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Waterborne highlight environment-friendly toughened glass ink and preparation method thereof

A glass ink and high-brightness technology, applied in ink, household utensils, applications, etc., can solve problems such as large environmental damage, and achieve the effects of prolonging the service life of equipment, reducing low-temperature viscosity, and environmental protection costs

Active Publication Date: 2017-06-09
郑州市亚美凯新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Traditional tempered glass inks are obtained by dissolving resins with varnishes such as xylene, cyclohexanone, and isophorone. This varnish contains a large amount of toxic and volatile solvents, which is harmful to people and the surrounding environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A water-based high-brightness environment-friendly tempered glass ink is characterized in that it is made of the following raw materials in parts by weight: 25 parts of inorganic pigments, 50 parts of low melting point frit, 23 parts of varnish, and 0.5 parts of wetting and dispersing agent , 0.5 part of defoamer, 1 part of solid additive. The solid additive is P 2 o 5 .

[0024] The inorganic pigment is copper chrome black (Hunan Jufa Technology Co., Ltd., B2856).

[0025] The low melting point frit is composed of the following components by weight percentage: SiO 2 35.2%, B 2 o 3 3.2%, TeO 2 3%, Al 2 o 3 1%, Na 2 O 14.2%, K 2 O 2.1%, CaO 3.8%, 3.6%, Li 2 O 1.1%, TiO 2 0.5%, F 3%, Sb 2 o 3 1%, ZrO 2 0.3%, the balance is ZnO.

[0026] Described varnish is made up of the composition of following percentage by weight: 25% water-based modified thermosetting acrylic resin Joncryl ® 678 (BASF), 25% hydroxyethylcellulose HBR250 (Ashlane), 14.6% ethanol, 8% bu...

Embodiment 2

[0035] A water-based high-brightness environment-friendly tempered glass ink is characterized in that it is made of the following raw materials in parts by weight: 25 parts of inorganic pigments, 50 parts of low melting point frit, 23.2 parts of varnish, and 0.5 parts of wetting and dispersing agent , 0.5 parts of defoamer, 0.05-2 parts of leveling agent, 0.8 parts of solid additive. The solid additive is P 2 o 5 .

[0036] The inorganic pigment is iron chromium brown (Hunan Jufa Technology Co., Ltd., A2901).

[0037] The low melting point frit is composed of the following components by weight percentage: SiO 2 42.3%, B 2 o 3 6.2%, TeO 2 1%, Al 2 o 3 1%, Na 2 O 10.2%, K 2 O 2.1%, CaO 3.8%, BaO 3.7%, Li 2 O 2.3%, TiO 2 0.5%, F 1.8%, P 2 o 5 0.2%, the balance is ZnO.

[0038] Described varnish is made up of the composition of following percentage by weight: 10% water-based modified thermosetting acrylic resin Joncryl ® 678 (BASF), 30% water-based hydroxyethylcell...

Embodiment 3

[0047] A water-based high-brightness environment-friendly tempered glass ink is characterized in that it is made of the following raw materials in parts by weight: 25 parts of inorganic pigments, 50 parts of low melting point frit, 23 parts of varnish, and 0.5 parts of wetting and dispersing agent , 0.5 part of defoamer, 1 part of solid additive. The solid additive is P 2 o 5 .

[0048] The inorganic pigment is titanium nickel yellow (10401 of Fluor New Materials Co., Ltd.).

[0049] The low melting point frit is composed of the following components by weight percentage: SiO 2 32.2%, B 2 o 3 8.2%, TeO 2 0.08%, Al 2 o 3 3.5%, Na 2 O 12.6%, K 2 O 2.1%, CaO 3.8%, BaO 7.2%, Li 2 O 2.3%, TiO 2 0.8%, F 3%, NiO 0.6%, and the balance is ZnO.

[0050] Described varnish is made up of the composition of following percentage by weight: 15% water-based modified thermosetting acrylic resin Joncryl ® 678 (BASF), 25% water-based hydroxyethylcellulose HBR250 (Ashlane), 15% ethano...

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PUM

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Abstract

The invention belongs to waterborne highlight environment-friendly toughened glass ink and a preparation method thereof. The toughened glass ink is prepared from, by weight, 8-30 parts of inorganic pigments, 30-78 parts of a low-melting-point frit, 10-55 parts of ink abrasive oil, 0-2 parts of a wetting dispersant, 0-1 part of a defoamer, 0-2 parts of a flatting agent and a 0-2 parts of a solid additive. The glass ink is low in melting point, good in weather fastness, good in brightness and high in artistic appreciation; the low-melting-point frit is low in melting temperature and power saving, service life of the device can be effectively prolonged, and oxide is less volatile; the low-melting-pint frit does not contain Pb, Cr<6+>, Cd and Bi, cost of the ink can be effectively reduced, and harmful Pb, Cd and Cr<6+> are not contained; a Te element is introduced in the low-melting-point frit which can reduce the melting temperature, low-temperature viscosity of the frit is effectively reduced, and high covering power and anti-ultraviolet linear capacity of the glass are achieved.

Description

technical field [0001] The invention belongs to the field of chemical inks, and in particular relates to a water-based high-brightness environment-friendly tempered glass ink and a preparation method thereof. Background technique [0002] As we all know, glass tempered ink should have low sintering temperature, good weather resistance, excellent hiding power and good visual effect and other properties. However, traditional tempered inks contain lead and cadmium, or add a large amount of high-cost bismuth oxide. Oxide melting in traditional frits needs to be carried out at above 1200°C. Higher melting temperatures require more power consumption and greater damage to melting equipment, which greatly reduces its service life. At high temperature, oxides volatilize more, and many oxide vapors are poisonous, which will also cause greater damage to the health of operators. The present invention adopts 800°C-1000°C melting process, which is more low-carbon and environment-friendl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/033C09D11/037C09D11/03C09D11/107C09D11/14C09D11/30C09D11/32C09D11/36C09D11/38
CPCC09D11/03C09D11/033C09D11/037C09D11/107C09D11/14C09D11/30C09D11/32C09D11/36C09D11/38
Inventor 杨中民周岩何宜刚
Owner 郑州市亚美凯新材料有限公司
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