize large-scale production and application of lactic acid at present.
The commonly used chemical synthesis methods are the lactonitrile method and the propionic acid method. The lactonitrile method uses acetaldehyde and highly toxic hydrocyanic acid as the reaction raw materials, and concentrated sulfuric acid as the catalyst. Therefore, the production process is seriously polluted and has potential safety hazards.
The propionic acid method uses toxic chlorine gas as a raw material, which not only requires high operational safety and airtightness, but also easily pollutes the atmospheric environment

Method used

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  • Method for preparing lactate

Examples

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preparation Embodiment 1

[0043] This preparation example prepares Sn-MFI molecular sieve, and specific preparation method is:

[0044] tin tetrachloride pentahydrate (SnCl 4 .5H 2 O) Dissolve in water, add this aqueous solution to tetraethyl orthosilicate (TEOS) and stir, add tetrapropylammonium hydroxide (TPAOH, 20% aqueous solution) and water under stirring, and continue stirring for 30 minutes to obtain a chemical composition of 0.03SnO 2 : SiO 2 :0.45TPA: 35H 2 The clear liquid of O was then crystallized at 433K for 2 days, and then the obtained solid was filtered, washed with distilled water, dried at 393K for 5 hours, and then calcined at 823K for 10 hours to obtain a molecular sieve sample. Among them, the amount of TEOS is 15.31g, the amount of TPAOH is 33.67g, SnCl 4 .5H 2 The amount of O used is 0.38g, and the amount of water used is 39.64g.

preparation Embodiment 2

[0046] This preparation example references "Nemeth L, Moscoso J, Erdman N, et al.Synthesis and characterization of Sn-Beta as a selective oxidation catalyst [J]. Studies in Surface Science & Catalysis, 2004, 154 (04): 2626-2631" Method prepares Sn-Beta molecular sieve, the preparation method of the adopted Sn-Beta molecular sieve is:

[0047] tin tetrachloride pentahydrate (SnCl 4 .5H 2 O) Dissolve in water, add tetraethyl ammonium hydroxide (TEAOH) to this aqueous solution and stir with tetraethyl ammonium hydroxide (TEAOH), stir until TEOS evaporates to obtain alcohol, add hydrogen fluoride (HF) to the clarified liquid , forming a paste-like thin layer. Finally, a suspension of dealuminated nano Beta seeds (20nm) and water is added to obtain a chemical composition of 0.03SnO 2 : SiO 2 :6TEA:15H 2 O: 10HF clear liquid, then crystallized at 413K for 10 days, then filtered the obtained solid, washed with distilled water, dried at 393K for 5 hours, and then roasted at 823K ...

preparation Embodiment 3

[0049] References for this preparation example "Yang X, Wu L, Wang Z, et al. Conversion of dihydroxyacetone to methyl lactate catalyzed by highly active hierarchical Sn-USY at room temperature [J]. Catalysis Science & Technology, 2016, 6 (6): 1757- 1763" method to prepare Sn-USY molecular sieve, the preparation method of the adopted Sn-USY molecular sieve is:

[0050] H-USY molecular sieve was mixed with nitric acid, treated at 85°C for 8h, the sample was filtered and washed with deionized water, and dried at 120°C for 12h to obtain a solid sample. This solid sample was mixed with tin tetrachloride pentahydrate (SnCl 4 .5H 2 O) mixed for 1h to obtain a chemical composition of 0.03SnO 2 : 100SiO2 2 The mixed liquid was dried at 100°C for 12 hours, and finally calcined at 550°C for 3 hours to obtain a molecular sieve sample. Among them, the amount of H-USY is 2.0g, the amount of nitric acid is 50mL, the amount of SnCl 4 .5H 2 The amount of O used is 0.6 g.

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Abstract

The invention relates to a method for preparing lactate. The method comprises the following steps: contacting pyruvic aldehyde and alcohol with a catalyst in a reactor, and reacting to obtain a lactate-containing product, wherein the molar ratio of the pyruvic aldehyde to the alcohol is 1:(20-225), the reaction temperature is 30-180 DEG C, the reaction time is 1-10 hours, the catalyst contains a mixture of a titanium-silicon molecular sieve and a tin-silicon molecular sieve, and the weight ratio of the pyruvic aldehyde to the mixture of the titanium-silicon molecular sieve and the tin-siliconmolecular sieve based on dry basis weight is 1:(0.1-6). The method provided by the invention has high pyruvic aldehyde conversion rate and high lactate yield.

Description

technical field [0001] The invention relates to a method for preparing lactate. Background technique [0002] Methyl lactate, hydroxycarboxylate compound, chemical formula C 4 h 8 o 3 , Colorless liquid, flammable, soluble in water, ethanol, organic solvents, irritating, density 1.09, boiling point 144.8°C, melting point -66.2°C. Methyl lactate is an important oxygen-containing organic chemical intermediate, which can be used as a high-boiling solvent, cleaning agent, synthetic raw material, etc., and is widely used in medicine, resin coatings, adhesives, cleaning agents, dry cleaning fluids, printing inks, cosmetics, tobacco and alcohol , beverages and other food industries. For example, it can be used as a solvent for nitrocellulose, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate and cellulose ether. When used as a solvent for nitrocellulose paint and paint, it can improve the whitening resistance and ductility of the paint. As an importa...

Claims

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Application Information

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IPC IPC(8): C07C67/00C07C69/68B01J29/80
CPCC07C67/00C07C45/64B01J29/80B01J35/19C07C69/68C07C49/175Y02P20/584
Inventor 夏长久刘聿嘉王亚敏彭欣欣罗一斌朱斌林民舒兴田
Owner CHINA PETROLEUM & CHEM CORP
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