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Poly(3-hydroxybutyrate-3-hydroxyhexanoate) carboxymethyl cellulose straw powder composite full biodegradable material

The technology of carboxymethyl cellulose and hydroxycaproate is applied in the field of polycarboxymethyl cellulose straw powder composite biodegradable material and its preparation, which can solve the problems of high cost, poor impact resistance, high brittleness and the like , to achieve the effect of product safety, good impact resistance, and improved mechanical properties

Inactive Publication Date: 2018-05-29
中科众创(重庆)秸秆产业研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In order to overcome the disadvantages of poor impact resistance, high brittleness, and high cost of poly PHBHHx materials, the present invention uses poly PHBHHx to mix a certain proportion of straw powder, carboxymethyl cellulose, phosphate coupling agent, and polyethylene oxide to produce A poly(3-hydroxybutyrate-3-hydroxyhexanoate) carboxymethyl cellulose straw powder composite biodegradable material

Method used

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Effect test

Embodiment 1

[0020] A poly(3-hydroxybutyrate-3-hydroxyhexanoate) carboxymethyl cellulose straw powder composite biodegradable material is prepared from the following raw materials in parts by weight: PHBHHx 45-60 parts, 30-40 parts of straw powder, 0.2 parts of carboxymethyl cellulose, 1-3 parts of phosphate coupling agent, 2-5 parts of polyethylene oxide.

[0021] In an embodiment of the present invention, the particle size of the straw fiber powder is 60 mesh.

[0022] In the embodiment of the present invention, the raw materials: PHBHHx (Dongguan Yingsheng Plastic Chemical Co., Ltd.); straw powder (Shaanxi Jinhe Agricultural Technology Co., Ltd.), carboxymethyl cellulose (Shijiazhuang Senlong Chemical Co., Ltd. ), phosphate coupling agent (Yangzhou Tianyang Auxiliary Co., Ltd.), polyethylene oxide (Zhengzhou Shengyu Chemical Products Co., Ltd.).

[0023] In the embodiment of the design of the present invention, the main instruments and equipment involved: constant temperature blast dry...

Embodiment 2

[0034] A poly(3-hydroxybutyrate-3-hydroxyhexanoate) carboxymethyl cellulose straw powder composite biodegradable material is prepared from the following raw materials in parts by weight: PHBHHx 45-60 parts, 30-40 parts of straw powder, 0.4 parts of carboxymethyl cellulose, 1-3 parts of phosphate coupling agent, 2-5 parts of polyethylene oxide.

[0035] In an embodiment of the present invention, the particle size of the straw fiber powder is 60 mesh.

[0036] In the embodiment of the present invention, the raw materials: PHBHHx (Dongguan Yingsheng Plastic Chemical Co., Ltd.); straw powder (Shaanxi Jinhe Agricultural Technology Co., Ltd.), carboxymethyl cellulose (Shijiazhuang Senlong Chemical Co., Ltd. ), phosphate coupling agent (Yangzhou Tianyang Auxiliary Co., Ltd.), polyethylene oxide (Zhengzhou Shengyu Chemical Products Co., Ltd.).

[0037]In the embodiment of the design of the present invention, the main instruments and equipment involved: constant temperature blast dryi...

Embodiment 3

[0048] A poly(3-hydroxybutyrate-3-hydroxyhexanoate) carboxymethyl cellulose straw powder composite biodegradable material is prepared from the following raw materials in parts by weight: PHBHHx 45-60 parts, 30-40 parts of straw powder, 0.6 parts of carboxymethyl cellulose, 1-3 parts of phosphate coupling agent, 2-5 parts of polyethylene oxide.

[0049] In an embodiment of the present invention, the particle size of the straw fiber powder is 60 mesh.

[0050] In the embodiment of the present invention, the raw materials: PHBHHx (Dongguan Yingsheng Plastic Chemical Co., Ltd.); straw powder (Shaanxi Jinhe Agricultural Technology Co., Ltd.), carboxymethyl cellulose (Shijiazhuang Senlong Chemical Co., Ltd. ), phosphate coupling agent (Yangzhou Tianyang Auxiliary Co., Ltd.), polyethylene oxide (Zhengzhou Shengyu Chemical Products Co., Ltd.).

[0051] In the embodiment of the design of the present invention, the main instruments and equipment involved: constant temperature blast dry...

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Abstract

The invention provides a poly(3-hydroxybutyrate-3-hydroxyhexanoate)-carboxymethyl cellulose-straw powder composite full biodegradable material. The material is prepared by the following steps: mixingpoly(3-hydroxybutyrate-3-hydroxyhexanoate) (PHBHHx) and straw powder, adding a certain amount of carboxymethyl cellulose, phosphate coupling agent and polyoxyethylene, putting all the materials into athree-dimensional mixing machine for mixing, transferring the mixture into a mould, and putting the mould onto a plate vulcanizing machine for compression molding, so as to obtain a composite material. Compared with a poly(3-hydroxybutyrate-3-hydroxyhexanoate) product, a product prepared from the poly(3-hydroxybutyrate-3-hydroxyhexanoate)-plant fiber composite material has great advantages that the hydrophilicity of the material is improved, the mixing efficiency of the composite material is increased, and the processing property of the composite material can be obviously improved; the mechanical property and the mechanical property of the prepared product are greatly improved; the prepared composite material is high in tensile strength and strong in impact toughness, therefore, the composite material is a full degradable material with good environmental protection value and economic value.

Description

technical field [0001] The invention relates to a composite material and a preparation method thereof, specifically, a poly(3-hydroxybutyrate-3-hydroxyhexanoate) carboxymethyl cellulose straw powder composite biodegradable material and its preparation method. Background technique [0002] The thermoplastic polyester polyhydroxyalkanoic acid (PHA) produced by microbial fermentation is a copolymer of polyhydroxybutyric acid PHB and polyhydroxyvaleric acid PHV, usually written as P(3HB-co-3HV). It is a kind of macromolecular polymer stored in the cells of microorganisms in a granular state under non-equilibrium growth conditions. Pure PHB is hard and brittle, with poor impact resistance and difficult to process and use. When PHA contains an appropriate amount of PHV, the hardness of the material decreases, the elasticity becomes better, and the processability is good. PHA is a real and completely degradable high-grade material, that is, it can be completely degraded into wate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L97/02C08L1/28C08L23/30C08L71/02
CPCC08L67/04C08L2201/06C08L2205/035C08L97/02C08L1/286C08L23/30C08L71/02
Inventor 屈朝辉屈志豪袁小丽
Owner 中科众创(重庆)秸秆产业研究院有限公司
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