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High-flame-retardant high-thermal-conductive PVC (polyvinyl chloride) compound cable material and preparation method thereof

A composite cable material, high thermal conductivity technology, used in circuits, electrical components, plastic/resin/wax insulators, etc., can solve the problems of high temperature resistance, poor melt leveling performance, organic solvent insulation, etc., to improve Processing fluidity, good dielectric properties, and the effect of improving compatibility

Inactive Publication Date: 2018-12-28
XINYA ELECTRONICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Wires and cables are mainly composed of wires, insulating layers, filling structures, shielding layers and sheaths. The materials of insulating layers and sheaths include polyvinyl chloride, polytetrafluoroethylene, etc. PVC materials have excellent mechanical and physical properties. , flexibility, chemical resistance, cheap price, and excellent processing performance, but it is not resistant to oil, organic solvents, hard insulation, and high temperature resistance is difficult to meet the demand
Although polytetrafluoroethylene material has soft mechanical properties, low surface energy, high and low temperature resistance, corrosion resistance, weather resistance, low friction coefficient, high lubrication and other performance properties, it has a high melting point and poor melt leveling performance, which leads to poor processing performance. Poor, difficult to melt extrude

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] 100 parts of polyvinyl chloride, 36 parts of PTFE micropowder, 49 parts of perfluoroalkoxy copolymer, 15 parts of ethylene-chlorotrifluoroethylene copolymer, 30 parts of composite compatibilizer, 20 parts of nano zinc oxide, thermal conductive filler 42 parts, 10 parts of para-aramid fiber and 15 parts of modified magnesium hydroxide,

[0035] The mass ratio of cyclohexyl methacrylate, p-methylstyrene and vinyl butyrate in the composite compatibilizer is 0.8:1.2:2;

[0036] The thermally conductive filler is prepared from raw materials with the following weight components:

[0037] 25 parts of micron aluminum nitride powder, 15 parts of 20 micron aluminum oxide powder, 15 parts of aluminum oxide powder, 2 parts of nano silicon nitride whiskers,

[0038] In the micron aluminum nitride powder, the weight ratio of the 2 micron aluminum nitride powder and the 5 micron aluminum nitride powder is 1:1, and the average particle size of the nano silicon nitride whiskers is 600 nm.

[003...

Embodiment 2

[0046] 100 parts of polyvinyl chloride, 31 parts of PTFE micropowder, 44 parts of perfluoroalkoxy copolymer, 25 parts of ethylene-chlorotrifluoroethylene copolymer, 35 parts of composite compatibilizer, 30 parts of nano zinc oxide, thermal conductive filler 53 parts, 15 parts of para-aramid fiber and 10 parts of modified magnesium hydroxide,

[0047] The mass ratio of cyclohexyl methacrylate, p-methylstyrene and vinyl butyrate in the composite compatibilizer is 2.6:3.5:2.5;

[0048] The thermally conductive filler is prepared from raw materials with the following weight components:

[0049] 30 parts of micron aluminum nitride powder, 20 parts of 20 micron alumina powder, 20 parts of alumina powder, 3 parts of nano silicon nitride whiskers,

[0050] In the micron aluminum nitride powder, the weight ratio of the 2 micron aluminum nitride powder to the 5 micron aluminum nitride powder is 3:1, and the average particle size of the nano silicon nitride whiskers is 600 nm.

[0051] In the for...

Embodiment 3

[0058] 100 parts of polyvinyl chloride, 33 parts of polytetrafluoroethylene powder, 45 parts of perfluoroalkoxy copolymer, 22 parts of ethylene-chlorotrifluoroethylene copolymer, 32 parts of composite compatibilizer, 25 parts of nano zinc oxide, thermal conductive filler 47 parts, 12 parts of para-aramid fiber and 13 parts of modified magnesium hydroxide,

[0059] The mass ratio of cyclohexyl methacrylate, p-methylstyrene and vinyl butyrate in the composite compatibilizer is 1.5:2.6:2.1;

[0060] The thermally conductive filler is prepared from raw materials with the following weight components:

[0061] 28 parts of micron aluminum nitride powder, 17 parts of 20 micron alumina powder, 17 parts of alumina powder, 2 parts of nano silicon nitride whiskers,

[0062] In the micron aluminum nitride powder, the weight ratio of the 2 micron aluminum nitride powder and the 5 micron aluminum nitride powder is 2:1, and the average particle size of the nano silicon nitride whiskers is 600 nm.

[0...

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Abstract

The invention particularly relates to a high-flame-retardant high-thermal-conductive PVC (polyvinyl chloride) compound cable material and a preparation method thereof. The high-flame-retardant high-thermal-conductive PVC compound cable material is prepared from the following raw materials in parts by weight: 100 parts of polyvinyl chloride, 31-36 parts of polytetrafluoroethylene micro-powder, 44-49 parts of a perfluoroalkoxy copolymer, 15-25 parts of an ethylene-trifluorochlor oethylene copolymer, 30-35 parts of a composite compatibilizer, 20-30 parts of nano zinc oxide, 42-53 parts of thermal-conductive filler, 10-15 parts of para-aramid fiber and 10-15 parts of modified magnesium hydrate. According to the invention, polytetrafluoroethylene is dispersed in the perfluoroalkoxy copolymer and the ethylene-trifluorochlor oethylene copolymer in a form of micro-powder, and is then blended with polyvinyl chloride, and meanwhile, the thermal-conductive filler, a fire retardant and the aramidfiber are added at proper proportions, therefore, the prepared compound cable material is stable in chemical properties, excellent in physical mechanical properties, electrical insulation properties and flame retardance, high in thermal conductivity, high in tensile strength and strong in toughness, facilitates the production, and reduces production cost.

Description

Technical field [0001] The invention relates to the field of cable manufacturing, in particular to a PVC composite cable material with high flame retardancy and high thermal conductivity and a preparation method thereof. Background technique [0002] Wires and cables are indispensable basic equipment for transmitting electric energy, transmitting information, and manufacturing various motors, electrical appliances, meters, automobiles, machine tools and other equipment, and are essential basic products in an electrified and information society. In 2012, my country surpassed the United States to become the world's largest producer of wires and cables, and its industry output value was second only to the automotive industry in the electrical and electrical industry. As an important basic industry, the wire and cable industry has been hailed as the "blood vessel" and "nerve" of the national economy. It occupies a very important position in my country's national economy and is respon...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L27/18C08L77/10C08L23/08C08K13/06C08K9/06C08K9/04C08K3/22C08K3/28C08K7/08H01B3/44
CPCC08K2003/2224C08K2003/2296C08K2003/282C08K2201/011C08L27/06C08L2201/02C08L2203/202C08L2205/035C08L2205/16H01B3/443C08L27/18C08L77/10C08L23/0892C08K13/06C08K9/06C08K9/04C08K3/22C08K3/28C08K7/08
Inventor 石刘建贺云峰
Owner XINYA ELECTRONICS
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