Preparation method of chelate adsorbent
A technology of chelating adsorbents and organic solvents, applied in the field of materials, can solve problems such as poor economy, property loss, landslides and debris flows, and achieve good stability
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Embodiment 1
[0029] The preparation of graft monomer EDTAD, its preparation steps are as follows:
[0030] Suspend 18g of EDTA (acid) in 31ml of anhydrous pyridine, then add 25ml of anhydride under nitrogen protection, and stir at 65°C for a certain period of time. According to this, the product is cooled and filtered under a stable nitrogen flow, washed with 200ml of anhydrous acetic anhydride and anhydrous acetic anhydride, and finally dried in a vacuum oven at 50-60°C to obtain the grafted monomer EDTAD. The EDTAD obtained by the reaction was tested by infrared.
[0031] The infrared spectrum of the present embodiment gained EDTAD sees figure 1 , in the infrared spectrum of EDTAD at 1809cm -1 and 1765cm -1 Absorption characteristic peaks appear and the low-frequency peak is slightly stronger than the high-frequency peak, which are two characteristic absorption peaks of the C=O stretching vibration absorption of the acid anhydride. These are the characteristic peaks of the cyclic anhy...
Embodiment 2
[0033] Suspend 30g of EDTA (acid) in 50m of anhydrous pyridine, then add 50ml of anhydride under nitrogen protection, and stir at 65°C for a certain period of time. According to this, the product was cooled and filtered under a stable nitrogen flow, washed with 200ml of anhydride and ether, and finally dried in a vacuum oven at 50-60°C to obtain the grafted monomer EDTAD. The EDTAD obtained by the reaction was tested by infrared.
[0034] The infrared spectrum of the present embodiment gained EDTAD sees figure 1 , in the infrared spectrum of EDTAD at 1796cm -1 and 1749cm -1 Absorption characteristic peaks appear and the low frequency peak is slightly stronger than the high frequency peak, which are two characteristic absorption peaks of the C=O stretching vibration absorption of the acid anhydride. These are the characteristic peaks of the cyclic anhydride. at 1252cm -1 The stretching vibration peak at is the C-O-C stretching vibration peak of the cyclic anhydride, at 1060...
Embodiment 3
[0036] 1g chitosan monomer is completely dissolved with 2ml glacial acetic acid, after a certain period of time, after dissolving, solution is added in 50mlN, in the N-dimethylformamide, then add 1g embodiment 1 gained EDTAD grafting monomer, and at 65 Polymerization reaction was carried out at ℃ and in a nitrogen-enclosed environment until the reaction was complete. After the reaction was completed, it was washed with 50ml of N,N-dimethylformamide and filtered, then washed with 100ml of distilled water for centrifugation, and then washed with 100ml of saturated sodium bicarbonate solution for centrifugation. , then wash with 100ml of distilled water and carry out centrifugation, finally wash with 50ml of 95% ethanol and carry out centrifugation, place it in a vacuum oven and dry it at 70°C to obtain the chitosan graft of the present invention.
[0037] The chitosan graft obtained is placed in the calcium solution of configuration and adsorbed for 2h, and the solution after ads...
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