Organic electroluminescent device and packaging method thereof

A technology of electroluminescent devices and encapsulation methods, which is applied to organic semiconductor devices, organic semiconductor device materials, electric solid devices, etc., and can solve problems such as low service life, easy to be corroded, and reduced luminous quantum efficiency, and achieve service life high effect

Inactive Publication Date: 2014-09-17
OCEANS KING LIGHTING SCI&TECH CO LTD +2
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the light-emitting layer in the OLED is very sensitive to pollutants, oxygen, water vapor, etc. in the atmosphere. Chemical reactions under the action of pollutants, oxygen, and water vapor will lead to a decrease in the quantum efficiency of light emission, and the cathode is generally composed of a more active Metal formation, vulnerable to corrosion in air or oxygen, resulting in poor stability and low service life of OLEDs

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Organic electroluminescent device and packaging method thereof
  • Organic electroluminescent device and packaging method thereof
  • Organic electroluminescent device and packaging method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0096] The structure is ITO / MoO 3 :NPB / TCTA / Ir(ppy) 3 :TPBI / Bphen / CsN 3 :Bphen / Al / (H 2 Pc:CuPc / AIN) 7 Encapsulation of organic electroluminescent devices

[0097] (1) Provide an anode, the anode is indium tin oxide glass, expressed as ITO. First, put the anode into acetone, ethanol, deionized water and ethanol for ultrasonic cleaning, each ultrasonic cleaning for 5 minutes, then blow dry with nitrogen, and then dry in an oven to obtain a clean and dry anode. Further use UV-ozone (UV-ozone) to treat the cleaned and dried anode for surface activity treatment for 30 minutes to increase the oxygen content on the surface of the anode and improve the work function of the anode;

[0098] (2) The hole injection layer formed on the surface of the anode by vacuum evaporation, the vacuum degree of vacuum evaporation is 1×10 -5 Pa, the evaporation rate is The hole injection layer is made of molybdenum trioxide (MoO 3 ) doped in N,N'-diphenyl-N,N'-di(1-naphthyl)-1,1'-biphenyl-4,4'...

Embodiment 2

[0108] The structure is ITO / MoO 3 :NPB / TCTA / Ir(ppy) 3 :TPBI / Bphen / CsN 3 :Bphen / Al / (H 2 Pc:ZnPc / TiN) 7 Encapsulation of organic electroluminescent devices

[0109] In steps (1) to (7), the rest is the same as that in Example 1, except that the time for surface activation treatment on the anode is 50 minutes.

[0110] (8) Vacuum evaporation is used to form an organic barrier layer on the cathode, and the vacuum degree of vacuum evaporation is 5×10 -5 Pa, the evaporation rate is The organic barrier layer is composed of phthalocyanine (H 2 Pc) doped in one of the zinc phthalocyanines (ZnPc), denoted as H 2 Pc: ZnPc, wherein, phthalocyanine (H 2 The molar ratio of Pc) to zinc phthalocyanine (ZnPc) is 3:100; the thickness of the organic barrier layer is 150 nm;

[0111] (9) Magnetron sputtering is used to form an inorganic barrier layer on the organic barrier layer, and the vacuum degree of the background is 1×10 -5 Pa; The flow rate of the argon gas that feeds in the mag...

Embodiment 3

[0114] The structure is ITO / MoO 3 :NPB / TCTA / Ir(ppy) 3 :TPBI / Bphen / CsN 3 :Bphen / Al / (H 2 Pc:FePc / VN) 7 Encapsulation of organic electroluminescent devices

[0115] In steps (1) to (7), the rest is the same as that in Example 1, except that the time for surface activation treatment on the anode is 40 minutes.

[0116] (8) Vacuum evaporation is used to form an organic barrier layer on the cathode, and the vacuum degree of vacuum evaporation is 5×10 -5 Pa, the evaporation rate is The organic barrier layer is composed of phthalocyanine (H 2 Pc) doped in one of iron phthalocyanine (FePc), denoted as H 2 Pc: FePc, wherein, phthalocyanine (H 2 The molar ratio of Pc) to iron phthalocyanine (FePc) is 1:100; the thickness of the organic barrier layer is 100 nm;

[0117] (9) Magnetron sputtering is used to form an inorganic barrier layer on the organic barrier layer, and the vacuum degree of the background is 1×10 -5 Pa; The flow rate of the argon gas that feeds in the magnetron...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Thicknessaaaaaaaaaa
Thicknessaaaaaaaaaa
Login to view more

Abstract

The invention relates to an organic electroluminescent device and a packaging method thereof. The organic electroluminescent device comprises an anode, a cavity injection layer, a cavity transmission layer, a luminescent layer, an electron transmission layer, an electron injection layer and a cathode which are successively stacked, and five to seven protection layers stacked on the cathode. Each protection layer comprises an organic barrier layer and an inorganic barrier layer stacked on the organic barrier layer. Each organic barrier layer is formed by doping phthalocyanine to one from copper phthalocyanine, zinc phthalocyanine, iron phthalocyanine, cobalt phthalocyanine, manganese phthalocyanine and nickel phthalocyanine. Each inorganic barrier layer is formed by aluminum nitride, titanium nitride, vanadium nitride, niobium nitride, zirconium nitride or tantalum nitride. The compact protection layers formed by organic materials and inorganic materials can effectively reduce corrosion by external active substances such as water, oxygen and the like to the organic layer and the cathode, and the five to seven protection layers can satisfy the sealing performance for packing and provide effective protection for the organic layer and the cathode, thus the service life of the organic electroluminescent device can be longer.

Description

technical field [0001] The invention relates to the technical field of electroluminescence, in particular to an organic electroluminescence device and a packaging method thereof. Background technique [0002] Organic electroluminescent device (OLED) is a current-mode semiconductor light-emitting device based on organic materials. Its typical structure is to make a layer of tens of nanometers thick organic light-emitting material on the ITO glass as the light-emitting layer, and there is a metal electrode with a low work function above the light-emitting layer. When a voltage is applied to the electrodes, the light-emitting layer produces light radiation. [0003] OLED devices have the advantages of active luminescence, high luminous efficiency, low power consumption, lightness, thinness, and no viewing angle restrictions. They are considered by industry insiders to be the new generation of devices that are most likely to occupy a dominant position in the future lighting and...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): H01L51/50H01L51/52H01L51/54H01L51/56
CPCH10K50/8445H10K2102/00H10K71/00
Inventor 周明杰王平钟铁涛陈吉星
Owner OCEANS KING LIGHTING SCI&TECH CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap