Surface cleaning method of polished silicon substrate material

Abstract

The invention relates to a surface cleaning method of a polished silicon substrate material, which is characterized by comprising the following concrete steps of: taking 0.5-5 parts of nonionic surfactant, 0.1-5 parts of FA / OII type chelating agent, 0.1-5 parts of FA / O II type compound corrosion inhibitor and the balance of deionized water in parts by weight, and uniformly stirring to prepare a water-soluble surface cleaning solution with the pH value of 6.5-7.6; carrying out polishing cleaning on a silicon substrate material subjected to alkaline chemical-mechanical polishing by using the cleaning solution obtained in the step 1 under the conditions of less than 4000Pa of low pressure and 400-5000ml / minute of large flow, wherein the polishing cleaning time is at least 30 seconds-3 minutes, so that the surface of the silicon substrate material is clean. The invention has the advantages that low-pressure large-flow cleaning is carried out on the silicon substrate material by immediately using the cleaning solution after the polishing process in a CMP (Chemical-Mechanical Polishing) working procedure, and a clean and perfect polished surface can be obtained.

Description

technical field [0001] The invention belongs to the cleaning technology of semiconductor materials, in particular to a method for cleaning the surface of a silicon substrate material after CMP after polishing. Background technique [0002] Crystalline silicon is gray-black, belongs to atomic crystal, is hard and has metallic luster, and has semiconductor properties. The chemical properties of silicon are relatively active. It can combine with oxygen and other elements at high temperature. It is insoluble in water, nitric acid and hydrochloric acid, but soluble in hydrofluoric acid and lye. Monocrystalline silicon is an important semiconductor material used in the manufacture of high-power transistors, rectifiers, solar cells, and more. [0003] Silicon substrate is currently the most common substrate material. As a substrate material, the crystal surface is required to be ultra-smooth and ultra-clean. Studies have shown that the quality of the device depends largely on the...

AI Technical Summary

Problems solved by technology

[0004] The present invention aims to overcome the deficiencies in the prior art and provide a simple, easy, pollution-free and clean method for cleaning the surface of the silicon substrate material after polishing, which solves the problem of high energy on the surface of the silicon substrate wafer after the silicon substrate material is polished. Adsorption of abrasive particles causes surface scratches, residual polishing fluid has a high surface tension and is easy to spheroidize, and continues to chemically react with the surface of the silicon substrate, resulting in uneven corrosion of the silicon substrate, and the conversion of contaminated heavy metal ions into atoms and formation of silicon atoms on the surface of the silicon substrate Alloys cause heavy metal contamination of silicon substrates

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