Soft magnetic composite material and preparation method thereof
A technology of soft magnetic composite materials and magnetic powder, applied in the direction of magnetism of inorganic materials, can solve problems such as low temperature resistance, serious environmental pollution, and difficulty in effectively removing residual stress, and achieve the effect of improving magnetic properties and eliminating internal stress
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specific Embodiment approach 1
[0013] Embodiment 1: A soft magnetic composite material provided in this embodiment is composed of magnetic powder, a silicon dioxide layer coated with magnetic powder, and a glass layer coated outside the silicon dioxide layer; wherein, the magnetic powder is a magnetic metal Powder, magnetic metal alloy powder and magnetic metal compound powder or a combination of several of them.
[0014] The soft magnetic composite material provided in this embodiment can adjust the composition and ratio of the glass layer according to the coefficient of thermal expansion. The thermal expansion coefficients of the two substances in one material do not match, and internal stress is easily generated inside the material when the temperature changes, which in turn reduces the magnetic properties of the soft magnetic composite material. Therefore, in the selection of the cladding layer, the thermal expansion coefficient should be matched with the thermal expansion coefficient of the soft magnet...
specific Embodiment approach 2
[0017] Specific embodiment two: the difference between this embodiment and specific embodiment one is: the magnetic powder is Fe powder, Ni powder, Co powder, iron alloy powder, nickel alloy powder, cobalt alloy powder, iron-containing oxide powder, nickel-containing oxide One or a combination of powders and cobalt oxide powders are magnetic.
[0018] The iron alloy powder described in this embodiment is an alloy powder composed of iron element and one or more elements, and the mass fraction of iron is the largest, wherein the iron alloy powder can be Fe-Si-Al powder, Fe-Ni-Mo powder, Fe-Ni powder, Fe-Cu-Nb-Si-B powder, Fe-Pt powder, Fe-Ni-Cr powder, Fe-Zn powder, La-Co-Fe powder, Pb-Fe powder, W-Ni-Fe powder Powder and Zr-Ni-Sn-Fe powder or a combination of several of them.
[0019] The nickel alloy powder described in this embodiment is an alloy powder composed of nickel element and one or more elements, and the mass fraction of nickel is the largest, wherein the nickel all...
specific Embodiment approach 3
[0021] Specific Embodiment Three: The preparation method of a soft magnetic composite material provided in this embodiment is specifically completed according to the following steps:
[0022] 1. Put the magnetic powder into the cleaning agent and ultrasonicate at a frequency of 24KHz~35KHz for 10min~20min, filter to obtain the magnetic powder, add ethanol and oleic acid to it, and use ammonia water with a concentration of 20%~30% by mass to adjust the pH value of the solution to Adjust to 8.5~9.5, ultrasonically disperse at a frequency of 24KHz~35KHz for 1 hour~2 hours or stir at a speed of 600r / min~1200r / min for 1 hour~2 hours to obtain a solid-liquid mixture;
[0023] Among them, the mass ratio of oleic acid and magnetic powder is (0.03~0.2):1, the volume ratio of oleic acid and ethanol is 1:(40~75), and the magnetic powder is magnetic metal powder, magnetic metal alloy powder and One or a combination of several magnetic metal compound powders;
[0024] 2. Add ethanol to th...
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