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Metal surface silane treating agent containing acrylic acid and preparation method of metal surface silane treating agent

A silane treatment agent and metal surface technology, applied in anti-corrosion coatings, coatings, etc., can solve problems such as voids, uneven density, weak metal support, etc., to achieve enhanced corrosion resistance and low polarization current density Effect

Inactive Publication Date: 2013-05-15
江苏金科环境工程科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the field of metal surface treatment, although traditional phosphate conversion and chromate passivation surface treatment technologies can achieve good results, the waste liquid discharged during the treatment process Contains heavy metal ions such as zinc, manganese, nickel, chromium and carcinogens such as nitrite, which is very serious to environmental pollution, and the metal surface silanization treatment technology does not involve substances that are harmful to the environment, the production process has low energy consumption, and the technical application field Widely used, it is considered to be expected to replace phosphate conversion treatment and chromate passivation treatment. It is the latest development direction of metal surface protection alone. In the existing technology, the film formed on the surface of metal workpieces treated with silane solution has uneven density and Holes, cracks, and weak support to the metal body

Method used

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Embodiment 1

[0018] Embodiment 1: the metal surface silane treatment agent that contains acrylic acid, the mixed liquor that is prepared by following components, the weight (gram) of each component in every 500 grams of mixed liquors is: vinyl three (beta-methoxyethylene Oxy)silane 12, film-forming resin 1.5, acrylic acid 4, triethanolamine 1.7, oxalic acid 1, propylene glycol 8, 2-n-octyl-4-isothiazolin-3-one 1.6, polydimethylsiloxane 0.3, Sodium dodecylbenzene sulfonate 2, sodium bicarbonate 6 and ethylene glycol dimethyl ether 95, the balance is deionized water.

[0019] The preparation method of the described metal surface silane treatment agent containing acrylic acid comprises the following steps:

[0020] (1) Preparation of film-forming resin:

[0021] According to formula weight (g): urea 1-3, anilinomethyltriethoxysilane 1.5-2.5, oxalic acid 3-5, iron oxide 0.1-0.2, potassium persulfate 0.1-0.2, polyethylene glycol 400 1-2 , sodium metasilicate 0.7-0.9 deionized water 10-12; pre...

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PUM

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Abstract

The invention discloses metal surface silane treating agent containing acrylic acid and a preparation method of the metal surface silane treating agent. The metal surface silane treating agent containing acrylic acid is a mixed solution which is prepared from the following components: ethenyl tri-(beta-methoxyethyoxyl) silane, film-forming resin, acrylic acid, triethanolamine, oxalic acid, propylene glycol, 2-n-octyl-4-isothiazolin-3-acetone, polydimethylsiloxane, antioxidant 1010, sodium bicarbonate and ethylene glycol dimethyl ether. According to the metal surface silane treating agent and the preparation method of the metal surface silane treating agent disclosed by the invention, the ethenyl tri-(beta-methoxyethyoxyl) silane is adopted as the main material, glycol dimethyl ether is adopted as a solvent, and the cost is low; meanwhile, acrylic acid and various different auxiliary materials are added to the materials, and the treatment time and the treatment temperature of the treating agent are improved. When the silane treating agent disclosed by the invention is used to treat a metal workpiece, a polyacid film layer is formed on the surface of the metal workpiece; the film layer has the characteristics of being strong in adhesive force, free of holes and cracks, compact and uniform and small in polar current density; moreover, the production process is environment-friendly and pollution-free.

Description

technical field [0001] The invention relates to the field of metal surface treatment, in particular to a metal surface silane treatment agent containing acrylic acid and a preparation method thereof. Background technique [0002] In the field of metal surface treatment, although traditional phosphate conversion and chromate passivation surface treatment technologies can achieve good results, the waste liquid discharged during the treatment process contains heavy metal ions such as zinc, manganese, nickel, chromium and nitrous acid. Carcinogens such as salt are very serious to environmental pollution, and metal surface silanization treatment technology is considered to be expected to replace phosphate conversion treatment and chromate passivation treatment because it does not involve substances that are harmful to the environment, the production process has low energy consumption, and the technology has a wide range of applications. Chemical treatment is the latest developm...

Claims

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Application Information

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IPC IPC(8): C09D4/06C09D7/12C09D5/08
Inventor 夏坤财
Owner 江苏金科环境工程科技有限公司
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