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Thermal conductivity filler composition as well as high thermal conductivity insulating composite material and preparation method thereof

A technology of insulating composite materials and thermally conductive fillers, which is applied in the field of thermally conductive filler compositions and high thermally conductive insulating composite materials, can solve the problems of low thermal conductivity of ordinary inorganic thermally conductive fillers, reduced mechanical properties and insulating properties, and cannot be applied to the field of insulation. Excellent mechanical and insulating properties, excellent dielectric properties, and the effect of improving water vapor barrier properties

Active Publication Date: 2018-06-22
GUANGDONG SHENGYI SCI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The first way does not need to add thermally conductive fillers, relying on the polymer itself to achieve thermal conductivity, the scope of application is narrow, and it cannot be applied to the field of insulation due to its own electrical conductivity; the second way is to form a thermal conduction path by adding inorganic thermally conductive fillers to contact each other in the polymer system To achieve thermal conductivity, it has a wide range of applications. However, the thermal conductivity of ordinary inorganic thermally conductive fillers is still low, and the compatibility with polymer systems is poor. Usually, it is necessary to add 50% by weight to 90% by weight to achieve high thermal conductivity. function, which often leads to a reduction in the mechanical and insulating properties of the polymer material

Method used

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  • Thermal conductivity filler composition as well as high thermal conductivity insulating composite material and preparation method thereof
  • Thermal conductivity filler composition as well as high thermal conductivity insulating composite material and preparation method thereof
  • Thermal conductivity filler composition as well as high thermal conductivity insulating composite material and preparation method thereof

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preparation example Construction

[0053] The preparation of component A takes place in a solvent, for example in absolute ethanol solution. The inventors of the present invention found that adjusting the reaction environment to be weakly alkaline is beneficial to the preparation of component A with good properties. For example, the pH of the reaction solution can be adjusted to 8-9. The pH can be adjusted with an alkaline solution, for example, a 10% aqueous NaOH solution.

[0054] When preparing Component A, in some cases, the surface modification reaction can be accelerated by heating. For example at temperatures around 80° C., sufficient surface modification can be achieved after 30 minutes.

[0055] After the reaction, the reaction solution can be dried to obtain dry Component A.

[0056] The preparation of component B is also carried out in a solvent, for example in dry dimethylformamide (DMF).

[0057] The preparation of component B is preferably carried out under ultrasonic dispersion. Ultrasonic d...

Embodiment

[0069] Preparation of thermally conductive filler composition

[0070] Alumina can be spherical alumina or / and angular alumina; angular alumina can be purchased commercially from MZS-3 from Albemarle; AM-210, AM-43, LA4000 from Sumitomo; M15 from Foshan Huaya. Spherical alumina can be purchased from BAK-2 and BAK-10 of Baitu High-tech Materials Technology; AS-10 and AS-05 of Showa Denko.

[0071] Aluminum nitride can be purchased from Japan Toyo Aluminum TFZ-N01P, TFZ-A02P, etc.;

[0072] Boron nitride can be purchased commercially as JYBN-0010 and JYBN-0100 from Bengbu Xinyuan Material Technology; BBN-10C and BBN-30C from Baitu High-tech Material Technology.

[0073]The graphene oxide used in the examples was prepared by the Hummers method. Specifically, concentrated sulfuric acid was added in an ice-water bath, appropriate amount of graphite and sodium nitrate were added under the condition of magnetic stirring, and potassium permanganate was added in stages. Control the...

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Abstract

The invention discloses a thermal conductivity filler composition. The thermal conductivity filler composition is characterized by being prepared from the following components in parts by weight: 90 to 95 percent of component A and 5 to 10 percent of component B, wherein the component A is prepared from thermal conductivity filler and a silane coupling agent, and the silane coupling agent accountsfor 1 to 3 percent of the total weight of the component A; the component B is prepared from graphene oxide and isocyanate, and the isocyanate accounts for 70 to 80 percent of the total weight of thecomponent B. The invention also discloses a high thermal conductivity insulating composite material and a high thermal conductivity insulation base film and preparation methods of the high conductivity thermal insulating composite material and the high thermal insulation base film. The high thermal conductivity insulating composite material has high thermal conductivity, good insulation and mechanical properties, good dielectric properties and high water vapor barrier property.

Description

technical field [0001] The invention relates to the field of thermally conductive materials, in particular to a thermally conductive filler composition, a high thermally conductive insulating composite material and methods for preparing them. Background technique [0002] With the development of electronic components and electronic equipment toward miniaturization and miniaturization, more and more heat is accumulated in a limited space. Therefore, higher requirements are placed on the thermal conductivity and heat dissipation performance of insulating materials. The thermal conductivity of ordinary polymer materials is mostly difficult to meet the heat dissipation requirements. [0003] At present, there are two main ways to improve the thermal conductivity of polymers: (1) Synthesize polymers with high thermal conductivity structures, such as polyacetylene, polyaniline, polypyrrole, etc., which mainly conduct electricity through electronic heat conduction mechanisms; or ha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K9/06C08K3/22C08K3/28C08K3/38C08K9/04C08K3/04C08L67/02C08L79/08C08J5/18
CPCC08J5/18C08J2367/02C08J2379/08C08K3/04C08K3/22C08K3/28C08K3/38C08K9/04C08K9/06C08K2003/2227C08K2003/282C08K2003/385
Inventor 左陈茹敬宏唐亚峰伍宏奎
Owner GUANGDONG SHENGYI SCI TECH
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