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Thermoplastic low-smoke halogen-free flame-retardant environment-friendly sheath material for power cables and preparation method thereof

A power cable and thermoplastic technology, which is applied in the field of thermoplastic low-smoke halogen-free flame-retardant and environment-friendly sheathing material for power cables and its preparation, can solve the problem of reduced mechanical properties and processing properties of materials, impact on cable service life, loss of cable manufacturers, etc. problems, to achieve the effect of improving heat aging resistance, excellent physical and mechanical properties, and delaying aging

Active Publication Date: 2013-05-29
ANHUI HUAJIN CABLE GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Low-smoke halogen-free flame-retardant polyolefin cable sheathing material is an environmentally friendly product. The development of such high-performance flame-retardant materials is an important topic and a difficulty in flame-retardant technology, because the flame-retardant system generally uses hydrated inorganic fillers As a flame retardant, although this type of flame retardant is non-toxic and low-smoke, its flame-retardant efficiency is low, and a large filling amount is required to achieve high flame-retardant performance, which will cause a decrease in the mechanical properties and processing properties of the material. In particular, the impact on the latter is more serious
As a high-fill low-smoke halogen-free flame-retardant polyolefin material, it is easy to crack, which is a fatal defect of cable products, which seriously affects the service life of cables and causes great losses to cable manufacturers.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0050] Thermoplastic low-smoke, halogen-free, flame-retardant and environment-friendly sheathing material for power cables, the components and their parts by weight are:

[0051] 70 parts of EVA with VA content of 28%

[0052] HDPE 20 parts

[0053] EPDM 10 copies

[0054] Maleic anhydride grafted EVA 20 parts

[0055] 120 parts of modified magnesium hydroxide

[0056] Microencapsulated red phosphorus 6 parts

[0057] 4 parts melamine cyanurate

[0058] Antioxidant 1035 1 part

[0059] Antioxidant DSTP 0.5 part

[0060] Ethylene bis stearamide 1.5 parts

[0061] 4 copies of DCP

[0062] 3 parts zinc oxide

[0063] 1 part calcium stearate

[0064] Dimethyl methylphosphonate 15 parts

[0065] Nano kaolin 35 parts

[0066] 2 parts stearic acid

[0067] 0.8 parts of isopropyl tris (dioctyl pyrophosphate acyloxy) titanate.

[0068]Wherein, the modified magnesium hydroxide is prepared by the following method: bake the magnesium hydroxide at 115°C for 5 hours, add disti...

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PUM

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Abstract

The invention discloses a thermoplastic low-smoke halogen-free flame-retardant environment-friendly sheath material for power cables and a preparation method thereof. The thermoplastic low-smoke halogen-free flame-retardant environment-friendly sheath material for power cables comprises the following components in parts by weight: 60-80 parts of EVA (ethylene-vinyl acetate), 20-30 parts of HDPE (high-density polyethylene), 10-15 parts of EPDM (ethylene-propylene-diene monomer), 15-25 parts of compatiblizing agent, 100-150 parts of halogen-free flame retardant, 0.5-1 part of antioxidant 1035, 0.5-1 part of antioxidant DSTP, 1-2 parts of ethylene bis stearamide, 3-5 parts of DCP (dicumyl peroxide), 2-4 parts of zinc oxide, 1-2 parts of calcium stearate, 10-20 parts of dimethyl methyl phosphonate, 30-40 parts of nano kaolin, 2-3 parts of stearic acid and 0.5-1 part of isopropyl tri(dioctylpyrophosphate)titanate. The sheath material disclosed by the invention has the advantages of excellent physical and mechanical properties, excellent flame retardancy, favorable high / low temperature resistance, favorable oil resistance, favorable solvent resistance, favorable wear resistance, favorable ozone resistance, favorable aging resistance, high flexibility, crack resistance and the like, is very durable, environment-friendly and pollution-free, and can completely satisfy the requirements for modern power cables.

Description

technical field [0001] The invention relates to a sheathing material for power cables, in particular to a thermoplastic low-smoke, halogen-free, flame-retardant and environment-friendly sheathing material for power cables and a preparation method thereof. Background technique [0002] At present, with the introduction of EU ROHS and REACH environmental protection regulations and the needs of public safety, low-smoke halogen-free flame-retardant polyolefin materials have replaced PVC in the field of cables and are widely used in high-speed railways, urban rail transit and automobiles, ships, Nuclear power plants, high-rise buildings, optical communications, mobile communication base stations and other fields. [0003] Low-smoke halogen-free flame-retardant polyolefin cable sheathing material is an environmentally friendly product. The development of such high-performance flame-retardant materials is an important topic and a difficulty in flame-retardant technology, because th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L23/06C08L23/16C08K13/06C08K3/02C08K5/3492C08K3/22C08K5/098C08K5/5333C08K3/34C09C1/00C09C3/12C09C3/10H01B7/295
Inventor 冯显安冯显根冯显智周光玉施家斌姚天新姚健骏
Owner ANHUI HUAJIN CABLE GROUP
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