High-k gate dielectric material and preparation method thereof
A technology of gate dielectric and thin film, applied in the field of high-k gate dielectric material and its preparation, amorphous Er2O3-Al2O3 high-K gate dielectric composite oxide thin film, which can solve the problem of low crystallization temperature, increased diffusion of impurities at grain boundaries, leakage High crystallization temperature, good flatness, and wide band gap can be achieved without problems such as current increase
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[0038] The preparation method of the high-k gate dielectric material of the present invention comprises the following steps:
[0039] Select a P-type Si (100) substrate, the resistivity of the silicon wafer is 2-10 Ω cm, the substrate temperature is room temperature, and the Er 2 o 3 and Al 2 o 3 On the P-type Si(100) substrate, the ErAlO amorphous composite oxide film is formed by radio frequency magnetron sputtering. The purity of the mixed ceramic target material is 99.99%, Al 2 o 3 Accounting for 30% molar ratio, RF power is 40W, sputtering gas is Ar and O 2 , oxygen partial pressure ratio P=P(O 2 ) / ((P(O 2 )+P(Ar)) are 0%, 1% and 3%, the working pressure is 1.0Pa, and the P-type (100) silicon wafer with a resistivity of 2-10Ω·cm is ultrasonically cleaned with deionized water for 10 minutes before growth, and then Etch with 1% HF acid for 30 s to remove the natural oxide layer on the surface of the Si substrate, and finally send it into the growth chamber for 30 min...
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