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Flame-retardant polyester composite material and preparation method thereof

A composite material, flame retardant polyester technology, applied in the field of materials, can solve the problems of plastic plasticization, reducing product durability temperature, product durability temperature reduction, etc.

Inactive Publication Date: 2014-10-29
MITAC PRECISION TECH(KUNSHAN) CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Generally speaking, the glass transition temperature of PLA is 60°C, and the durable temperature of the finished product is only about 55°C; on the other hand, the flame retardancy level of PLA itself is only V-2, and it will melt when burning. Phenomenon, in some special fields, such as electronic appliances, automotive interiors, etc., conventional polylactic acid cannot meet the requirements of use, and it is necessary to add flame retardants to it for flame retardant modification
However, the flame retardants available in the existing market usually have a plasticizing effect on plastics, resulting in a lower durable temperature of the product
In the current flame retardant research of PLA, it can usually be found that the addition of flame retardants can make the flame retardant grade of the material reach V-0, but it reduces the durable temperature of the product.

Method used

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  • Flame-retardant polyester composite material and preparation method thereof
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  • Flame-retardant polyester composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] (1) Place the styrene-ethylene-butadiene-styrene copolymer and paraffin processing oil in a high-speed mixer at a ratio of 2:1 by weight for high-speed mixing. After about 10 minutes, the processing oil and styrene -The ethylene-butadiene-styrene copolymer reaches a uniformly mixed state, and it is taken out for use;

[0043] (2) Take 5 parts by weight of the mixture obtained in step (1), 100 parts by weight of polylactic acid resin, 100 parts by weight of polycarbonate resin, 30 parts by weight of phosphorus compound flame retardant with structural formula FR-1, and 5 parts by weight of talc Parts and 2 parts by weight of chain extender are first mixed evenly by dry mixing, and then introduced into a twin-screw extruder with a volumetric feeder for melt-kneading processing at 180-210°C, after melt-kneading processing The obtained extruded bar is cooled by cold water into a solid state, and cylindrical particles are produced by a pelletizer;

[0044] (3) Dry the above-menti...

Embodiment 2

[0046] (1) Place the styrene-ethylene-butadiene-styrene copolymer and paraffin processing oil in a high-speed mixer at a ratio of 2:1 by weight for high-speed mixing. After about 10 minutes, the processing oil and styrene -The ethylene-butadiene-styrene copolymer reaches a uniformly mixed state, and it is taken out for use;

[0047] (2) Take 5 parts by weight of the mixture obtained in step (1), 100 parts by weight of polylactic acid resin, 100 parts by weight of polycarbonate resin, 30 parts by weight of phosphorus-based compound flame retardant with structural formula FR-2, and 5 parts by weight of talc Parts, 2 parts by weight of the chain extender, 0.4 parts by weight of the anti-dripping agent, firstly mixed uniformly by dry mixing, and then introduced into the twin-screw extruder with a volumetric feeder for melting and mixing at 180-210°C Kneading process, the extruded strip obtained after melt kneading process is cooled into a solid state by cold water, and cylindrical pa...

Embodiment 3

[0050] (1) Place the styrene-ethylene-butadiene-styrene copolymer and paraffin processing oil in a high-speed mixer at a ratio of 2:1 by weight for high-speed mixing. After about 10 minutes, the processing oil and styrene -The ethylene-butadiene-styrene copolymer reaches a uniformly mixed state, and it is taken out for use;

[0051] (2) Take 5 parts by weight of the mixture obtained in step (1), 100 parts by weight of polylactic acid resin, 100 parts by weight of polycarbonate resin, 30 parts by weight of phosphorus compound flame retardant with structural formula FR-3, and 5 parts by weight of talc Parts, 2 parts by weight of the chain extender, 0.4 parts by weight of the anti-dripping agent, firstly mixed uniformly by dry mixing, and then introduced into the twin-screw extruder with a volumetric feeder for melting and mixing at 180-210°C Kneading process, the extruded strip obtained after melt kneading process is cooled into a solid state by cold water, and cylindrical particle...

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Abstract

The invention belongs the technical field of materials, and concretely relates to a flame-retardant polyester composite material and a preparation method thereof. The preparation method comprises the steps: putting thermoplastic elastomer and processing oil in a high-speed mixed for high-speed mixing according to a ratio until the processing oil and the thermoplastic elastomer are mixed uniformly, taking out for usage; uniformly stirring the obtained mixture, polylactic acid resin, polycarbonate resin, a phosphorus-serial compound flame retardant, a nucleation promoter and an anti-droop agent in a dry mixing way according to a ratio, then introducing the mixture into a double screw extruder via a volumetric feeder for fusion mixing processing, after fusion mixing processing is finished, cooling obtained extruded strips with cold water to become solid state, and preparing cylindrical particles by using a comminutor; and drying the above resin composition particles in a hot-wind circulating baking box, and then using an ejecting molding machine to prepare a test sample strip. The flame-retardant polyester composite material obtained by using the preparation method is a PLA / PC composition giving consideration to toughness, strength, flame resistance and high durable temperature.

Description

【Technical Field】 [0001] The invention belongs to the technical field of materials, and specifically relates to a flame-retardant polyester composite material and a preparation method thereof. 【Background technique】 [0002] PC (polycarbonate) is a macromolecular polymer containing carbonate groups in the molecular chain. It is an amorphous transparent engineering plastic with the advantages of high strength and modulus, high toughness, and low shrinkage. PC is usually blended with ABS to form a PC / ABS alloy to form engineering plastics with excellent comprehensive properties, which are widely used. However, PC / ABS alloys are not degradable. Today, with global resource shortages, rising oil prices and increasing environmental pressures, people are paying more and more attention to the application of non-petrochemical materials. Therefore, the application of bio-composite materials in the plastics industry has attracted more and more attention. [0003] Among all the commercially ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L69/00C08K5/5357B29B9/06B29C47/92B29C48/92
Inventor 杨刚朱明毅浦蔚蔚
Owner MITAC PRECISION TECH(KUNSHAN) CORP
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