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Illite/smectite clay containing anti-PID functional master batch for photovoltaic packaging film and preparation method for illite/smectite clay containing anti-PID functional master batch

A technology for encapsulating films and functional masterbatches, applied in the direction of films/sheets without carriers, adhesives, non-polymer adhesive additives, etc., can solve the problems of no anti-PID function, low battery performance, etc. Burning effect, excellent compatibility, and density-enhancing effect

Active Publication Date: 2019-05-03
NINGBO NENGZHIGUANG NEW MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The purpose of the present invention is to overcome the defect that the masterbatch for photovoltaic packaging film in the prior art does not have the anti-PID function, resulting in low battery performance, and provides a kind of I / Mont-containing compound that can have the anti-PID function and improve the performance of photovoltaic cells. Anti-PID functional master batch for photovoltaic encapsulation film of clay and preparation method thereof

Method used

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  • Illite/smectite clay containing anti-PID functional master batch for photovoltaic packaging film and preparation method for illite/smectite clay containing anti-PID functional master batch
  • Illite/smectite clay containing anti-PID functional master batch for photovoltaic packaging film and preparation method for illite/smectite clay containing anti-PID functional master batch
  • Illite/smectite clay containing anti-PID functional master batch for photovoltaic packaging film and preparation method for illite/smectite clay containing anti-PID functional master batch

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] An anti-PID functional masterbatch for photovoltaic encapsulation films containing Il / Mongolian clay, said masterbatch is composed of the following components in terms of weight percentage: EVA resin (E280PV (SAMSUNG TOTAL)) with a vinyl acetate content of 25% 50 %, modified zirconium phosphate crystal (Mianzhu Yaolong Chemical Co., Ltd.) 20%, crosslinking agent (di(4-methylbenzoyl) peroxide) 6%, silane coupling agent (methyl vinyl dimethyl Oxysilane) 1.5%, Nanoil / Mongolian clay with a particle size of 25nm (Zhejiang Kaideli Chemical Co., Ltd.) 15%, co-crosslinking agent (methyl triallyl isocyanurate) 5.5%, anti-ultraviolet Absorbent (2,4-dihydroxybenzophenone) 0.50%, light stabilizer (PR-31) (Clariant) 2.5%, and antioxidant BHT 1.5%.

[0045] The preparation method of the anti-PID functional masterbatch for the photovoltaic encapsulation film containing Iraqi / Mongolian clay is as follows:

[0046] (1) Preparation of modified zirconium phosphate crystals: Pour 50mL of ...

Embodiment 2

[0051] An anti-PID functional masterbatch for photovoltaic encapsulation films containing Iraqi / Mongolian clay, said masterbatch is composed of the following components in terms of weight percent: EVA resin (E262PV (Hanwha Total)) with a vinyl acetate content of 28% 88%, modified zirconium phosphate crystal (Mianzhu Yaolong Chemical Co., Ltd.) 4%, crosslinking agent (dicumyl peroxide) 0.5%, silane coupling agent (vinyl triethoxysilane) 0.5%, particle size 95nm nano-yi / Mongolian clay (Zhejiang Kaideli Chemical Co., Ltd.) 5%, co-crosslinking agent (triallyl isopolycyanate) 0.5%, anti-ultraviolet absorber (2-hydroxyl-4-normal octyloxybenzophenone) 0.1%, light stabilizer 944 (Clariant) 0.6% and antioxidant 1076 0.8%.

[0052] The preparation method of the anti-PID functional masterbatch for the photovoltaic encapsulation film containing Iraqi / Mongolian clay is as follows:

[0053] (1) Preparation of modified zirconium phosphate crystals: Pour 50mL of silane coupling agent into 15...

Embodiment 3

[0058] An anti-PID functional masterbatch for photovoltaic encapsulation films containing Il / Mongolian clay, said masterbatch is composed of the following components in terms of weight percentage: EVA resin (E280PV (SAMSUNG TOTAL)) with a vinyl acetate content of 28% 74 %, modified zirconium phosphate crystal (Mianzhu Yaolong Chemical Co., Ltd.) 15%, crosslinking agent (tert-butyl carbon peroxide-2-ethylhexyl ester) 4%, silane coupling agent (vinyltrimethoxysilane ) 0.5%, particle size is 50nm nanometer Yi / Mongolia clay (Zhejiang Kaideli Chemical Co., Ltd.) 3%, co-crosslinking agent (triallyl isopolycyanate) 2.5%, anti-ultraviolet absorber (2- Hydroxy-4-n-octyloxybenzophenone) 0.1%, light stabilizer (PR-25) (Clariant) 0.5%, and antioxidant 264 0.4%.

[0059] The preparation method of the anti-PID functional masterbatch for the photovoltaic encapsulation film containing Iraqi / Mongolian clay is as follows:

[0060] (1) Preparation of modified zirconium phosphate crystals: Pour ...

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Abstract

The invention relates to the field of photovoltaic packaging materials and particularly relates to an illite / smectite clay containing anti-PID functional master batch for a photovoltaic packaging filmand a preparation method for the illite / smectite clay containing anti-PID functional master batch. The master batch is prepared from the following ingredients in percentage by weight: 50% to 88% of EVA resin, 4% to 20% of modified zirconium phosphate crystal, 0.5% to 10% of cross-linker, 0.5% to 2.5% of silane coupler, 5% to 15% of nano illite / smectite clay and the balance of auxiliaries. According to the illite / smectite clay containing anti-PID functional master batch for the photovoltaic packaging film and the preparation method for the illite / smectite clay containing anti-PID functional master batch, the defect in the prior art that master batches for photovoltaic packaging films do not have an anti-PID function and thus performance of batteries is low is overcome; the illite / smectiteclay containing anti-PID functional master batch for the photovoltaic packaging film, prepared by the method, has a good anti-PID function; meanwhile, a top-class flame-retardant effect is achieved under the condition of not additionally adding flame retardants; and furthermore, the illite / smectite clay containing anti-PID functional master batch further has the advantages that the antibacterial and mildewproof effect is good, meanwhile, toxic and harmful substances in the functional master batch can be remarkably reduced, and the like.

Description

technical field [0001] The invention relates to the field of photovoltaic encapsulation materials, in particular to an anti-PID functional masterbatch for a photovoltaic encapsulation film containing Il / Mongolian clay and a preparation method thereof. Background technique [0002] In recent years, photovoltaic power generation has gradually become one of the important methods to achieve sustainable development of energy and environment. In solar cells, the encapsulation material is a very important part. Its function is to protect the cells from damage by oxygen and water vapor, maintain or improve the solar energy point-to-photoelectric conversion efficiency, and prolong the service life. Common solar cell packaging films mainly include EVA (ethylene-vinyl acetate copolymer), POE (ethylene-octene copolymer), PVB (polyvinyl butyral), PU (polyurethane) and silicone films. At present, EVA and POE are the mainstream products. [0003] Foreign developed countries started relat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08K9/06C08K3/32C08K3/34C08K5/132C08J3/22C09J123/08C09J11/04C09J11/06C09J7/10
Inventor 李全涛张发饶高培付冰占建军
Owner NINGBO NENGZHIGUANG NEW MATERIALS TECH
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