A kind of preparation method of current collector for lithium ion battery

A lithium-ion battery, current collector technology, applied in battery electrodes, electrode carriers/current collectors, circuits, etc., can solve the problems of reducing the internal resistance and polarization of the battery, unable to improve the lithium ion transmission speed of the lithium battery, and limited effect, etc. Achieve the effect of improving the transmission characteristics and improving the lithium ion transmission characteristics

Active Publication Date: 2019-01-01
中国东方电气集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The method adopted in the above-mentioned patent is similar to the mainstream gravure printing method in the lithium battery industry. It is to coat a layer of conductive material on the current collector to improve the conductivity. This method can be used to make up for the lack of conductivity of the positive active material itself. , it can improve its conductivity to a certain extent, but it can only increase the transmission speed of electrons, but cannot increase the transmission speed of lithium ions inside the lithium battery, and has a limited effect on reducing the internal resistance and polarization of the battery.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Prepare polyoxometalate lithium salt solution and aniline monomer solution at a molar ratio of 1:4, cover one side of the current collector aluminum foil with insulating tape, connect the other side to the negative pole of the DC power supply, connect the positive pole of the DC power supply to the counter electrode, and connect the The two electrodes are placed in the prepared conductive polymer monomer solution, and the prepared lithium polyoxometalate Li 3 PMo 12 o 40 The solution was slowly added to the aniline solution drop by drop, and at the same time, the DC power switch was turned on, and the power was turned on. The current was 0.5mA, and the voltage range was 1.5V. It was reacted at room temperature for 16 hours, and then the current collector after electroplating was repeatedly washed with distilled water and alcohol until the filtrate Until it is colorless, put the electroplated current collector in a vacuum drying oven at 40-200°C for 2-10 hours and set i...

Embodiment 2

[0022] Prepare lithium polyoxometalate lithium phosphotungstate Li at a molar ratio of 1:3 3 PW 12 o 40 solution and pyrrole monomer solution, one side of the current collector aluminum foil is covered with insulating tape, the other side is connected to the negative pole of the DC power supply, the positive pole of the DC power supply is connected to the opposite electrode, and the two electrodes are placed in the prepared conductive polymer monomer solution. Replace the prepared lithium polyoxometalate with lithium phosphotungstate Li 3 PW 12 o 40 Slowly add the solution to the pyrrole solution drop by drop, and at the same time turn on the DC power switch, start to energize, the current is 50mA, the voltage range is 5V, react at room temperature for 8-10 hours, and then wash the electroplated current collector repeatedly with distilled water and alcohol until the filtrate Until it is colorless, put the electroplated current collector in a vacuum drying oven at 40-200°C ...

Embodiment 3

[0025] According to the molar ratio of 1:9, lithium polyoxometalate lithium silicotungstate Li was prepared respectively 4 SiW 12 o 40 solution and pyrrole monomer solution, one side of the current collector aluminum foil is covered with insulating tape, the other side is connected to the negative pole of the DC power supply, the positive pole of the DC power supply is connected to the opposite electrode, and the two electrodes are placed in the prepared conductive polymer monomer solution. Replace the prepared lithium polyoxometalate with lithium silicotungstate Li 4 SiW 12 o 40 The solution is slowly added to the pyrrole solution drop by drop, and at the same time turn on the DC power switch, start to energize, the current is 100mA, the voltage range is 10V, react at room temperature for 8-10 hours, and then wash the electroplated current collector repeatedly with distilled water and alcohol until the filtrate Until it is colorless, put the electroplated current collecto...

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PUM

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Abstract

The invention discloses a preparation method of a current collector for a lithium ion battery. The preparation method comprises the following steps: (1) polyoxometallic acid lithium salt solution and conductive polymer monomer solution are respectively prepared according to a mole ratio of 1: (1-9); (2) one surface of an aluminum foil is covered with insulation cloth, and the other surface is connected with a negative electrode of a direct-current power supply; a positive electrode of the direct-current power supply is connected with a counter electrode; and the two electrodes are put in the prepared conductive polymer monomer solution; and (3) the direct-current power supply is switched on for electrifying; the prepared polyoxometallic acid lithium salt solution is added in the conductive polymer monomer solution for reaction by 1-24 hours at room temperature; the electroplated aluminum foil is washed by using distilled water and alcohol; and then, the washed aluminum foil is put in a 40-200 DEG C drying box for drying by 2-10 hours to obtain the current collector. The lithium ion transmission characteristics are improved, and the electron transmission characteristics are improved through conductive polymers, so that the dual requirements of composite materials on lithium ion transmission and electron transmission are met.

Description

technical field [0001] The invention relates to the technical field of lithium batteries, in particular to a method for preparing a current collector for lithium ion batteries. Background technique [0002] Lithium battery, as an effective energy conversion and energy storage device, has attracted much attention since its invention. Its characteristics of high working voltage, high energy density, high specific energy, high specific power, stable discharge, and no memory effect are widely used in Various electronic products. Although lithium batteries have achieved great success in 3C products, they are still in their infancy in the fields of power applications and energy storage. The key factor restricting their development is composite materials. At present, the cathode materials mainly used in the fields of power and energy storage are Lithium iron phosphate, lithium iron phosphate has the advantages of thermal stability and safety compared with other positive electrode ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D9/02C25D7/00H01M4/66
CPCC25D7/00C25D9/02H01M4/661H01M4/667Y02E60/10
Inventor 廖小东王瑨黄兴兰
Owner 中国东方电气集团有限公司
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