Light-transmitting, breathable and static electricity repellent PM2.5 air filter membrane and preparation method thereof
A PM2.5 and air filtration technology, applied in semi-permeable membrane separation, chemical instruments and methods, membrane technology, etc., can solve problems such as unfavorable human health, achieve high-efficiency electrostatic repulsion, increase transparency, and increase retention rate Effect
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[0026]Preparation of ultra-thin electrospun nanofiber layer: dissolving polymer powder in a polar organic solvent to obtain a polymer solution, wherein the polymer powder is polyethersulfone, polysulfone, polyvinyl alcohol, polyethylene oxide, At least one of polylactic acid, polyacrylonitrile, polyurethane, polyethylene, polyamide, and polystyrene, and the polar organic solvent is N,N-dimethylformamide, N,N-dimethylacetamide Any one of amides, N-methylpyrrolidone, and dimethyl sulfoxide or a combination thereof.
[0027] The polymer solution is degassed in vacuum to obtain a spinning solution.
[0028] The nanofiber film layer is obtained by electrospinning with non-woven fabric or screen mesh as the collecting matrix. The temperature of the spinning solution is 10-50°C, the ambient temperature is 5-45°C, the relative humidity is 20-60%, the spinning voltage is 5000-30000V, the distance from the spinneret to the receiving plate is 8-20cm, and the barrel extrusion The output...
Embodiment 1
[0034] Electrospinning is carried out on the surface of PP non-woven fabric with polyurethane as material, and the weight of PP is 20g / m 2 .
[0035] Specifically, a certain mass of polyurethane (PU) was dissolved in N,N-dimethylacetamide DMAc (5-30% by mass), stirred at 60°C to obtain a polymer solution, and the polymer solution was Vacuum defoaming at 60° C. for 4 hours to prepare spinning solutions, and make spinning solutions with different concentrations.
[0036] Electrospinning was carried out under the following conditions: the temperature of the spinning solution was 30 °C, the ambient temperature was 50 °C, the relative humidity was 20%, the receiving distance was 11 cm, the barrel extrusion rate was 25 μL / min, and the negative voltage was -3 kV, the positive voltage is 9.03 ~ 9.08 kV.
[0037] Disperse the tourmaline powder in the aqueous solution of acrylic acid by using an ultrasonic cell pulverizer in proportion to obtain a suspension containing tourmaline nano...
Embodiment 2
[0039] Electrospinning is carried out on the surface of PET screen with polyacrylonitrile as the material. The fineness of the single filament of the screen is 500dtex, and the mesh number is 40 mesh.
[0040] Specifically, a certain mass of polyacrylonitrile (PAN) was dissolved in DMAc (5-30% by mass), stirred at 80°C to obtain a polymer solution, and the polymer solution was vacuum defoamed at 80°C The spinning solution was obtained in 4 hours, and the spinning solution with different concentrations was prepared, and electrospinning was carried out under the following conditions: the temperature of the spinning solution was 40°C, the ambient temperature was 60°C, the relative humidity was 20%, and the receiving distance was 10°C. cm, the barrel extrusion rate is 30 μL / min, the negative voltage is -3 kV, and the positive voltage is 9.39 kV.
[0041] Disperse the tourmaline powder in an aqueous solution of acrylic acid by using an ultrasonic cell pulverizer in proportion to ob...
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