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Carbon material 3D toughened silicon carbide composite material and its preparation method and application

A technology for toughening silicon carbide and composite materials, which is applied in the field of carbon material 3D toughening silicon carbide composite materials and its preparation, can solve the problems of large amount of carbon material, poor interface bonding, complicated preparation process, etc., and achieves high bending strength, improved Bending strength, effect of reducing usage

Active Publication Date: 2020-12-15
绿业中试低碳科技(镇江)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Geng Haoran applied for "A device and process for preparing carbon fiber reinforced silicon carbide composite material" (CN 03138926.0) and "A multi-component silicon carbide ceramic with carbon fiber embedded in it", Zhang Yunlong's doctoral thesis "Short carbon fiber toughening carbonization Preparation of Silicon-based Composite Materials and Research on Its Fracture Mechanism", Qiao Guanjun's "Preparation Method of High-Strength and High-Density Isotropic Carbon Sliding Plate" (CN 101747039 A), Xiao Peng's "Carbon Fiber Reinforced Carbon-Silicon Carbide Dual-Matrix Friction Material "Preparation method" (CN 101486588 B) etc. all use carbon materials, especially carbon fiber toughened silicon carbide, but such methods have problems such as large amount of carbon materials, cumbersome preparation process, poor interface bonding, etc., and there are certain defects.

Method used

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  • Carbon material 3D toughened silicon carbide composite material and its preparation method and application

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Experimental program
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Effect test

Embodiment approach 1

[0023] This embodiment provides a carbon material 3D toughened silicon carbide composite material, including 5wt% of carbon fibers with a length of 1.0 mm, 3wt% of carbon nanotubes and 92wt% of silicon carbide (D50=0.6 um).

[0024] The preparation method of the above carbon material 3D toughened silicon carbide composite material is as follows:

[0025] Take 5 parts by mass of carbon fiber pretreated by wetting, 3 parts of carbon nanotubes and 92 parts of silicon carbide micropowder through wetting pretreatment and add them to the ball mill tank, and add silicon carbide grinding balls according to the ball-to-material ratio of 4:1, and the material The ratio accounts for 2 / 3 of the volume of the ball milling tank, the ball milling rate is 400 r / min, and the ball milling time is 0.5 h. After the ball milling, the carbon material 3D toughened silicon carbide composite material is obtained.

[0026] The method for the above-mentioned wetting pretreatment of carbon fibers and car...

Embodiment approach 2

[0030] This embodiment provides a carbon material 3D toughened silicon carbide composite material, which contains 1 wt% of carbon fibers with a length of 0.5 mm, 0.5 wt% of carbon nanotubes and 98.5 wt% of silicon carbide (D50=1.2 um).

[0031] The preparation method of the above carbon material 3D toughened silicon carbide composite material is as follows:

[0032] Take 1 mass part of carbon fiber pretreated by wetting, 0.5 part of carbon nanotubes and 98.5 parts of silicon carbide micropowder through wetting pretreatment and add them to the ball mill jar, and add silicon carbide grinding balls according to the ball-to-material ratio of 2:1 to Absolute ethanol was used as the dispersion medium, the material ratio accounted for 2 / 3 of the volume of the ball milling tank, the ball milling speed was 500 r / min, and the ball milling time was 6 h. After the ball milling, a carbon material 3D toughened silicon carbide composite material was obtained.

[0033] The method for the abov...

Embodiment approach 3

[0037] This embodiment provides a carbon material 3D toughened silicon carbide composite material, including 3wt% of carbon nanotubes with a length of 100 um, 10wt% of mesoporous porous carbon, and 87wt% of silicon carbide (D50=0.9 um).

[0038] The preparation method of the above carbon material 3D toughened silicon carbide composite material is as follows:

[0039]Take 3 parts by mass of carbon nanotubes pretreated by wetting, 10 parts of porous carbon mainly mesoporous and pretreated by wetting, and 87 parts of silicon carbide micropowder into a ball mill tank, and add carbonization at a ball-to-material ratio of 8:1. Silicon grinding balls, using absolute ethanol as the dispersion medium, the material ratio accounts for 2 / 5 of the volume of the ball milling tank, the ball milling rate is 400 r / min, the ball milling time is 12 h, and the carbon material 3D toughened silicon carbide composite material is obtained after ball milling .

[0040] The method for the above-mentio...

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Abstract

The invention relates to the field of inorganic materials and discloses a carbon material 3D toughened silicon carbide composite as well as a preparation method and an application thereof. The carbonmaterial 3D toughened silicon carbide composite comprises 0.01wt%-10wt% of a micrometer-sized carbon material, 0.01wt%-10wt% of a nanometer-sized carbon material and 80wt%-99wt% of silicon carbide, and a micrometer-nanometer-sized carbon material 3D toughening structure is formed by intervention of the micrometer-sized carbon material and the nanometer-sized carbon material into silicon carbide. Compared with the prior art, only a small quantity of the carbon material needs to be used for obviously improving the toughening effect of silicon carbide, interfacial bond property of the carbon material with silicon carbide is good, the formed silicon carbide composite is stable in performance, and silicon carbide composite ceramic prepared from the silicon carbide composite is high in bending strength.

Description

technical field [0001] The invention relates to the field of inorganic materials, in particular to a carbon material 3D toughened silicon carbide composite material and its preparation method and application. Background technique [0002] Silicon carbide ceramics have excellent characteristics such as high temperature strength, strong oxidation resistance, good wear resistance, good thermal stability, low thermal expansion rate, high thermal conductivity and strong chemical corrosion resistance, especially at 1400 °C, the strength is still The characteristics that remain basically unchanged make it widely used in the fields of automobiles, mechanical chemicals, environmental protection, space technology, etc., and it has become an irreplaceable structural material in many fields. [0003] However, silicon carbide has the problem of brittle cracking, which affects its further application, so the "toughening" of silicon carbide has become an urgent problem to be solved in the ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/80C04B35/78C04B35/565
CPCC04B35/565C04B35/78C04B2235/6562C04B2235/666C04B2235/5288C04B2235/96
Inventor 张志华张清香
Owner 绿业中试低碳科技(镇江)有限公司
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