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Device and method for comprehensively utilizing heat produced by decomposition of phosphorous gypsum in circulating fluid bed

A circulating fluidized bed and phosphogypsum technology, applied in chemical instruments and methods, sulfur compounds, inorganic chemistry, etc., can solve the problems of reducing and unfavorable weak reduction-monoxide double atmosphere conditions, increasing the difficulty and cost of acid production process, etc. To achieve the effect of improving the decomposition efficiency

Inactive Publication Date: 2010-11-10
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional air supply device and method blow in a large amount of air, which is not conducive to the formation of a weak reduction-oxidation double atmosphere condition, so the decomposition of phosphogypsum and SO 2 Concentration, etc. have adverse effects
Its main manifestation is that in order to maintain the fluidized state and fuel combustion, a large amount of fluidized air must be blown into the main furnace, so that the middle and lower parts of the bed cannot form stable weak reducing conditions during the decomposition of phosphogypsum, which is not conducive to phosphorus. Decomposition of gypsum and SO 2 generation, and a large amount of air also makes SO 2 The concentration is reduced due to dilution, which increases the difficulty and cost of the subsequent acid production process

Method used

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  • Device and method for comprehensively utilizing heat produced by decomposition of phosphorous gypsum in circulating fluid bed
  • Device and method for comprehensively utilizing heat produced by decomposition of phosphorous gypsum in circulating fluid bed
  • Device and method for comprehensively utilizing heat produced by decomposition of phosphorous gypsum in circulating fluid bed

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Raw material 1 Phosphogypsum

[0024] The main components of phosphogypsum are shown in the table below

[0025] Element

SO 3

CaO

SiO 2

Al 2 o 3

Fe 2 o 3

MgO

Total P 2 o 5

Total F

Na 2 o

K 2 o

moisture

content(%)

40.86

29.82

9.43

0.236

0.132

0.055

1.17

0.52

0.043

0.086

9.65

[0026] Raw material 2 raw coal

[0027] The carbon content of raw coal is 63.9%, the ash content is 28.67%, and the calorific value is 24.22MJ / kg. The raw material is collected in Chuxiong, Yunnan.

Embodiment approach

[0029] Under the condition of maintaining normal operating temperature (1000~1200℃), the phosphogypsum is evenly transported into the fluidized bed through the screw drying feeder at 930kg / h, and the fluidizing air volume is 700~800m 3 / h, the flue gas circulation rate is 10%, after multiple cycles of roasting, the clinker is mainly CaO, and the flue gas contains a high concentration of SO 2 .

[0030] Implementation results:

[0031] The clinker composition and flue gas composition analysis are as follows:

[0032]

[0033] Combined with data analysis, it can be known that CaSO 4 The decomposition rate is about 81.2%, SO 2 The volume fraction is 16.00%.

Embodiment 2

[0035] Raw material 1 Phosphogypsum

[0036] The main components of phosphogypsum are shown in the table below

[0037] Element

SO 3

CaO

SiO 2

Al 2 o 3

Fe 2 o 3

MgO

Total P 2 o 5

Total F

Na 2 o

K 2 o

moisture

content(%)

40.86

29.82

9.43

0.236

0.132

0.055

1.17

0.52

0.043

0.086

9.65

[0038] Raw material 2 raw coal

[0039] The carbon content of raw coal is 73.9%, the ash content is 28.67%, and the calorific value is 24.22MJ / kg. The raw material is collected in Chuxiong, Yunnan.

[0040] method of execution:

[0041] Under the condition of maintaining normal operating temperature (1000~1200℃), the phosphogypsum is evenly transported into the fluidized bed through the screw drying feeder at 930kg / h, and the fluidizing air volume is 700~800m 3 / h, the flue gas (120-200°C) circulation rate is 20%, after repeated cycles of roasting, the cli...

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Abstract

The invention discloses a device and a method for comprehensively utilizing heat produced by decomposition of phosphorous gypsum in a circulating fluid bed, namely, a novel fluidizing air supply device of an integrated device for utilizing the waste heat of a phosphorous gypsum decomposition circulating fluid bed and a method for reducing energy consumption and enhancing CaSO4 decomposition rate and SO2 concentration in the process of coproducing cement clinker and sulfuric acid by decomposing the phosphorous gypsum through the circulating fluid bed. A fluidizing air source consisting of air serving as a primary component and main circulating flue gas serving as a secondary component is adopted, a material is fed into a main furnace of the circulating fluid bed under the action of the gas force of circularly flowing flue gas and corresponding reformation is performed on an exhaust pipeline so as to fulfill the aim of exhausting and circulating the flue gas. A reaction atmosphere in the fluid bed can be controlled effectively and the phosphorous gypsum is decomposed under the condition of reduction-oxidation atmosphere, so that the decomposition efficiency of the phosphorous gypsum is improved. The comprehensive utilization of circulating flue gas having waste heat reduces energy loss in an air heating and material delivering process and further saves energy sources. Simultaneously, the circulating flue gas weakens the diluting effect of the fluidizing air on SO2 instead of a part of air, so that the aim of obtaining high-concentration SO2 is fulfilled.

Description

technical field [0001] The invention relates to a fluidized air supply device and an air supply mode of a phosphogypsum decomposition circulating fluidized bed waste heat utilization integrated device, especially in the comprehensive utilization, energy-saving and high-efficiency circulation flow of the thermal decomposition of phosphogypsum decomposed by a circulating fluidized bed The utility model relates to a fluidization air supply device for a fluidized bed boiler, which belongs to the technical field of solid waste recycling equipment. technical background [0002] Phosphogypsum is an industrial waste residue produced during the production of phosphoric acid, and its main component is CaSO 4 . At present, my country's phosphogypsum emissions have reached 30 million t / a. Pile of phosphogypsum occupies a lot of land, the soluble P 2 o 5 Harmful components such as fluoride and fluoride spread to the surrounding environment through water bodies, causing serious pollut...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B17/74C04B7/24
CPCY02P20/129Y02P40/10
Inventor 马丽萍牛学奎宁平郑绍聪张伟杜亚雷陈宇航
Owner KUNMING UNIV OF SCI & TECH
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