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Crystal silicon solar cell high adhesive force back surface field aluminum electrocondution slurry and preparation method

A technology of solar cells and conductive pastes, applied in the manufacture of cables/conductors, conductive materials dispersed in non-conductive inorganic materials, circuits, etc., can solve problems such as bending of silicon wafers and component processes that affect solar cell yields, and achieve Substrate deformation is small, the appearance is good, and the effect of strong adhesion

Inactive Publication Date: 2015-04-29
ZHEJIANG GUANGLONG ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the current manufacturing process of crystalline silicon solar cells, the aluminum conductive paste is printed on almost the entire backlight surface of the cell. -7 / °C, 20~300°C) and silicon (expansion coefficient is 26×10 -7 / °C, 20~300°C), the difference in thermal expansion coefficient causes the aluminum conductive paste to generate stress in the silicon wafer during sintering, causing the silicon wafer to bend, which directly affects the yield of solar cells and the subsequent component process

Method used

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  • Crystal silicon solar cell high adhesive force back surface field aluminum electrocondution slurry and preparation method
  • Crystal silicon solar cell high adhesive force back surface field aluminum electrocondution slurry and preparation method

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Experimental program
Comparison scheme
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Embodiment 1~5

[0024] A crystalline silicon solar cell high-adhesion back-field aluminum conductive paste, the aluminum conductive paste is formed by mixing the raw materials shown in Table 1 below (by mass percentage).

[0025] Table 1. Details of the composition of the aluminum conductive paste in Examples 1 to 5

[0026] Example

1

2

3

4

5

Aluminum powder

68

75

71

80

78

glass powder

6

4

3

1

2

organic binder

25

19

24.5

16

17.5

Auxiliary

1

2

2.5

3

2.5

[0027] The preparation method of the high-adhesion back-field aluminum conductive paste for crystalline silicon solar cells is as follows: put the raw material aluminum powder, silicon-aluminum alloy powder, glass powder and organic adhesive into a vacuum mixer according to the proportions in Table 1 above , continue to stir for about 2 hours to form a uniform mixture, then disperse through a three-ro...

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PUM

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Abstract

The invention discloses crystal silicon solar cell high adhesive force back surface field aluminum electrocondution slurry which comprises 68%-80% of aluminite powder, 1%-6% of glass powder, 16%-25% of organic bond and 1%-3% of auxiliaries. The auxiliaries are composed of 60% of wetting dispersant and 40% of diffusion pump oil. The aluminum electrocondution slurry is printed on the back surface of a crystal silicon solar cell piece. Aluminium-silicon alloy reaction is performed on aluminum and substrate silicon through infrared quick calcining technology. A preparation method for the aluminum electrocondution slurry comprises the following steps that the aluminite powder, the glass powder, the organic bond and the auxiliaries are put in a vacuum mixer to be mixed, and dispersed by a three-high mill to obtain aluminum electrocondution slurry with less than or equal to 15Mum of precision and 20-40 Pa.s viscosity. The aluminum electrocondution slurry is good in property, and suitable for the use of a crystal silicon solar cell back surface field. A calcined aluminum film and a silicon substrate have good adhesive force and water resistence, aluminium pills and aluminium blisters do not exist, the calcined cell piece is small in bending, and the conversion efficiency is higher.

Description

technical field [0001] The invention belongs to the field of new materials for solar cells, in particular to a high-adhesion back-field aluminum conductive paste for crystalline silicon solar cells and a preparation method thereof. Background technique [0002] Crystalline silicon solar cell is a semi-permanent physical battery that converts sunlight energy into electrical energy. With the extreme consumption of fossil (petroleum, coal, natural gas, etc.) The demand for clean energy is becoming more and more urgent. For a long time in the future, the sun will be an effective provider of clean energy for human beings. At present, crystalline silicon solar cells are one of the effective devices for converting solar energy into civil energy. Its application range is expanding from aerospace and military to people's daily life. Life, while not generating new pollution, the reduction in cost will make solar cells more widely used. [0003] According to the forecast of the Inter...

Claims

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Application Information

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IPC IPC(8): H01B1/22H01B13/00H01L31/0224
Inventor 朱金浩蒋剑波王猛许布万光耀陈珏荣高非朱庆庆
Owner ZHEJIANG GUANGLONG ENERGY TECH
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