Film for manufacturing semiconductor device and method of manufacturing the same
A manufacturing method and semiconductor technology, applied in semiconductor/solid-state device manufacturing, lamination devices, manufacturing tools, etc., can solve problems such as film floating and peeling, and achieve the effect of preventing interface peeling and improving yield
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Embodiment 1
[0099]
[0100] In a reaction vessel equipped with a cooling pipe, a nitrogen introduction pipe, a thermometer and a stirring device, 88.8 parts of 2-ethylhexyl acrylate (hereinafter referred to as "2EHA"), 2-hydroxyethyl acrylate (hereinafter referred to as " HEA".) 11.2 parts, 0.2 parts of benzoyl peroxide, and 65 parts of toluene were polymerized at 61° C. for 6 hours in a nitrogen stream to obtain an acrylic polymer A with a weight average molecular weight of 850,000. The molar ratio of 2EHA to HEA is 100mol to 20mol. The measurement of the weight average molecular weight will be described later.
[0101] Add 12 parts of 2-methacryloyloxyethyl isocyanate (hereinafter referred to as "MOI") to this acrylic polymer A (80 mol% relative to HEA), and perform addition reaction treatment at 50°C in an air stream. After 48 hours, an acrylic polymer A' was obtained.
[0102] Next, 8 parts of an isocyanate-based crosslinking agent (trade name "Coronate L", manufactured by Nippon ...
Embodiment 2
[0127]
[0128] As the dicing film in this example, the same dicing film as in Example 1 was used.
[0129]
[0130] With respect to 100 parts of an acrylate-based polymer mainly composed of ethyl acrylate-methyl methacrylate (manufactured by Negami Industry Co., Ltd., trade name: Parachrom W-197CM, Tg: 18°C), an isocyanate-based crosslinking agent (manufactured by Nippon Polyurethane Co., Ltd., trade name Coronate HX) 2 parts, epoxy resin (manufactured by JER Co., Ltd., Epikote 1001) 35 parts, phenolic resin (manufactured by Mitsui Chemicals Co., Ltd., trade name: Milex XLC-4L) 37 parts, 30 parts of spherical silica (manufactured by Admatechs Co., Ltd., trade name: SO-25R, average particle diameter: 0.5 μm) as an inorganic filler were dissolved in methyl ethyl ketone to prepare a concentration of 21.4% by weight .
[0131] A solution of the adhesive composition is applied on the release-treated film (substrate separator) with a sprayer to form a coating layer, and hot ai...
reference example 1
[0150]
[0151] As the dicing film in this reference example, the same dicing film as in Example 1 was used.
[0152]
[0153] The dicing film in this reference example was carried out and produced similarly to Example 1 except having changed the addition amount of the inorganic filler to 95 parts.
[0154]
[0155] The dicing / die-bonding film in this reference example was produced in the same manner as in Example 1 above.
[0156] (Measuring method of tensile elastic modulus of adhesive layer)
[0157] From the slit film in each example and comparative example, cut out a length of 10.0 mm, a width of 2 mm, and a cross-sectional area of 0.1 to 0.5 mm 2 of samples. The sample was subjected to a tensile test in the MD direction at a measurement temperature of 23° C., a distance between clamps of 50 mm, and a tensile speed of 50 mm / min, and the amount of change (mm) due to elongation of the sample was measured. Thus, in the obtained S-S (Strain-Strength) curve, a tange...
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