Device and method for comprehensively utilizing heat produced by decomposition of phosphorous gypsum in circulating fluid bed
A circulating fluidized bed and phosphogypsum technology, applied in chemical instruments and methods, sulfur compounds, inorganic chemistry, etc., can solve the problems of reducing and unfavorable weak reduction-monoxide double atmosphere conditions, increasing the difficulty and cost of acid production process, etc. To achieve the effect of improving the decomposition efficiency
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Embodiment 1
[0023] Raw material 1 Phosphogypsum
[0024] The main components of phosphogypsum are shown in the table below
[0025] Element
SO 3
CaO
SiO 2
Al 2 o 3
Fe 2 o 3
MgO
Total P 2 o 5
Total F
Na 2 o
K 2 o
content(%)
40.86
29.82
9.43
0.236
0.132
0.055
1.17
0.52
0.043
0.086
9.65
[0026] Raw material 2 raw coal
[0027] The carbon content of raw coal is 63.9%, the ash content is 28.67%, and the calorific value is 24.22MJ / kg. The raw material is collected in Chuxiong, Yunnan.
Embodiment approach
[0029] Under the condition of maintaining normal operating temperature (1000~1200℃), the phosphogypsum is evenly transported into the fluidized bed through the screw drying feeder at 930kg / h, and the fluidizing air volume is 700~800m 3 / h, the flue gas circulation rate is 10%, after multiple cycles of roasting, the clinker is mainly CaO, and the flue gas contains a high concentration of SO 2 .
[0030] Implementation results:
[0031] The clinker composition and flue gas composition analysis are as follows:
[0032]
[0033] Combined with data analysis, it can be known that CaSO 4 The decomposition rate is about 81.2%, SO 2 The volume fraction is 16.00%.
Embodiment 2
[0035] Raw material 1 Phosphogypsum
[0036] The main components of phosphogypsum are shown in the table below
[0037] Element
SO 3
CaO
SiO 2
Al 2 o 3
Fe 2 o 3
MgO
Total P 2 o 5
Total F
Na 2 o
K 2 o
content(%)
40.86
29.82
9.43
0.236
0.132
0.055
1.17
0.52
0.043
0.086
9.65
[0038] Raw material 2 raw coal
[0039] The carbon content of raw coal is 73.9%, the ash content is 28.67%, and the calorific value is 24.22MJ / kg. The raw material is collected in Chuxiong, Yunnan.
[0040] method of execution:
[0041] Under the condition of maintaining normal operating temperature (1000~1200℃), the phosphogypsum is evenly transported into the fluidized bed through the screw drying feeder at 930kg / h, and the fluidizing air volume is 700~800m 3 / h, the flue gas (120-200°C) circulation rate is 20%, after repeated cycles of roasting, the cli...
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