Sunlight controlled transparent film in low radiation, prepartion method and application
A transparent film and sunlight control technology, which is applied in the field of organic polymer and nano-inorganic particle composite film, can solve the problems of limited application, achieve the effects of increasing heat preservation and energy saving, overcoming environmental pollution, and good transparency of visible light
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Embodiment 1
[0050] (1) The indium oxide nanopowder coarse product that buys 3wt% tin doping is mixed with DMF, cyclohexanone, butylamine, Tween 80 by the weight percentage of Table 1-1, and add diameter is 0.8 millimeters of oxide The zirconium microbeads are sand-milled to separate the zirconia beads, and a solution system in which tin-doped indium oxide particles are uniformly dispersed with an average particle diameter of 25 nanometers is obtained.
[0051] Table 1-1:
[0052] composition weight percentage (%) 3wt% tin-doped indium oxide nanopowder coarse product 32.47 DMF 32.46 Cyclohexanone 32.47 Butylamine 1.3 Tween 80 1.3
[0053] A solution system in which the above-mentioned tin-doped indium oxide is uniformly dispersed, polyvinyl chloride, vinyltrimethoxysilane, dioctyl phthalate, 2-(2'hydroxy-5'-methylphenyl)benzo Triazole, antioxidant CA and TPP are mixed in a weight ratio of 2:100:2:25:1.5:1.3:0.5, and the volatile small molecule...
Embodiment 2
[0060] (1) Mix the purchased 18wt% tin-doped indium oxide nanopowder coarse product with the dispersion medium and dispersant in the ratio of Table 2-1, and carry out sand grinding with zirconia microbeads with a diameter of 0.8 mm to separate the oxide Zirconium beads to obtain a solution system in which tin-doped indium oxide particles have an average particle size of 80 nanometers and are uniformly dispersed.
[0061] table 2-1:
[0062] composition weight percentage (%) 18wt% tin-doped indium oxide crude product 31.85 Cyclohexanone 31.85 Chloroform 31.85 Dodecanoic acid 1.27 span 80
3.18
[0063] A solution in which the above-mentioned tin-doped indium oxide nanoparticles are uniformly dispersed, polyvinyl chloride, vinyltrimethoxysilane, dioctyl phthalate, 2-hydroxy-4-methoxybenzophenone, antioxidant The agent CA and TPP are mixed according to the weight ratio of 6:100:2:30:1.5:1:0.5, and the volatile small molecule solvent...
Embodiment 3
[0070] (1) make 7wt% antimony-doped tin oxide nanopowder rough product by oneself according to aforementioned document, this thick product mixes with the other composition of table 3-1 in the ratio shown, and be sand with the zirconia bead of 0.8 millimeters in diameter The grinding medium is sanded, and then the zirconia beads are separated to obtain a uniform dispersion of 7 wt% antimony-doped tin oxide nanoparticles, wherein the average particle size of the antimony-doped tin oxide particles is 50 nanometers. Mix the above-mentioned antimony-doped tin oxide nanoparticles uniformly dispersed solution, polystyrene, vinyltrimethoxysilane, and epoxy soybean oil in a weight ratio of 15:100:2:2:1.5, and then vacuum Remove the volatile small molecule solvent in the oven to obtain the masterbatch, the composition of which is shown in Table 3-2. The weight percent in Table 3-2 refers to the proportion of each component in the masterbatch.
[0071] Table 3-1
[0072] comp...
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