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Method for producing steel for low-nitrogen stranded wire by use of non-vacuum process of converter

A non-vacuum, converter technology, used in the manufacture of converters and other directions, can solve the problems of large fluctuations in product strength, toughness and other indicators, brittle fracture, and high process production costs

Active Publication Date: 2013-05-15
SHOUGANG CORPORATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This results in a large fluctuation range of product strength, toughness and other indicators after drawing by the product enterprise, and a low qualified rate of finished products; on the other hand, it is easy to cause brittle fracture during drawing, and in severe cases, it cannot be processed
[0004] The nitrogen content of high-carbon steel (carbon content greater than 0.77%) produced by Japanese companies is generally controlled below 40ppm. The main difference lies in the control of different processes. Japanese companies generally use molten iron three-stranding process, converter or electric furnace, and LF furnace to produce high-carbon steel. Refining+vacuum degassing, bloom opening, two-fire process, stable product quality, high process production cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Example 1: Heat No. 8B05482

[0027] Converter smelting: 211 tons of molten iron as raw material, 25 tons of scrap steel, and operating oxygen pressure of 7.5kg / cm 2 , The oxygen supply time is 14 minutes and 30 seconds; the amount of lime added is 7800kg, the light burned dolomite is 1660kg; the austenitic ore is 1800kg; the end carbon: 0.28%, phosphorus: 0.012%; the tapping temperature is 1620℃.

[0028] Deoxidation alloying: micro-nitrogen recarburizer 5kg / ton steel; silicon-calcium-barium 1.5kg / ton steel; silicon-manganese 1000kg, ferromanganese 1000kg, carbon ferrochrome 970kg.

[0029] LF refining furnace: 900kg of fluorite; 1400kg of lime; 650kg of synthetic slag, 320kg of submerged arc slag, bauxite: 200kg, calcium carbide: 50kg; aluminum particles: 50kg; ferrosilicon powder: 50kg; silicon calcium wire: 1m / ton steel ; Flow rate of soft argon blowing: 65NL / min, time 12 minutes 30 seconds;

[0030] Continuous casting: mold electromagnetic stirring parameters: 300A, 5Hz; m...

Embodiment 2

[0032] Example 2: Heat No. 8A04946

[0033] Converter smelting: 210 tons of molten iron as raw material, 26 tons of scrap steel, and operating oxygen pressure of 7.4kg / cm 2 , The oxygen supply time is 14 minutes and 45 seconds; the amount of lime added is 7900kg, the lightly burned dolomite is 1760kg; the austenitic ore is 1900kg; the end carbon: 0.26%, phosphorus: 0.011%; the tapping temperature is 1625℃.

[0034] Deoxidizing alloying: micro-nitrogen recarburizer 5kg / ton steel; silicon-calcium-barium 1.5kg / ton steel; silicon-manganese 1010kg, manganese 1010kg, carbon ferrochrome 1000kg.

[0035] LF refining furnace: 920kg of fluorite; 1410kg of lime; 680kg of synthetic slag, 300kg of submerged arc slag, bauxite: 180kg, calcium carbide: 50kg; aluminum particles: 50kg; ferrosilicon powder: 50kg; silicon calcium wire: 1m / ton steel ; Flow rate of soft argon blowing: 64NL / min, time 14 minutes 30 seconds;

[0036] Continuous casting: mold electromagnetic stirring parameters: 300A, 5Hz; mol...

Embodiment 3

[0038] Example 3: Heat No. 8B05478

[0039] Converter smelting: 215 tons of molten iron as raw material, 20 tons of scrap steel, and operating oxygen pressure of 7.6kg / cm 2 , The oxygen supply time is 13 minutes and 30 seconds; the amount of lime added is 7700kg, the light burned dolomite is 1650kg; the austenitic ore is 1820kg; the end carbon: 0.25%, phosphorus: 0.012%; the tapping temperature is 1621℃.

[0040] Deoxidizing alloying: micro-nitrogen recarburizer 5kg / ton steel; silicon-calcium-barium 1.5kg / ton steel; silicon-manganese 1010kg, ferromanganese 1000kg, carbon ferrochrome 1000kg.

[0041] LF refining furnace: 920kg of fluorite; 1500kg of lime; 800kg of synthetic slag, 300kg of submerged arc slag, bauxite: 200kg, calcium carbide: 50kg; aluminum particles: 50kg; ferrosilicon powder: 50kg; silicon calcium wire: 1m / ton steel ; Flow rate of soft argon blowing: 60NL / min, time 15 minutes 30 seconds;

[0042] Continuous casting: mold electromagnetic stirring parameters: 300A, 5Hz; ...

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PUM

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Abstract

The invention discloses a method for producing steel for a low-nitrogen stranded wire by use of the non-vacuum process of a converter, belonging to the technical field of steel for prestressed steel strand. The method comprises the steps of molten iron desulphurization and slagging off, converter smelting, slag blocking and tapping, steel ladle deoxidization and alloying, steel ladle slag modification, LF steel ladle refining, Si-Ca wire feeding, steel ladle bottom soft argon blowing, full-protection casting of 160mm*160mm small square billet and terminal electromagnetic stirring matched with a crystallizer; the technical parameters of control are as follows: the converter adopts double-slag operation, the end point carbon is under 0.20-0.30% control, the tapping temperature is 1,600-1,630 DEG C, and the thickness of roughing slag is 0-50mm; a micro-nitrogen carburant (N: 0.005-0.025%) is matched with 5kg of carbon per ton of steel, 1.5kg of Si-Ca-Ba per ton of steel is added for deoxidization, and 4kg of synthetic slag per ton of steel is added; the oxygen activity outside the LF refining station is controlled to be less than or equal to 10ppm, and the content of FeO and MnO in final slag is less than or equal to 3%; and 1m Ca-Si wire per ton of steel is fed, and the soft argon blowing time is 12-30 minutes. The method disclosed by the invention remarkably lowers the production cost and reaches the nitrogen quality control level of steel for producing a stranded wire in a vacuum degassing process.

Description

Technical field [0001] The invention belongs to the technical field of steel for prestressed steel strands, and in particular relates to a method for producing low-nitrogen stranded steel using a converter non-vacuum process, which is suitable for the production of nitrogen content in converters, LF furnaces, and billet continuous casting processes The production method of steel for steel strands with a content of less than 40ppm (the carbon content of steel is 0.78~0.90%) is applied to high-grade building prestressed concrete. Background technique [0002] Under certain circumstances, the nitrogen in steel will reduce the performance of the material. Its existence reduces the toughness and plasticity of the steel; it causes the steel to produce strain aging, aging precipitation hardening or aging brittleness; resulting in blue brittleness, red hot brittleness, and cold Brittle; Promote the loosening of the center or the formation of microscopic pores; produce hair lines and bubb...

Claims

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Application Information

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IPC IPC(8): C21C5/28C21C7/00C22C33/04
Inventor 周德孔祥涛王立峰王全礼周德光刘中柱朱殷翔孙齐松丁宁程四华李三凯
Owner SHOUGANG CORPORATION
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