Plating solution for electroplating molybdenum-nickel-cerium alloy plating on surface of oil-pumping part

A cerium alloy and plating solution technology is applied in the field of plating solution for electroplating molybdenum-nickel-cerium alloy coating on the surface of oil-pumping components, which can solve the problems of poor compression resistance and wear resistance, unsolved problems, expensive corrosion-resistant alloys, etc. Corrosion and friction resistance, low environmental hazards, process stability effect

Inactive Publication Date: 2014-12-24
无锡市锡山区鹅湖镇荡口青荡金属制品厂
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For more than 100 years, researchers of oil production machinery have carried out a lot of research work on corrosion and wear problems. On the sucker rod, such as using corrosion-resistant alloys: for example, K-grade sucker rods use 20Ni2Mo, which contains Ni, Cr, Mo Corrosion-resistant alloys are more expensive; use anti-corrosion coatings: including metal coatings (such as hot-dipped aluminum, chrome plating, spraying nickel-based alloys) and non-metallic coatings (such as epoxy resin coatings), existing problems: coating peeling off , this kind of sucker rod cannot be used in inclined wells; use non-metal: glass fiber reinforced plastic sucker rod, carbon fiber composite material continuous sucker rod, these two kinds of sucker rods are relatively expensive, and have poor compression and wear resistance; use corrosion inhibition Agent: relatively expensive, and the anti-corrosion effect is not ideal; on the oil suction pipe, nickel-phosphorus composite inner coating technology is used; bimetallic oil pipe; nitriding; FRP-lined oil pipe
Although some results have been achieved, the problem has not been solved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] A plating solution for electroplating a molybdenum-nickel-cerium alloy coating on the surface of an oil pumping part, the plating solution is composed of: nickel sulfate 36g / L, sodium molybdate 10g / L, cerium sulfate 1.5g / L, sodium hypophosphite 10g / L , boric acid 13g / L, ammonium sulfate 24g / L, tartaric acid 30g / L, potassium pyrophosphate 15g / L, ascorbic acid 10g / L, formaldehyde 3ml / L, dimethylhexynol 2ml / L, thiourea 4mg / L, The balance is water.

Embodiment 2

[0014] A kind of plating bath of electroplating molybdenum-nickel-cerium alloy coating on the surface of oil pumping parts, the composition of this plating bath is: nickel sulfate 40g / L, sodium molybdate 6g / L, cerium sulfate 2.5g / L, sodium hypophosphite 8g / L , boric acid 17g / L, ammonium sulfate 20g / L, tartaric acid 34g / L, potassium pyrophosphate 11g / L, ascorbic acid 14g / L, formaldehyde 1ml / L, dimethylhexynol 4ml / L, thiourea 2mg / L, The balance is water.

Embodiment 3

[0016] A kind of plating bath of electroplating molybdenum-nickel-cerium alloy coating on the surface of oil pumping parts, the composition of this plating bath is: nickel sulfate 37g / L, sodium molybdate 9g / L, cerium sulfate 1.8g / L, sodium hypophosphite 9.5g / L L, boric acid 14g / L, ammonium sulfate 23g / L, tartaric acid 31g / L, potassium pyrophosphate 14g / L, ascorbic acid 11g / L, formaldehyde 2.5ml / L, dimethylhexynol 2.5ml / L, thiourea 3.5 mg / L, the balance is water.

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PUM

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Abstract

The invention discloses a plating solution for electroplating a molybdenum-nickel-cerium alloy plating on the surface of an oil-pumping part. The plating solution comprises, 36-40 g/L of nickel sulfate, 6-10 g/L of sodium molybdate, 1.5-2.5 g/L of cerium sulfate, 8-10 g/L of sodium hypophosphite, 13-17 g/L of boric acid, 20-24 g/L of ammonium sulfate, 30-34 g/L of tartaric acid, 11-15 g/L of potassium pyrophosphate, 10-14 g/L of ascorbic acid, 1-3 mL/L of formaldehyde, 2-4 mL/L of dimethyl hexynol, 2-4m g/L of thiourea, and the balance water.

Description

technical field [0001] The invention relates to the technical field of electroplating, in particular to a plating solution for electroplating a molybdenum-nickel-cerium alloy coating on the surface of an oil pumping part. Background technique [0002] Sucker rods and tubing are used for oil recovery in oil fields. There are two world-class problems encountered in mines: corrosion and wear. Well fluids often contain CO 2 , H 2 Corrosive media such as S and brine can cause corrosion fatigue fracture of sucker rods, corrosion damage of oil well pumps and screw pumps, corrosion and perforation of oil pipes, and seriously affect crude oil production. Some pumping wells of Dongxin Oil Production Plant in Shengli Oilfield broke due to corrosion of couplings (45 steel, quenched and tempered) after three months of operation. In some pumping wells in Zhongyuan Oilfield, the sucker rods suffered from corrosion fatigue fracture after three months of operation. In deviated wells (es...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D3/56
Inventor 钱永清
Owner 无锡市锡山区鹅湖镇荡口青荡金属制品厂
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