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Hydration heat inhibited concrete expanding material as well as preparation method and applications thereof

A heat-of-hydration-inhibiting, expansive material technology, which is applied in the application fields of heat-of-hydration-inhibited concrete expansive materials and their preparation, drying shrinkage, and temperature shrinkage performance, can solve the problems of large reduction in water absorption, low early strength, and fluidity. The problem of increasing the slump loss of the state concrete is achieved, and the effects of reducing temperature shrinkage cracks, improving the performance of absolute moisture expansion, and increasing the temperature shrinkage stress are achieved.

Active Publication Date: 2015-04-29
CHINA BUILDING MATERIALS ACAD
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Problems solved by technology

However, this technology does not describe and analyze the heat of hydration inhibition effect of the raw materials and processes of synthetic dextrin in detail, and the multifunctional anti-cracking additive has (1) limited expansion rate (0.0452%), (2) due to Fly ash is added to the formula, and fly ash needs to be added during use, which increases the transportation cost of the product
[0007] Among the building materials for the purpose of compensating for cold shrinkage, the representative ones are: (1) Low-heat micro-expansion cement with granulated blast furnace slag as the main component and an appropriate amount of Portland cement clinker and gypsum, (such as the current national Standard "Low Heat Micro-expansion Cement" GB2938), this type of cement has the problems of low expansion efficiency and low early strength
(2) Control the magnesia content in the cement to 4%-5%, and the expansion agent containing magnesia derived therefrom, such as a "three expansion source concrete anti-cracking agent" disclosed in the Chinese patent literature with the publication number CN101143769A (CMA)", a "magnesium oxide composite expansion agent" disclosed in the Chinese patent literature with the publication number CN1412144A, a "durable three-expansion source concrete expansion agent" disclosed in the Chinese patent literature with the publication number CN101456694A, magnesium oxide The expansion agent has the problem that the firing temperature and hydration reaction are not easy to control, so its application in the field of construction engineering is limited
Dextrin is a product obtained from starch gelatinization. Its raw material type and preparation process have a great influence on the inhibition effect of cement hydration heat and setting time. There is a lack of detailed and effective experimental research in this regard.
[0017] In the part involving internal curing materials, it is inconvenient to use water-absorbing light aggregates such as ceramsite, and it needs to be pre-soaked with saturated water in advance; superabsorbent resin materials have poor ability to absorb salt and alkali aqueous solutions, and the water absorption ratio is greatly reduced
In addition, under the wrapping of viscous media such as cement, the water absorption speed will slow down, which will lead to problems such as increased slump loss of fluid concrete
[0018] In the existing technology, there is no literature that considers the combined use of expansion agent-hydration heat inhibitor-internal curing agent

Method used

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  • Hydration heat inhibited concrete expanding material as well as preparation method and applications thereof
  • Hydration heat inhibited concrete expanding material as well as preparation method and applications thereof
  • Hydration heat inhibited concrete expanding material as well as preparation method and applications thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0109] Embodiment 1, preparation with CA 2 Calcium aluminate clinker as the main mineral and its application in the preparation of expansion agent

[0110] 1. First prepare the calcium dialuminate (CaO·2Al 2 o 3 , abbreviated as CA 2 ) as the main mineral calcium aluminate clinker, using Al 2 o 3 Content 74.5%, SiO 2 Bauxite with a content of 8.2% ( ) and CaO content of 55.5% (≥55%), SiO 2 Limestone with a content of 0.2%, prepare the raw meal according to the ratio shown in Table 1, use a ball mill to grind the raw meal, and control the fineness of the raw meal to 450m 2 / kg, using an electric furnace or a rotary kiln to calcinate calcium aluminate clinker, the calcining temperature is 1550°C-1650°C, and the calcining time is 60-120min to obtain calcium aluminate clinker. The main mineral composition ratio of calcium aluminate clinker is shown in Table 1:

[0111] Table 1 The proportion of main mineral components of calcium aluminate clinker

[0112]

[0113] 2...

Embodiment 2

[0123] Example 2. Preparation of Heat of Hydration Inhibitor and Performance Testing

[0124] The heat of hydration inhibitor is prepared by using commercially available cornstarch and wheatstarch as raw materials through dry heat reaction. Firstly, according to the ratio of corn starch and wheat starch in Examples 2-1 to 2-24 shown in Table 3, the ingredients were prepared, and then the starch was subjected to hydrochloric acid catalytic pretreatment (hydrochloric acid mass concentration 12.5%, dosage 0.1wt%), Drying, control the moisture content of the starch at 1-5%, and then heat-convert the dried starch, strictly control the heating temperature (110-130°C), the heating uniformity of the starch and the reaction time (8-10 hours), During the heating process, continuous and uniform stirring is carried out, the reaction product is cooled, and sieved to obtain the heat of hydration inhibitor. The heat of hydration inhibitor samples were tested for cold water solubility and re...

Embodiment 3

[0136] Embodiment three, performance detection of internal curing agent

[0137] The internal curing agent of the present invention adopts commercially available polyacrylate cross-linked resin (SAP, purchased from Beijing Huaruixiang Technology Co., Ltd.), with a particle size of 100-120 mesh, a water absorption rate of 400mL / g, and a salt water (NaCl aqueous solution with a concentration of 0.9%) ) rate ≥ 30mL / g.

[0138] The concrete mix ratio used in the test is as follows: PO42.5MPa cement: 430kg / m 3 ; Expansion material: 50kg / m 3 ;Water: 235kg / m 3 ;Sand (fineness modulus 2.6): 700kg / m 3 ;Stone (particle size 5-20mm): 985kg / m 3 .

[0139] In the test, the expansion material includes expansion agent and heat of hydration inhibitor, and the product of the embodiment of the present invention is used to grind together to a specific surface area of ​​300m 2 / kg; Also add internal curing agent SAP according to Table 5.

[0140] There are two kinds of SAP mixing methods: ...

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Abstract

The invention discloses a hydration heat inhibited concrete expanding material as well as a preparation method and applications thereof. The hydration heat inhibited concrete expanding material is implemented by complexly using first two or three of an expanding agent, a hydration heat inhibitor and an inner curing agent. The hydration heat inhibited concrete expanding material disclosed by the invention fully plays the superimposed effect of the three types of materials, so that the dry shrinkage resistance and cold shrinkage resistance of concrete can be maximized. Experiments prove that concrete with the hydration heat inhibited concrete expanding material disclosed by the invention produces a large expansion in the temperature-fall period, thereby considerably improving the temperature shrinkage (caused by hydration heat) resistance of the concrete; the temperature rise of concrete can be effectively reduced; high relative humidity can be kept in the concrete for a long time, thereby providing a good hydration reaction environment for the expanding agent, and reducing dry shrinkage.

Description

technical field [0001] The invention belongs to the technical field of concrete admixtures for building materials, and in particular relates to a hydration heat-inhibiting concrete expansion material and a preparation method thereof and its application in improving concrete resistance to drying shrinkage and temperature shrinkage caused by hydration heat. Background technique [0002] Cracks caused by shrinkage of concrete are a common quality problem and generally affect the durability of concrete structures. Among them, drying shrinkage (including self-drying shrinkage) and temperature shrinkage (shrinkage deformation caused by hydration heat) are the two most important types of shrinkage, especially the early cracking of concrete structures caused by temperature shrinkage is becoming more and more common. After years of research and practice, people have explored technical ways to reduce these two shrinkages from different perspectives such as technology and materials. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B22/14
Inventor 赵顺增刘立贾福杰李长成武旭南
Owner CHINA BUILDING MATERIALS ACAD
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