Thermal conductivity filler composition as well as high thermal conductivity insulating composite material and preparation method thereof
A technology of insulating composite materials and thermally conductive fillers, which is applied in the field of thermally conductive filler compositions and high thermally conductive insulating composite materials, can solve the problems of low thermal conductivity of ordinary inorganic thermally conductive fillers, reduced mechanical properties and insulating properties, and cannot be applied to the field of insulation. Excellent mechanical and insulating properties, excellent dielectric properties, and the effect of improving water vapor barrier properties
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[0053] The preparation of component A takes place in a solvent, for example in absolute ethanol solution. The inventors of the present invention found that adjusting the reaction environment to be weakly alkaline is beneficial to the preparation of component A with good properties. For example, the pH of the reaction solution can be adjusted to 8-9. The pH can be adjusted with an alkaline solution, for example, a 10% aqueous NaOH solution.
[0054] When preparing Component A, in some cases, the surface modification reaction can be accelerated by heating. For example at temperatures around 80° C., sufficient surface modification can be achieved after 30 minutes.
[0055] After the reaction, the reaction solution can be dried to obtain dry Component A.
[0056] The preparation of component B is also carried out in a solvent, for example in dry dimethylformamide (DMF).
[0057] The preparation of component B is preferably carried out under ultrasonic dispersion. Ultrasonic d...
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[0069] Preparation of thermally conductive filler composition
[0070] Alumina can be spherical alumina or / and angular alumina; angular alumina can be purchased commercially from MZS-3 from Albemarle; AM-210, AM-43, LA4000 from Sumitomo; M15 from Foshan Huaya. Spherical alumina can be purchased from BAK-2 and BAK-10 of Baitu High-tech Materials Technology; AS-10 and AS-05 of Showa Denko.
[0071] Aluminum nitride can be purchased from Japan Toyo Aluminum TFZ-N01P, TFZ-A02P, etc.;
[0072] Boron nitride can be purchased commercially as JYBN-0010 and JYBN-0100 from Bengbu Xinyuan Material Technology; BBN-10C and BBN-30C from Baitu High-tech Material Technology.
[0073]The graphene oxide used in the examples was prepared by the Hummers method. Specifically, concentrated sulfuric acid was added in an ice-water bath, appropriate amount of graphite and sodium nitrate were added under the condition of magnetic stirring, and potassium permanganate was added in stages. Control the...
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