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Lead-free piezoceramic-polyvinyl alcohol (PVA) piezoelectric composite material and preparation method thereof

A technology of polyvinyl alcohol piezoelectric, piezoelectric composite materials, applied in material selection for piezoelectric devices or electrostrictive devices, manufacturing/assembly of piezoelectric/electrostrictive devices, piezoelectric devices/electrostrictive Devices, etc., can solve problems such as human and ecological environment damage, and achieve good piezoelectric and dielectric properties, simple process, and easy-to-obtain materials

Inactive Publication Date: 2010-03-03
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because lead in lead-based ceramics and ceramics and polymer materials will cause serious damage to humans and the ecological environment

Method used

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  • Lead-free piezoceramic-polyvinyl alcohol (PVA) piezoelectric composite material and preparation method thereof
  • Lead-free piezoceramic-polyvinyl alcohol (PVA) piezoelectric composite material and preparation method thereof
  • Lead-free piezoceramic-polyvinyl alcohol (PVA) piezoelectric composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] According to formula (1-x)(K b Na 1-b )NbO 3 -xLiSbO 3 (x=0.05, b=0.5) mix ceramic powder raw material, make piezoelectric composite material sample with PVA again by following volume percentage, its XRD collection of patterns is as follows figure 1 As shown, the performance parameters of the test are shown in Table 1:

[0034] Table 1

[0035] KNNLS and PVA body

Embodiment 2

[0037] According to formula (1-x)(K b Na 1-b )NbO 3 -xLiNbO 3 (x=0.06, b=0.48) mix ceramic powder raw material, make piezoelectric composite material sample with PVA again by following volume percentage, its XRD collection of patterns is as follows figure 2 As shown, the performance parameters of the test are shown in Table 2:

[0038] Table 2

[0039] KNLN and PVA

Embodiment 3

[0041] According to formula (1-x)(K b Na 1-b )NbO 3 -xBiScO 3 -yMnCO 3 (x=0.02, b=0.5, y=0.008) mix ceramic powder raw material, make piezoelectric composite material sample with PVA again by following volume percentage, its XRD collection of patterns is as follows image 3 As shown, the performance parameters of the test are shown in Table 3:

[0042] table 3

[0043] KNNBSM and PVA

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Abstract

The invention relates to a potassium-sodium niobate based lead-free piezoceramic-polyvinyl alcohol (PVA) piezoelectric composite material and a preparation method thereof. The preparation method comprises the following steps: mixing materials according to a formula (1-x)(LiaNabK1-a-b)(Nb1-cSbc)O3-xABO3-yM, adopting analytical pure anhydrous carbonate or oxide as the raw material, and using the traditional ceramic preparation technique to prepare ceramic powder; mixing the ceramic powder and polyvinyl alcohol into mixed powder according to a volume ratio of 5 / 90 to 95 / 5, adding deionized waterto the mixed powder and heating to dissolve the PVA; and then carrying out ultrasonic dispersion, drying the mixed powder, then conducting cold-pressing and forming by a sheet-pressing machine, then using a muffle furnace for heating treatment, finally sputtering metal electrodes on the surface thereof, carrying out silicon oil bath for polarization, finally obtaining the potassium-sodium niobatebased lead-free piezoceramic-polyvinyl alcohol piezoelectric composite material. The piezoelectric composite material is pure perovskite crystal phase, has no mixed phase and has good piezoelectric performance and dielectric property.

Description

technical field [0001] The invention relates to a preparation technology of a piezoelectric composite material, in particular to a piezoelectric composite material of potassium sodium niobate (KNN) lead-free piezoelectric ceramics and polyvinyl alcohol (PVA) and a preparation method thereof, belonging to piezoelectric composite field of materials technology. Background technique [0002] Polymer-based piezoelectric composites have good flexibility and machinability, and can be processed into large-area sheets or complex shapes. The polymer-based piezoelectric composite material has a small density ρ, a low sound velocity υ, and a low acoustic impedance Z=ρυ, which is easy to achieve acoustic impedance matching with underwater acoustics and biological tissues. Polymer-based piezoelectric composites due to the dielectric constant (ε 33 ) is low, and the piezoelectric voltage coefficient g 33 high. Compared with polymers, polymer-based piezoelectric composites have higher p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L41/22H01L41/18H01L41/08C04B26/04C08L29/04C08K3/24H10N30/00H10N30/092H10N30/85
Inventor 朱基亮李绪海王明松蒋猛朱建国肖定全
Owner SICHUAN UNIV
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