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A graphite electrode protective agent

A graphite electrode and protective agent technology, which is applied in the coating and other directions, can solve the problems of the difference in thermal expansion coefficient between the coating and the graphite electrode, the decrease of the electrode's ability to resist high-current impact, and the increase in the unit consumption of the graphite electrode, so as to shorten the smelting time and smelting time The effect of shortening and high electric power utilization efficiency

Active Publication Date: 2021-01-15
亚创环能科技集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Graphite electrodes used in silicon smelting, steelmaking or other smelting furnaces, the main raw materials include natural graphite, petroleum coke, pitch coke and coal tar pitch, it has good high temperature performance, low thermal expansion coefficient, light weight, strong corrosion resistance and easy processing , excellent thermal shock resistance, but it is usually used in a high-temperature oxidizing atmosphere. The general working temperature is 1200°C-1500°C. The above oxidation increases suddenly, and the oxidation loss accounts for 40% to 60% of the total consumption, and it intensifies as the temperature rises. The higher the temperature, the faster the oxidation speed, and the oxidation loss of the electrode accounts for more than 60% of the total consumption.
Due to the high-temperature oxidizing atmosphere, the graphite motor is prone to serious oxidation, so it gradually becomes thinner from the oxidized part, and even fractures appear in the connecting part, which reduces the wear resistance of the electrode; in addition, due to the skin effect of the current , the thinner electrode, the current density increases, and the electrode's ability to withstand large current impacts also decreases, which leads to an increase in the unit consumption of the graphite electrode
[0003] At present, the Chinese patent CN92110580.0 uses refractory materials and organic binders to make primer and surface coatings. Although it can protect graphite electrodes to a certain extent, the coefficient of thermal expansion of coatings and graphite electrodes in the heating process of graphite electrodes has not been solved. The problem of large differences often leads to partial peeling or peeling during the process of rising to high temperature, which directly affects the use effect, and the organic adhesive used leads to the highly volatile decomposition of the coating during use, resulting in too many pores in the coating. Does not form an effective continuous coating, weakening the protective effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The raw material formula is calculated in parts by weight of components: 50 parts of silicone resin, 1.2 parts of organic montmorillonite, 7 parts of 100% bentonite pregelatin, 4 parts of 400 mesh talc powder, 8 parts of mica powder, 25.6 parts of conductive mica powder, AC300 0.2 parts of defoaming agent, 4 parts of mixed solvent, 2 parts of HPA202 anti-sagging agent and 2 parts of carbon black to prepare the protective agent.

[0024] The sample prepared by coating 0.2mm of the above protective agent on a graphite electrode with a size of 20mm*20mm*60mm was heated to 1600°C under air conditions and kept for 72 hours, then cooled naturally to room temperature, and the oxidation loss was 5.7 %, the resistivity is 2.8μΩ·m, the thermal conductivity is 420W / (m*℃), and the coating does not fall off or crack. It can save electricity by 20% if it is used on the graphite electrode surface of refining furnace in steelmaking plant.

Embodiment 2

[0036] The raw material formula is calculated in parts by weight of components: 42 parts of silicone resin, 2 parts of organic montmorillonite, 6 parts of 100% bentonite pregelatin, 7 parts of 400 mesh talc powder, 5 parts of mica powder, 47 parts of conductive mica powder, AC300 0.4 parts of defoaming agent, 1.5 parts of HPA202 anti-sagging agent and 4 parts of carbon black are used to prepare the protective agent.

[0037] The sample prepared by coating 0.1mm of the above protective agent on a graphite electrode with a size of 20mm*20mm*60mm was heated to 1500°C under air conditions and kept for 60h, then naturally cooled to room temperature and weighed. The loss is 5.9%, the resistivity is 2.9μΩ·m, and the thermal conductivity is 416W / (m*℃). The coating does not fall off or crack.

Embodiment 3

[0039] The raw material formula is calculated in parts by weight of components: 20 parts of silicone resin, 2 parts of organic montmorillonite, 5 parts of 100% bentonite pregelatin, 9 parts of 400 mesh talc powder, 3 parts of mica powder, 3 parts of mixed solvent, conductive mica 60 parts of powder, 0.1 part of AC300 defoamer, 4 parts of HPA202 anti-sagging agent and 1 part of carbon black to prepare a protective agent.

[0040] Coat 0.4mm of the above-mentioned protective agent on a graphite electrode with a size of 20mm*20mm*60mm to prepare the test sample. After heating the sample to 1450°C under air conditions and keeping it warm for 48 hours, it is naturally cooled to room temperature and weighed. The loss is 5.7%, the resistivity is 3μΩ·m, the thermal conductivity is 392W / (m*℃), and the coating does not fall off or crack.

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Abstract

The invention discloses a graphite electrode protective agent. The protective agent is prepared from the following components in parts by weight: 15-125 parts of silicone resin, 0.3-3 parts of organicmontmorillonite, 2-18 parts of 100% bentonite pre-gel, 1-10 parts of 400 mesh talcum powder, 2-20 parts of mica powder, 7-64 parts of conductive mica powder, 0-10 parts of a mixed solvent, 0.06-0.5 parts of an AC300 defoaming agent, 0.6-5 parts of an HPA202 anti-sag agent and 0.6-5 parts of carbon black. The agent has obvious oxidation resistance, can prevent electrodes from being oxidized at high melting temperature and the electrode end from deforming and can keep continuous arc or few arc breaks, melting efficiency is improved, melting time is shortened, electric energy is saved, the service life of the whole power supply system is effectively prolonged, equipment accidents are reduced, and equipment maintenance intensity is reduced.

Description

technical field [0001] The invention belongs to the technical field of metal smelting, and in particular relates to a graphite electrode protective agent. Background technique [0002] Graphite electrodes used in silicon smelting, steelmaking or other smelting furnaces, the main raw materials include natural graphite, petroleum coke, pitch coke and coal tar pitch, it has good high temperature performance, low thermal expansion coefficient, light weight, strong corrosion resistance and easy processing , excellent thermal shock resistance, but it is usually used in a high-temperature oxidizing atmosphere. The general working temperature is 1200°C-1500°C. The above oxidation increases suddenly, and the oxidation loss accounts for 40% to 60% of the total consumption, and it intensifies as the temperature rises. The higher the temperature, the faster the oxidation rate, and the oxidation loss of the electrode accounts for more than 60% of the total consumption. Due to the high-t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/04C09D7/61C09D7/62
CPCC08K2201/001C08K2201/014C09D183/04C09D7/61C09D7/62C08K13/06C08K3/346C08K3/34C08K3/04
Inventor 张作帅
Owner 亚创环能科技集团有限公司
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