Mildew-resistant paperboard coating based on attapulgite modification and preparing method thereof
A technology of attapulgite and soil reform, applied in the field of coatings, can solve problems such as product quality decline, reduction of carton mechanical strength, and damage to the waterproof effect of the coating layer.
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[0015] The invention provides a method for preparing an attapulgite-modified anti-mildew cardboard coating, comprising:
[0016] 1) The process of decocting Chinese herbal medicines in water to obtain Chinese herbal medicine extracts;
[0017] 2) In the presence of ultraviolet rays, the process of activating attapulgite, plant ash, sodium chloroplatinate and molybdenum disulfide to obtain an activated product;
[0018] 3) Under acidic conditions, the process of mixing the activator with the amino acid and performing modification treatment to obtain the modified activator;
[0019] 4) Conduct a contact reaction of acrylic emulsion, polystyrene, dioctyl phthalate, aluminum oxide, boron nitride and sodium nitrite, and then add emulsifiers, modified activators, and Chinese herbal medicine extracts to the reaction system Liquid is mixed to make the process of anti-mold cardboard coating based on attapulgite modification;
[0020] Among them, Chinese herbal medicines include mugwo...
Embodiment 1
[0033] 1) Take mugwort leaves, bamboo leaves, borneol, Yubaifu, chuanxiong, scallion, angelica, kudzu root, melon skin, coptis, water according to 100:52:48:40:29:78:39:25:36:95: 700 weight ratio, and decocted at 160°C for 5 hours to obtain Chinese herbal medicine extract;
[0034] 2) In the presence of ultraviolet light with a wavelength of 230nm, attapulgite, plant ash, sodium chloroplatinate and molybdenum disulfide were mixed in a weight ratio of 100:58:22:36, and activated at 80°C for 14 hours to obtain activated thing;
[0035] 3) Under the condition of pH 5, the activated substance was mixed with amino acid (weight ratio 100:55) and modified at 55°C for 8 hours to obtain the modified activated substance;
[0036] 4) Mix acrylic emulsion, polystyrene (weight-average molecular weight: 5000), dioctyl phthalate, aluminum oxide, boron nitride and sodium nitrite, and mix them at 100°C and a vacuum of 8MPa The contact reaction was carried out at low temperature for 1.5h, and...
Embodiment 2
[0039] 1) Take mugwort leaves, bamboo leaves, borneol, Yubaifu, chuanxiong, scallion, angelica, kudzu root, melon skin, coptis, water according to 100:47:42:38:24:74:36:22:29:88: 400 weight ratio mixed, and decocted at 150 ° C for 4 hours to obtain the Chinese herbal medicine extract;
[0040] 2) In the presence of ultraviolet rays with a wavelength of 200nm, attapulgite, plant ash, sodium chloroplatinate and molybdenum disulfide were mixed in a weight ratio of 100:55:14:32, and activated at 75°C for 12 hours to obtain activated thing;
[0041]3) Under the condition of pH 4, the activated substance was mixed with amino acid (weight ratio 100:47) and then modified at 50°C for 6 hours to obtain the modified activated substance;
[0042] 4) Mix acrylic emulsion, polystyrene (weight-average molecular weight: 3000), dioctyl phthalate, aluminum oxide, boron nitride and sodium nitrite, and mix them at 95°C and a vacuum of 5MPa The contact reaction was carried out for 1 hour, and th...
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