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Low-smoke halogen-free flame-retardant cable material

A flame-retardant cable material and raw material technology, applied in the field of cable materials, can solve the problems of reduced mechanical properties and processing properties of materials, influence of mechanical properties of polymer materials, poor flame-retardant efficiency of magnesium hydroxide, etc., to reduce surface energy and accelerate The rate of thermal decomposition and the effect of improving the modification effect

Inactive Publication Date: 2019-08-30
JIANGSU XINCHANGFENG CABLE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the small particle size and large specific surface of nano-magnesium hydroxide, its surface contains a large number of hydrophilic groups, which has strong water absorption and is prone to agglomeration, so that its compatibility with the body resin is poor, resulting in high molecular weight. The mechanical properties of the material are affected, which limits its application in polymer materials; in addition, the flame retardant efficiency of magnesium hydroxide is poor, and its addition needs to be particularly high to give the flame retardant material the ideal flame retardant performance, but Excessive addition will inevitably lead to a decrease in the mechanical properties and processing properties of the material, affecting the performance of the material

Method used

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  • Low-smoke halogen-free flame-retardant cable material

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Effect test

Embodiment 1

[0022] A low-smoke halogen-free flame-retardant cable material, the raw materials of which include the following components in parts by weight: 15 parts of ethylene-vinyl acetate copolymer, 8 parts of linear low-density polyethylene, 8 parts of ethylene-octene copolymer, 10 parts of acid anhydride grafted linear polyethylene, 0.6 part of stearic acid, 0.1 part of antioxidant 1010, and 8 parts of modified porous sheet-like nano-magnesium hydroxide.

[0023] Wherein, the modified porous flaky nano-magnesium hydroxide is a porous flaky nano-magnesium hydroxide modified by nano polyacrylate microemulsion, and its preparation method comprises the following steps:

[0024] a) Weigh 13.3g of magnesium chloride, add 210mL of deionized water to prepare magnesium chloride solution, slowly add 140mL of ammonia water with a concentration of 25%, add 7g of sodium lauryl sulfate after the dropwise addition, mix well and pour In the autoclave, carry out hydrothermal reaction, the reaction te...

Embodiment 2

[0029] A low-smoke halogen-free flame-retardant cable material, the raw materials of which include the following components by weight: 35 parts of ethylene-vinyl acetate copolymer, 25 parts of linear low-density polyethylene, 25 parts of ethylene-octene copolymer, 35 parts of acid anhydride grafted linear polyethylene, 5 parts of magnesium stearate, 3 parts of antioxidant 168, 25 parts of modified porous sheet-like nano-magnesium hydroxide.

[0030] Wherein, the modified porous flaky nano-magnesium hydroxide is a porous flaky nano-magnesium hydroxide modified by nano polyacrylate microemulsion, and its preparation method comprises the following steps:

[0031] a) Weigh 47.5g of magnesium chloride, add 750mL of deionized water to prepare a magnesium chloride solution, slowly add 500mL of ammonia water with a concentration of 28%, add 25g of sodium lauryl sulfate after the addition, mix well and pour In the autoclave, carry out hydrothermal reaction, the reaction temperature is ...

Embodiment 3

[0036] A low-smoke halogen-free flame-retardant cable material, the raw materials of which include the following components in parts by weight: 25 parts of ethylene-vinyl acetate copolymer, 16 parts of linear low-density polyethylene, 16 parts of ethylene-octene copolymer, 20 parts of acid anhydride grafted linear polyethylene, 2.5 parts of polyethylene wax, 1.5 parts of antioxidant DLTP, and 16 parts of modified porous sheet-shaped nano-magnesium hydroxide.

[0037] Wherein, the modified porous flaky nano-magnesium hydroxide is a porous flaky nano-magnesium hydroxide modified by nano polyacrylate microemulsion, and its preparation method comprises the following steps:

[0038] a) Weigh 28.5g of magnesium chloride, add 450mL of deionized water to prepare magnesium chloride solution, slowly add 300mL of ammonia water with a concentration of 26%, add 15g of sodium lauryl sulfate after the addition, mix well and pour In the autoclave, carry out hydrothermal reaction, the reaction...

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Abstract

The invention provides a low-smoke halogen-free flame-retardant cable material, which is prepared from the following raw materials in parts by weight: 15 to 35 parts of an ethylene-vinyl acetate copolymer, 8 to 25 parts of linear low-density polyethylene, 8 to 25 parts of ethylene-olefin copolymer, 10 to 35 parts of maleic anhydride grafted linear polyethylene, 0.6 to 5 parts of a lubricant, 0.1 to 3 parts of an antioxidant, and 8 to 25 parts of modified porous flake-like nanometer magnesium hydroxide. According to the low-smoke halogen-free flame-retardant cable material of the invention, thetraditional nano magnesium hydroxide is replaced with the porous flake-like nano magnesium hydroxide as an inorganic flame retardant, so that the heating area of nano magnesium hydroxide particles iseffectively increased, the rate of thermal decomposition is accelerated, and the flame retardant efficiency of the nano magnesium hydroxide is improved; in addition, nano polyacrylate is adopted to modify the surface of porous nano magnesium hydroxide, so as to weaken the hydrophilicity of the surface of the nano magnesium hydroxide, reduce the surface energy thereof, and enable the nano magnesium hydroxide to be evenly distributed in matrix resin, thereby effectively improving the mechanical properties and flame retardant properties of the material.

Description

technical field [0001] The invention relates to the field of cable materials, in particular to a low-smoke, halogen-free, flame-retardant cable material. Background technique [0002] Flame retardants, also known as flame retardants, fire retardants or fire retardants, are additives that impart flame retardancy to flammable polymers, and can improve the flame retardancy, self-extinguishing or smoke suppression of flammable or combustible materials. Some highly efficient organic halogen-containing flame retardants in traditional flame retardants are incomparable to other flame retardants, but their harm to the environment and human beings cannot be ignored. Therefore, with people's increasing awareness of environmental protection, safety and health, countries around the world have begun to focus on research, development and application of environmentally friendly flame retardants to replace flame retardants that threaten the environment and humans, thus making non-toxic, The...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L51/06C08K9/08C08K7/24
CPCC08L23/0853C08L2205/035C08L2205/025C08L2201/02C08L2201/22C08L2203/202C08K2201/011C08L23/0815C08L51/06C08K9/08C08K7/24
Inventor 张军虎张雅珩赵佩佩
Owner JIANGSU XINCHANGFENG CABLE
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