ABS (Acrylonitrile Butadiene Styrene) modified resin with high hardness, flame retardance and antistatic property

A technology of flame retardant and antistatic ABS resin, which is applied in the field of high hardness flame retardant and antistatic ABS modified resin, can solve the problems of low strength, weak flame retardant and heat resistance, poor surface gloss, etc., and achieve broad application prospects , Low production cost, and the effect of improving wear resistance

Inactive Publication Date: 2015-07-29
宣海成
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current ABS resin plastic still has the disadvantages of low strength, poor surface abrasion resistance, poor flame retardancy and heat resistance in extreme cases, and poor surface gloss.
At the same time, ABS resin is very easy to generate static electricity accumulation when it is in contact with other surfaces, resulting in vacuuming, electric shock, discharge and ignition, which will cause distortion of precision instruments, short-circuit scrapping of electronic components, fire and explosion accidents, which will bring great importance to industrial production and scientific research. loss

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] A high-hardness flame-retardant antistatic ABS modified resin, consisting of the following components by weight:

[0046] ABS resin 80 parts

[0047] 8 parts polyimide fiber

[0048] 15 parts of p-diazodiphenylamine paraformaldehyde condensate

[0049] Polyisocyanate block 5 parts

[0050] Silicone modified polyurethane resin 15 parts

[0051] 10 parts of 6-ethoxy-2,2,4-trimethyl-1,2-dihydroquinoline

[0052] Dimethyl styrylpyridine sulfate 3 parts

[0053] 2 parts isobutyraldehyde

[0054] Curing agent 8 parts

[0055] Dipropylene glycol dimethyl ether 1 part

[0056] 1 part polyvinyl butyral

[0057] Antistatic agent 7 parts

[0058] Zinc ferrite 8 parts

[0059] 0.2 parts of 4-tert-butylcyclohexanone

[0060] Cyclododecanone 0.2 parts

[0061] Barium sulfate 10 parts

[0062] 1,2,3,4-cyclopentane tetracarboxylic acid 8 parts

[0063] 10 parts of deionized water;

[0064] Described antistatic agent comprises following raw material by weight fraction:

...

Embodiment 2

[0078] A high-hardness flame-retardant antistatic ABS modified resin, consisting of the following components by weight:

[0079]ABS resin 100 parts

[0080] 20 parts polyimide fiber

[0081] 30 parts of p-diazodiphenylamine paraformaldehyde condensate

[0082] Polyisocyanate block 15 parts

[0083] Silicone modified polyurethane resin 25 parts

[0084] 20 parts of 6-ethoxy-2,2,4-trimethyl-1,2-dihydroquinoline

[0085] Dimethyl styrylpyridine sulfate 6 parts

[0086] 8 parts of isobutyraldehyde

[0087] Curing agent 12 parts

[0088] Dipropylene glycol dimethyl ether 4 parts

[0089] 4 parts polyvinyl butyral

[0090] Antistatic agent 15 parts

[0091] 4 parts of N-methylpyrrolidone

[0092] Zinc ferrite 10 parts

[0093] Diketopyrrolopyrrole pigment 10 parts

[0094] 0.5 parts of 4-tert-butylcyclohexanone

[0095] Cyclododecanone 0.5 parts

[0096] 5 parts gamma-butyrolactone

[0097] Barium sulfate 15 parts

[0098] 1,2,3,4-cyclopentane tetracarboxylic acid 16...

Embodiment 3

[0114] A high-hardness flame-retardant antistatic ABS modified resin, consisting of the following components by weight:

[0115] ABS resin 90 parts

[0116] 10 parts polyimide fiber

[0117] 20 parts of p-diazodiphenylamine paraformaldehyde condensate

[0118] Polyisocyanate block 10 parts

[0119] Silicone modified polyurethane resin 20 parts

[0120] 15 parts of 6-ethoxy-2,2,4-trimethyl-1,2-dihydroquinoline

[0121] Dimethyl styrylpyridine sulfate 5 parts

[0122] 6 parts of isobutyraldehyde

[0123] Curing agent 10 parts

[0124] Dipropylene glycol dimethyl ether 2 parts

[0125] 3 parts polyvinyl butyral

[0126] Antistatic agent 10 parts

[0127] N-Methylpyrrolidone 2 parts

[0128] Zinc ferrite 9 parts

[0129] Diketopyrrolopyrrole pigment 9 parts

[0130] 0.3 parts of 4-tert-butylcyclohexanone

[0131] Cyclododecanone 0.4 parts

[0132] 3 parts gamma-butyrolactone

[0133] Barium sulfate 12 parts

[0134] 1,2,3,4-cyclopentane tetracarboxylic acid 10 part...

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PUM

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Abstract

The invention relates to ABS (Acrylonitrile Butadiene Styrene) modified resin with high hardness, flame retardance and antistatic property. The ABS modified resin comprises the following components of ABS resin, aromatic polyimide fibers, diazo diphenylamine paraformaldehyde condensation product, a polyisocyanate block, silicone-modified polyurethane resin, 6-ethyoxyl-2,2,4-trimethyl-1,2-dihydroquinoline, styryl pyridine dimethyl sulfate salts, isobutyraldehyde, a curing agent, dimethoxy dipropylene glycol, polyvinyl butanol, an antistatic agent, zinc ferrite, 4-tert-Butylcyclohexanone, cyclododecanone, barium sulfate, 1,2,3,4-cyclopentanetetracarboxylic acid and deionized water. The ABS modified resin disclosed by the invention has the characteristics of high hardness, flame retardance and antistatic property.

Description

technical field [0001] The invention relates to a high-hardness flame-retardant antistatic ABS modified resin. Background technique [0002] ABS resin plastic is the polymer with the largest output and the widest application today. It has good physical and mechanical properties, high impact strength, chemical stability, good electrical properties, good product processing and machining performance, and is resistant to water, inorganic salts, acid and alkali, and is a widely used engineering material. However, the current ABS resin plastic still has the disadvantages of low strength, poor surface abrasion resistance, weak flame retardancy and heat resistance in extreme cases, and poor surface gloss. At the same time, ABS resin is very easy to generate static electricity accumulation when it is in contact with other surfaces, resulting in vacuuming, electric shock, discharge and ignition, which will cause distortion of precision instruments, short-circuit scrapping of electron...

Claims

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Application Information

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IPC IPC(8): C08L55/02C08L79/08C08L59/00C08L75/04C08L29/14C08L29/04C08L1/14C08L33/02C08K13/02C08K3/30C08K5/3432C08K5/3437C08K5/07C08K5/06C08K5/092
Inventor 宣海成
Owner 宣海成
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