Easily-degradable anti-shrinkage polypropylene master batch and preparation method thereof

A polypropylene, anti-shrinkage technology, applied in the field of polypropylene masterbatch

Inactive Publication Date: 2017-05-17
NINGXIA YANCHI WEST CHANGXIANG AGRI BIOTECH
View PDF4 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The technical problem solved by the present invention is to overcome the defects of the existing polypropylene masterbatch and its preparation method, use polypropylene as the base material, optimize the type and formula of the masterbatch raw material, improve the production process, and scientifically compound the compound containing biological antioxidant Antioxidant; modified nano-carbon that can significantly improve the high temperature resistance and shrinkage resistance of polypropylene masterbatch, relative tensile load, strength, toughness and elastic modulus; can significantly improve the impact resistance of polypropylene masterbatch and is easy to biodegrade , calcium fruit fiber that reduces production costs; polyethylene / winter rye peptide compound that can greatly improve the low temperature resistance of polypropylene masterbatch; bitter almond oil that can effectively improve the lubricity and oxidation resistance of polypropylene masterbatch; and other The synergistic effect of processing aids finally produces an environmentally friendly, easily degradable and shrink-resistant polypropylene masterbatch with good physical properties;

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Easily-degradable anti-shrinkage polypropylene master batch and preparation method thereof
  • Easily-degradable anti-shrinkage polypropylene master batch and preparation method thereof
  • Easily-degradable anti-shrinkage polypropylene master batch and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] Embodiment 1 raw material preparation

[0050] 1. Preparation of calcium fruit fiber:

[0051] The preparation method of the calcium fruit fiber comprises the following steps: uniformly mixing fresh calcium fruit stems, calcium fruit leaves and waste sawdust at a mass ratio of 7:4:1.5, placing them in an ultrasonic cleaning machine at 200W and 30KHz for cleaning for 4 minutes, draining Drying, crushing, adding water with 1 times the amount of the crushed material, ultrasonic extraction at room temperature 300W, 40KHz for 12min, and then performing high-voltage pulse electric field treatment for 12min under the conditions of electric field strength 30kV / cm, pulse time 500μs, and pulse frequency 300Hz; adjust the pH value 8. Add biological enzyme with 0.2% mass of the mixture, and enzymatically hydrolyze at 55°C for 12 minutes; the enzymolyzed solution is concentrated under reduced pressure to a solid content of 50%, and placed in a microwave dryer at 2000W and 140°C for ...

Embodiment 2

[0073] An easily degradable, shrink-resistant polypropylene masterbatch, mainly prepared from the following raw materials in parts by weight:

[0074] 40 parts of polypropylene, 18 parts of calcium fruit fiber, 9 parts of polyethylene / winter rye peptide complex, 9 parts of modified nano-carbon, 2 parts of ultraviolet absorber, 2 parts of ethylene-methyl acrylate copolymer, 1 part of anti-aging agent 1 part, 1 part of tributyl citrate, 1 part of coupling agent, 0.8 part of bitter almond oil, 0.4 part of composite antioxidant;

[0075] Described composite antioxidant is that antioxidant 1010, antioxidant 168 and biological antioxidant are uniformly mixed by mass ratio 1.5:2:3;

[0076] The ultraviolet absorber is UV-531;

[0077] The ethylene-methyl acrylate copolymer uses American DuPont EMA1125AC.

[0078] The preparation method comprises the following steps: first, accurately weigh each raw material according to the formula, and according to the principle of the equal-incre...

Embodiment 3

[0080] An easily degradable, shrink-resistant polypropylene masterbatch, mainly prepared from the following raw materials in parts by weight:

[0081] 30 parts of polypropylene, 17 parts of calcium fruit fiber, 8 parts of polyethylene / winter rye peptide complex, 8 parts of modified nano-carbon, 1 part of ultraviolet absorber, 1.5 parts of ethylene-methyl acrylate copolymer, 0.8 parts of anti-aging agent part, 0.8 part of tributyl citrate, 0.8 part of coupling agent, 0.6 part of bitter almond oil, 0.3 part of composite antioxidant;

[0082] Described composite antioxidant is that antioxidant 1010, antioxidant 168 and biological antioxidant are uniformly mixed in a mass ratio of 1:1:2;

[0083] The ultraviolet absorber is UV-531;

[0084] The ethylene-methyl acrylate copolymer is preferably US DuPont EMA1125AC.

[0085] The preparation method comprises the following steps: first, accurately weigh each raw material according to the formula, and according to the principle of the...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses an easily-degradable anti-shrinkage polypropylene master batch, wherein polypropylene serves as a base material, the types and the formula of the master batch are optimized, and a production process is improved. A complex antioxidant which contains a biologic antioxidant, modified nanocarbon which can obviously improve high temperature resistance, shrinkage resistance, relative tensile load, strength and toughness and elasticity modulus of the polypropylene master batch, calcium fruit fibers which can obviously improve shock resistance of the polypropylene master batch, are easily biodegradable and lower production cost, polyethylene / winter rye peptide complexes which can greatly improve low temperature resistance of the polypropylene master batch and bitter almond oil which can effectively improve lubricating property and oxidation resistance of the polypropylene master batch are scientifically compounded; the obtained compound has a synergistic effect with other processing aids; finally, the environment-friendly easily-degradable anti-shrinkage polypropylene master batch with good physical property is obtained.

Description

technical field [0001] The invention relates to a polypropylene masterbatch, in particular to an easily degradable and shrink-resistant polypropylene masterbatch and a preparation method thereof. Background technique [0002] Polypropylene is a general-purpose plastic with good comprehensive properties, and its total output has surpassed polyvinyl chloride to become the second largest general-purpose plastic after polyethylene. Main features: non-toxic, odorless, low density, strength, stiffness, hardness and heat resistance are superior to low-pressure polyethylene, high bending fatigue resistance, can be used at about 100 degrees. It has good electrical properties and high frequency Insulation is not affected by humidity, but becomes brittle at low temperature, not wear-resistant, and easy to age. Because of its notch sensitivity, low heat distortion temperature, large molding shrinkage, poor hardness and wear resistance, its application in product packaging, automobiles,...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L23/12C08L97/02C08L23/06C08L23/08C08L91/00C08K13/06C08K9/02C08K7/06C08K7/24C08K5/11C08K5/134C08K5/526C08H8/00C12N1/16C12P21/06C07K5/02C12R1/865
CPCC08L23/12C07K5/0215C08H8/00C08L2201/06C08L2201/08C08L2205/02C08L2205/035C12N1/16C12P21/06
Inventor 李建树
Owner NINGXIA YANCHI WEST CHANGXIANG AGRI BIOTECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap