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A kind of gemini composite surfactant for oil displacement and preparation method thereof

A composite surfactant and surfactant technology, which is applied in the field of oil displacement Gemini composite surfactant and its preparation, can solve the problem of poor temperature and salt resistance stability, poor water solubility and foaming performance, and affect the oil displacement effect and other problems, to achieve good emulsification performance, strong foaming power, and reduce capillary resistance

Inactive Publication Date: 2020-06-23
NANYANG INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the invention has poor long-term temperature and salt resistance stability, and is easily affected by the reservoir environment. In the actual oil displacement process, the flow is slow, the oil displacement efficiency is low, and the water solubility and foaming performance are relatively poor, which affects the oil displacement effect.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A Gemini composite surfactant for oil displacement, comprising components and contents thereof: 28 parts by weight of Gemini surfactant, 1.2 parts by weight of sodium lauryl sulfate, 4.6 parts by weight of 1,3-propane sultone , 15 parts by weight of sorbitan oleate, 6.8 parts by weight of isopropanol, 13 parts by weight of polyoxyethylene octylphenol ether, 10.2 parts by weight of acetone, 3.5 parts by weight of ethylene bisstearamide, oligomeric sesqui 5.2 parts by weight of siloxane, 5.8 parts by weight of additives, 3.3 parts by weight of polyvinyl alcohol, 4.3 parts by weight of dodecylbenzenesulfonic acid, and 23 parts by weight of water.

[0036] The components and contents contained in the Gemini surfactant are: 5.8 parts by weight of ether, 16.5 parts by weight of ethylene oxide, 18 parts by weight of benzene, 15 parts by weight of aluminum trichloride, 12.8 parts by weight of n-octanoyl chloride, cyclohexane 2.8 parts by weight, 3.5 parts by weight of adipoyl c...

Embodiment 2

[0050] A Gemini composite surfactant for oil displacement, comprising components and contents thereof: 29 parts by weight of Gemini surfactant, 1.4 parts by weight of sodium lauryl sulfate, 4.8 parts by weight of 1,3-propane sultone , 16 parts by weight of sorbitan oleate, 6.9 parts by weight of isopropanol, 14 parts by weight of polyoxyethylene octylphenol ether, 10.4 parts by weight of acetone, 3.6 parts by weight of dimethyl tetrachloroterephthalate, 5.3 parts by weight of oligomeric silsesquioxane, 5.9 parts by weight of additives, 3.4 parts by weight of polyvinyl alcohol, 4.4 parts by weight of dodecylbenzenesulfonic acid, and 24 parts by weight of water.

[0051] The components and contents contained in the Gemini surfactant are: 5.9 parts by weight of ether, 16.8 parts by weight of ethylene oxide, 18.5 parts by weight of benzene, 16 parts by weight of aluminum trichloride, 13 parts by weight of n-octanoyl chloride, cyclohexane 2.9 parts by weight, 3.6 parts by weight of...

Embodiment 3

[0065] A Gemini composite surfactant for oil displacement, comprising components and contents thereof: 33 parts by weight of Gemini surfactant, 1.8 parts by weight of sodium lauryl sulfate, and 5.5 parts by weight of 1,3-propane sultone , 22 parts by weight of sorbitan oleate, 7.7 parts by weight of isopropanol, 18 parts by weight of polyoxyethylene octylphenol ether, 11.5 parts by weight of acetone, 4.4 parts by weight of dimethyl tetrachloroterephthalate, 6.6 parts by weight of polydimethylsiloxane, 6.3 parts by weight of additives, 4.8 parts by weight of polyvinyl alcohol, 5.4 parts by weight of dodecylbenzenesulfonic acid, and 28 parts by weight of water.

[0066] The components and contents contained in the Gemini surfactant are: 7.5 parts by weight of ether, 18.3 parts by weight of ethylene oxide, 23.8 parts by weight of benzene, 23 parts by weight of aluminum trichloride, 15.5 parts by weight of n-octanoyl chloride, cyclohexane 4.3 parts by weight, 4.4 parts by weight o...

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Abstract

The invention discloses a Gemini composite surfactant for oil displacement and a preparation method of the Gemini composite surfactant and belongs to the technical field of surfactants. The Gemini composite surfactant is prepared from components in parts by weight as follows: 28-33 parts of a Gemini surfactant, 1.2-1.8 parts of lauryl sodium sulfate, 4.6-5.5 parts of 1,3-propanesultone, 15-22 parts of Span 80, 6.8-7.7 parts of isopropyl alcohol, 13-18 parts of 2-(2-[4-(1,1,3,3-tetramethylbutyl)phenoxy]ethoxy)ethanol, 10.2-11.5 parts of acetone, 3.5-4.4 parts of a heat resistant agent, 5.2-6.6parts of an enhancer, 5.8-6.3 parts of an auxiliary, 3.3-4.8 parts of polyvinyl alcohol, 4.3-5.4 parts of dodecylbenzene sulfonic acid and 23-28 parts of water. The Gemini composite surfactant for oildisplacement has excellent comprehensive performance, can remarkably reduce surface tension and is good in surface activity and oil displacement efficiency, and recovery efficiency of crude oil is improved.

Description

technical field [0001] The invention relates to the technical field of surfactants, in particular to a Gemini composite surfactant for oil displacement and a preparation method thereof. Background technique [0002] For ordinary oil reservoirs, there are large-scale products of surfactant oil displacement agents, and ideal effects have been achieved in enhancing oil recovery. However, with the development of oil exploration in the direction of low permeability, deep wells and complex and difficult conditions, mining is also developing in the direction of high temperature, high salt and low permeability. The successful application of surfactants in ordinary oil reservoirs, under the conditions of high temperature and high salinity, due to the easy change of the structure of the chemical agent, the existing oil displacement agents cannot achieve the desired effect, which limits the development of oil. [0003] At present, in oil extraction, the commonly used surfactants are p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/584
Inventor 陈海玲宋伟
Owner NANYANG INST OF TECH
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