Preparation method for textile fiber/graphene/Ag3PO4 composite environment catalysis material

Abstract

The invention relates to a preparation method for a textile fiber / graphene / Ag3PO4 composite environment catalysis material. The preparation method comprises the following steps: dipping textile fibers in a saturated solution of graphene oxide, then drying the textile fibers, cleaning the textile fibers, placing the textile fibers in a solution of a reducing agent, carrying out a reaction at 50 to 80 DEG C for 0.5 to 1 h and then successively carrying out cleaning and drying so as to obtain textile fiber / graphene; and adding the textile fiber / graphene into a AgNO3 solution, carrying out stirring, then adding Na3PO4 and urea, carrying out a hydrothermal reaction at 120 to 180 DEG C for 3 to 8 h and successively carrying out cooling, cleaning and drying so as to obtain the textile fiber / graphene / Ag3PO4 composite environment catalysis material. The preparation method provided by the invention is simple and is suitable for industrial production; and the obtained textile fiber / graphene / Ag3PO4 composite environment catalysis material has good environment purifying effect.

Description

technical field [0001] The invention belongs to the field of preparation of environmental catalytic materials, in particular to a textile fiber / graphene / Ag 3 PO 4 A method for preparing a composite environmental catalytic material. Background technique [0002] Environmental resources are an important basis for the survival and development of human society. The governance and protection of the environment has been running through the history of the development of human industrial society and is directly related to the sustainable development of human society. Water shortage is an important issue facing society today, and the treatment of industrial wastewater has always been the top priority in the environmental field. In recent years, the treatment of some low-concentration toxic pollutants in actual wastewater, such as conjugated dyes, chlorinated aromatic compounds, polybrominated diphenyl ethers, antibiotics, etc., has become the focus of international research. Adsor...

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Problems solved by technology

Adsorption and biological treatment are commonly used in industry. The adsorption method only transfers toxic pollutants from the liquid phase to the solid phase, but does not completely eliminate organic pollutants. The biological treatment cycle is long and the equipment occupies a large area. Biological toxicity can not be effectively removed

In contrast, advanced oxidation technologies can directly degrade dyes and other organic substances by producing strong oxidizing active species, and even completely mineralize them, which has attracted widespread attention. However, these advanced oxidation technologies also have certain limitations, such as easy to bring Secondary pollution, high treatment cost, unsuitable for large-flow wastewater treatment, and the priority removal of toxic target pollutants in the presence of a large number of organic / inorganic compounds is quite difficult, so it is very difficult to design and develop an efficient removal of toxic target pollutants in actual wastewater systems The catalytic system is of great significance

[0003] In order to construct high-efficiency micro-nano structures on the surface of textile fibers and overcome the adverse effects of the use of adhesives on the performance of catalytic fibers, the researchers tried to use the sol-gel finishing method to prepare catalytic functional fibers. The research results showed that the catalytic fibers prepared by this method The fiber has certain catalytic properties, but there are the following problems: (1) the curing of the gel must be carried out at high temperature, which has an impact on the physical and mechanical properties of the textile fiber, such as a large loss of tear strength; (2) the sol- The gel method prepares an amorphous nano-photocatalyst with no photocatalytic performance, so it needs to be converted to the desired crystal form through a certain way, and the crystallinity of the crystal phase needs to be improved to reduce lattice defects; (3) high temperature Sintering is currently the most common method for transforming from amorphous phase to fixed shape and increasing crystallinity, but the calcination temperature generally needs to be 300°C or above to achieve it. Obviously, conventional textile fibers cannot withstand such a high temperature. This is the sol-gel method. Common problems when applied to organic-loaded substrates; (4) direct contact between photocatalysts and fibers will cause photooxidative degradation of fibers, resulting in a decrease in the physical and mechanical properties of textile fibers

The low-temperature method is to use the precursor as the precursor to prepare a stable sol through sol-gel technology, and then synthesize it on the surface of the fiber in situ, and realize the transformation of the nano-photocatalyst from the amorphous state to the fixed state on the fiber in boiling water at 100 ° C. The catalytic functional fiber prepared by the method has good net performance and is convenient to use, but there are problems such as textile fiber being degraded by photooxidation and large loss of strength.

Improving the photocatalytic performance by further increasing the loading of metal oxides on fiber materials will cause serious agglomeration of metal oxides, affect the effective specific surface area available for catalytic materials, and change the porous structure of textile fibers / metal oxide materials. , which is not conducive to the enrichment of organic pollutants on the surface of fiber materials, and will also affect the catalytic performance of catalytic materials

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