Binder resin emulsion for energy device electrode, and energy device electrode and energy device using the same
A binder resin and energy technology, applied in battery electrodes, electrolytic capacitors, hybrid capacitor electrodes, etc., can solve the problems of difficulty in ion adsorption and desorption, increase in electrode resistance of capacitors, etc., achieve low resistance, improved charge and discharge characteristics, Excellent penetration effect
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Embodiment 1
[0141] Prepare a 2 L separable flask equipped with a stirrer, thermometer and condenser. An ethylene-methacrylic acid copolymer (MFR: 60 g / 10 minutes, ethylene unit / methacrylic acid unit=80 / 20 (mass ratio), melting point: 87° C.) 150 g, purified water 826.7 g, and N, N-dimethylethanolamine 23.3 g as a neutralizing agent (the amount corresponding to neutralizing 75 mol% of the carboxyl groups of the copolymer) . After raising the temperature to 95° C. while stirring the contents of the flask, it was kept at the same temperature for 1 hour, and the copolymer was water-dispersed and emulsified by neutralization reaction. Next, the temperature was lowered to 88° C. and kept at the same temperature for 3 hours to complete the neutralization reaction, and then cooled to room temperature to obtain the binder resin emulsion of the present invention. The average particle diameter of the obtained emulsion was about 0.13 μm, and the non-volatile matter after drying under normal pressu...
Embodiment 2
[0162] According to making the dry mass of the mixture layer be about 12.5mg / cm 2 , the slurry prepared in the above test (1) was uniformly coated on one side surface of a negative electrode current collector (manufactured by Hitachi Electric Cable Co., Ltd., rolled copper foil, thickness 14 μm, 200×100 mm) with a micro coater. Then, it dried under normal pressure at 80 degreeC for 1 hour, and formed the mixture layer. Then, according to making the bulk density of the mixture layer be 1.5g / cm 3 or 1.8g / cm 3 , After compression molding with a roller press, punch a 9mmΦ hole with a punching machine. This was subjected to vacuum heat treatment at 120° C. for 5 hours to prepare a negative electrode in which a mixture layer made of the binder resin emulsion of the present invention and an active material was provided on the surface.
Embodiment 3
[0166] According to making the dry mass of the mixture layer be about 29mg / cm 2 , the slurry prepared in the above test (1) was evenly coated on both sides of the negative electrode current collector (manufactured by Hitachi Electric Cable Co., Ltd., rolled copper foil, thickness 10 μm, 200×100 mm) with a transfer roller. Then, the coating is dried for 5 minutes with a conveyor oven at 120° C. to form a mixture layer, and the bulk density of the mixture layer is 1.8 g / cm 3 , Compression molding with a roller press. It was cut into a 56 mm square to make a short thin sheet, which was subjected to vacuum heat treatment for 5 hours in a vacuum dryer at 120° C. to make a negative electrode.
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