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Chemical heat treatment method capable of obviously improving corrosion resistance of gear

A chemical heat treatment and corrosion resistance technology, applied in the direction of metal material coating process, coating, solid-state diffusion coating, etc. performance, improve overall performance, the effect of low oxidation temperature

Active Publication Date: 2014-05-14
溧阳市永恒热处理有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, in practical industrial applications, due to the complexity of the gear working environment, while improving the surface hardness of the gear, it is also necessary to take into account the electrochemical corrosion resistance of the surface. The ε phase is usually loose and porous on the surface of the gear after ion nitriding. Yes, an oxygen concentration battery is formed between the peak and the valley, and the oxygen deficiency in the valley is easily corroded, forming pitting corrosion, which reduces its electrochemical corrosion performance to a certain extent
And the nitrided layer is thin, brittle and easy to fall off
In order to overcome the above defects, salt bath oxidation, vacuum furnace oxidation, surface coating and other methods are generally used in actual production. The oxidation medium is mostly oxygen or hydrogen-oxygen mixture, the operation is complicated, and the processing cost is relatively high.

Method used

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  • Chemical heat treatment method capable of obviously improving corrosion resistance of gear
  • Chemical heat treatment method capable of obviously improving corrosion resistance of gear
  • Chemical heat treatment method capable of obviously improving corrosion resistance of gear

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1)

[0027] Put the 42CrMo gear into the ion nitriding furnace. After vacuuming to a certain degree of vacuum, adjust the voltage and current to start glowing, and then pass in hydrogen for ion sputtering. After sputtering for a certain period of time, continue to pass in nitrogen to adjust the nitrogen and hydrogen. ratio, so that N 2 :H 2 =1:3, when the temperature reaches the nitriding temperature of 560°C, start timing for ion nitriding, set the nitriding atmosphere pressure to 350Pa, and the holding time to 10h. After ion nitriding, close the nitrogen and hydrogen valves. When the temperature drops to the oxidation temperature of 300°C, extract the air pressure in the furnace to a certain degree of vacuum again, adjust the voltage and current for ignition, and at the same time feed air, set the air flow rate to 4L / min, and set the furnace atmosphere pressure to 100Pa. The holding time is 0.25h. After the oxidation, the pretreatment before the electrochemical corrosion exper...

Embodiment 2)

[0030] Put the 42CrMo gear into the ion nitriding furnace. After vacuuming to a certain degree of vacuum, adjust the voltage and current to start glowing, and then pass in hydrogen for ion sputtering. After sputtering for a certain period of time, continue to pass in nitrogen to adjust the nitrogen and hydrogen. ratio, so that N 2 :H 2 =1:3, when the temperature reaches the nitriding temperature of 560°C, start timing for ion nitriding, set the nitriding atmosphere pressure to 350Pa, and the holding time to 10h. After ion nitriding, close the nitrogen and hydrogen valves. When the temperature drops to the oxidation temperature of 300°C, extract the air pressure in the furnace to a certain degree of vacuum again, adjust the voltage and current for ignition, and at the same time feed air, set the air flow rate to 4L / min, and set the furnace atmosphere pressure to 100Pa. The holding time is 0.5h. After the oxidation, the pretreatment before the electrochemical corrosion experi...

Embodiment 3)

[0033] Put the 42CrMo gear into the ion nitriding furnace. After vacuuming to a certain degree of vacuum, adjust the voltage and current to start glowing, and then pass in hydrogen for ion sputtering. After sputtering for a certain period of time, continue to pass in nitrogen to adjust the nitrogen and hydrogen. ratio, so that N 2 :H 2 =1:3, when the temperature reaches the nitriding temperature of 560°C, start timing for ion nitriding, set the nitriding atmosphere pressure to 350Pa, and the holding time to 10h. After ion nitriding, close the nitrogen and hydrogen valves. When the temperature drops to the oxidation temperature of 300°C, extract the air pressure in the furnace to a certain degree of vacuum again, adjust the voltage and current for ignition, and at the same time feed air, set the air flow rate to 4L / min, and set the furnace atmosphere pressure to 100Pa. The holding time is 1h. After the oxidation, the pretreatment before the electrochemical corrosion experime...

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Abstract

The invention belongs to a metal surface chemical heat treatment technology and aims to provide a chemical heat treatment method capable of obviously improving the corrosion resistance of a gear. According to the method, ion oxidation treatment is carried out on the gear which is subjected to ion nitriding, wherein air is used as an air source, the ion oxidation treatment and the ion nitriding are carried out in the same furnace; and after the ion nitriding is carried out on the gear at 560 DEG C, and air is introduced for oxidization for 0.25-1 hour after the temperature is reduced to 350-450 DEG C. According to the chemical heat treatment method, one layer of a dense oxidized film which mainly contains Fe3O4 is generated on the surface of a nitriding layer of the gear; under the same condition, compared with a gear sample which is not oxidized, the gear which is subjected to ion oxidization has the advantages that the corrosion resistance can be obviously improved and the surface rigidity gradient of the nitriding layer is obviously slowed down. The chemical heat treatment method is simple to operate; compared with other oxidization methods, the method provided by the invention has the advantages that no auxiliary equipment is used, an oxidization medium is air, and the oxidization temperature is low and the consumption of energy sources is reduced; moreover, the chemical heat treatment method has the advantages of low treatment cost, high production efficiency and the like.

Description

technical field [0001] The invention belongs to metal surface chemical heat treatment technology, and aims at a chemical heat treatment method for significantly improving the corrosion resistance of gears. Background technique [0002] Gears have good comprehensive performance. In order to meet their surface wear resistance, nitriding methods are usually used, mainly including: (1) ion nitriding; (2) salt bath nitriding; (3) gas nitriding, etc. Ion nitriding chemical heat treatment is the earliest developed technology with the widest application range. It has the advantages of uniform nitriding layer, high efficiency, less pollution, short processing time, and small workpiece deformation. It has become an indispensable part of many products. Missing surface strengthening process. [0003] However, in practical industrial applications, due to the complexity of the gear working environment, while improving the surface hardness of the gear, it is also necessary to take into ac...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C8/36C23C8/80
Inventor 胡静李景才宋仁国蔡剑勇杨星梅
Owner 溧阳市永恒热处理有限公司
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