Solder resist composition and printed circuit board
A technology of printed circuit boards and compositions, which is applied in the directions of printed circuits, printed circuit manufacturing, and secondary treatment of printed circuits, etc. It can solve the problems of white solder mask deterioration and coloring, reduced reflectivity, and insufficient absorption, etc., to achieve reflection suppression The effect of reducing the rate and increasing the illuminance
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[0078] Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not limited to a following example.
[0079] (A) Synthesis of carboxyl-containing resin without aromatic ring
Synthetic example 1
[0081] In a 2-liter detachable flask equipped with a stirrer, a thermometer, a reflux condenser, a dropping funnel, and a nitrogen introduction tube, 900 g of diglyme as a solvent, 21.4 g of peroxide (2 -Ethylhexanoic acid) tert-butyl (manufactured by NOF Corporation, trade name: PERBUTYL O), heated to 90°C. After heating, 309.9 g of methacrylic acid, 116.4 g of methyl methacrylate, and 109.8 g of lactone-modified 2-hydroxyethyl methacrylate (manufactured by Daicel Chemical Industries, Ltd., trade name: PLAC CEL FM 1), 21.4 g of bis(4-tert-butylcyclohexyl) peroxydicarbonate (manufactured by NOF Corporation, trade name: PERBUTYL TCP) as a polymerization initiator. Furthermore, this was aged for 6 hours to obtain a carboxyl group-containing copolymer resin. In addition, the above reaction was carried out under a nitrogen atmosphere.
[0082] Next, to the obtained carboxyl group-containing copolymer resin, 363.9 g of 3,4-epoxycyclohexylmethyl acrylate (manufactured by Daicel Ch...
Synthetic example 2
[0084] In a flask equipped with a thermometer, a stirrer, a dropping funnel, and a reflux condenser, add diethylene glycol monoethyl ether acetate as a solvent, and azobisisobutyronitrile as a catalyst, and heat it to A monomer in which methacrylic acid and methyl methacrylate were mixed dropwise at a molar ratio of 0.40:0.60 at 80°C for 2 hours. After further stirring for 1 hour, the temperature was raised to 115° C. to deactivate and obtain a resin solution.
[0085] After the resin solution is cooled, using tetrabutylammonium bromide as a catalyst, under the condition of 95-105°C and 30 hours, butyl glycidyl ether and the equivalent carboxyl group of the obtained resin are reacted at a molar ratio of 0.40. Addition reaction, and cool.
[0086] Furthermore, tetrahydrophthalic anhydride and the OH group of the resin obtained above were added-reacted at the molar ratio of 0.26 under the conditions of 95-105 degreeC, and 8 hours. It was taken out after cooling to obtain a sol...
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