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Preparation method of modified polypropylene nano fiber and oil absorption felt made from modified polypropylene nano fiber

A technology of nanofibers and polypropylene, applied in the direction of single-component polypropylene artificial filaments, fiber chemical characteristics, chemical instruments and methods, etc., can solve the problems of high device requirements, high cost, and high conductivity requirements of solutions, and achieve Good application prospect, strong oil absorption rate, easy to manufacture effect

Inactive Publication Date: 2015-12-09
深圳市东城绿色投资有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Melt-blown technology is currently the largest ultra-fine fiber manufacturing method, which relies on high-speed, high-temperature airflow (often close to the melting point of the polymer) to blow the polymer melt to make it stretch rapidly to obtain ultra-fine fibers. The diameter of sprayed fibers is mostly between 2 and 4 μm, and there are still some difficulties in the preparation of nanoscale fibers
The researchers tried various methods to further reduce the fiber diameter, but the Rayleigh-Taylor instability caused by surface tension occurred in the nanofibers during the melt-blowing process, which caused the fibers to break into spherical particles, and the pure polypropylene melt-blown method prepared nanofibers. The diameter limit has its own theoretical limit
Using the template method to prepare polypropylene fiber has complicated operation steps, high cost, and short length of the prepared fiber, which is only suitable for theoretical research in the laboratory, not suitable for industrial production
The electrospinning method requires thousands of volts or even tens of thousands of volts of direct current high voltage, which requires high conductivity of the solution. Polypropylene is a non-polar polymer with poor spinnability, and there is no suitable solvent at room temperature. High-temperature melt electrospinning has high requirements for devices, which greatly limits its industrial application prospects

Method used

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  • Preparation method of modified polypropylene nano fiber and oil absorption felt made from modified polypropylene nano fiber
  • Preparation method of modified polypropylene nano fiber and oil absorption felt made from modified polypropylene nano fiber
  • Preparation method of modified polypropylene nano fiber and oil absorption felt made from modified polypropylene nano fiber

Examples

Experimental program
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Effect test

Embodiment 1

[0048](1) high-speed premixing of island phase polymer polypropylene, marine phase polymer polylactic acid and inorganic nanomaterial nano calcium carbonate, wherein the mass fraction of polypropylene is 5%, and the inorganic nano material nano calcium carbonate mass fraction is 0.01%, The balance is marine phase polymer polylactic acid;

[0049] (2) The mixture is melt-extruded and directly cooled and granulated in the air;

[0050] (3) the masterbatch in step (2) is produced with melt-blown equipment to obtain superfine composite fibers;

[0051] (4) Dissolving and removing the marine phase polymer in the ultrafine composite fiber with a solvent, and obtaining the modified polypropylene nanofiber after drying.

Embodiment 2

[0053] (1) high-speed premixing of island phase polymer polypropylene, marine phase polymer polylactic acid and inorganic nanomaterial nano calcium carbonate, wherein the mass fraction of polypropylene is 5%, and the inorganic nano material nano calcium carbonate mass fraction is 0.01%, The balance is marine phase polymer polylactic acid;

[0054] (2) The mixture is melt-extruded and directly cooled and granulated in the air;

[0055] (3) the masterbatch in step (2) is produced with melt-blown equipment to obtain superfine composite fibers;

[0056] (4) Dissolving and removing the marine phase polymer in the ultrafine composite fiber with a solvent, and obtaining the modified polypropylene nanofiber after drying.

Embodiment 3

[0058] (1) high-speed premixing of island phase polymer polypropylene, marine phase polymer polylactic acid and inorganic nanomaterial nano-calcium carbonate, wherein the massfraction of polypropylene is 15%, and the inorganic nanomaterial nano-calcium carbonate massfraction is 2%, The balance is marine phase polymer polylactic acid;

[0059] (2) The mixture is melt-extruded and directly cooled and granulated in the air;

[0060] (3) the masterbatch in step (2) is produced with melt-blown equipment to obtain superfine composite fibers;

[0061] (4) Dissolving and removing the marine phase polymer in the ultrafine composite fiber with a solvent, and obtaining the modified polypropylene nanofiber after drying.

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Abstract

At present, a large-scale polypropylene fiber production process mainly comprises melt spinning and melt blowing, and the diameter of melt-spun polypropylene fiber ranges from 10 mu m to 20 mu m or is thicker. The melt blowing technique is the superfine fiber manufacturing method most commonly used at present, a polymer melt is blown by air flow with high temperature approaching a polymer melting point at a high speed, so that the polymer melt is quickly stretched, and superfine fiber is obtained. However, the diameter of most existing melt-blown fiber ranges from 2 mu m to 4 mu m, and preparation of the polypropylene nano fiber is still difficult. The preparation method of the modified polypropylene nano fiber and the oil absorption felt made from the modified polypropylene nano fiber have the characteristics of simplicity in manufacturing, convenience in use, high oil absorption rate, easiness in recycling and the like.

Description

technical field [0001] The invention relates to the field of oil pollution treatment, in particular to a modified polypropylene nanofiber preparation process and an oil-absorbing felt. technical background [0002] Usually, during the processing and transportation of oil, a considerable amount of oil will be leaked and discarded, which not only wastes limited resources, but also poses a great threat to the environment. It is very difficult to remove oil pollution. At present, the control of oil pollution in the world is divided into chemical methods and physical methods. [0003] Chemical method: According to the pollution situation, use emulsification dispersion, oil collection or oil coagulation method to control. For oil films with a thickness of less than 1mm, it is effective to use chemical dispersants to clean up oil stains, but chemical cleaning methods need to consume a lot of chemicals and may cause secondary pollution. [0004] Physical method: It is the most com...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F1/10D01F6/06B01J20/28B01J20/30
Inventor 黄国铭
Owner 深圳市东城绿色投资有限公司
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