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Sunlight controlled transparent film in low radiation, prepartion method and application

A transparent film and sunlight control technology, which is applied in the field of organic polymer and nano-inorganic particle composite film, can solve the problems of limited application, achieve the effects of increasing heat preservation and energy saving, overcoming environmental pollution, and good transparency of visible light

Inactive Publication Date: 2009-02-25
长春迪高实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The preparation of solar control low-E coatings by solution coating is a relatively low-cost method, but the dispersion medium of the solution is a highly toxic organic solvent, which limits the application of this method

Method used

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  • Sunlight controlled transparent film in low radiation, prepartion method and application

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] (1) The indium oxide nanopowder coarse product that buys 3wt% tin doping is mixed with DMF, cyclohexanone, butylamine, Tween 80 by the weight percentage of Table 1-1, and add diameter is 0.8 millimeters of oxide The zirconium microbeads are sand-milled to separate the zirconia beads, and a solution system in which tin-doped indium oxide particles are uniformly dispersed with an average particle diameter of 25 nanometers is obtained.

[0051] Table 1-1:

[0052] composition weight percentage (%) 3wt% tin-doped indium oxide nanopowder coarse product 32.47 DMF 32.46 Cyclohexanone 32.47 Butylamine 1.3 Tween 80 1.3

[0053] A solution system in which the above-mentioned tin-doped indium oxide is uniformly dispersed, polyvinyl chloride, vinyltrimethoxysilane, dioctyl phthalate, 2-(2'hydroxy-5'-methylphenyl)benzo Triazole, antioxidant CA and TPP are mixed in a weight ratio of 2:100:2:25:1.5:1.3:0.5, and the volatile small molecule...

Embodiment 2

[0060] (1) Mix the purchased 18wt% tin-doped indium oxide nanopowder coarse product with the dispersion medium and dispersant in the ratio of Table 2-1, and carry out sand grinding with zirconia microbeads with a diameter of 0.8 mm to separate the oxide Zirconium beads to obtain a solution system in which tin-doped indium oxide particles have an average particle size of 80 nanometers and are uniformly dispersed.

[0061] table 2-1:

[0062] composition weight percentage (%) 18wt% tin-doped indium oxide crude product 31.85 Cyclohexanone 31.85 Chloroform 31.85 Dodecanoic acid 1.27 span 80

3.18

[0063] A solution in which the above-mentioned tin-doped indium oxide nanoparticles are uniformly dispersed, polyvinyl chloride, vinyltrimethoxysilane, dioctyl phthalate, 2-hydroxy-4-methoxybenzophenone, antioxidant The agent CA and TPP are mixed according to the weight ratio of 6:100:2:30:1.5:1:0.5, and the volatile small molecule solvent...

Embodiment 3

[0070] (1) make 7wt% antimony-doped tin oxide nanopowder rough product by oneself according to aforementioned document, this thick product mixes with the other composition of table 3-1 in the ratio shown, and be sand with the zirconia bead of 0.8 millimeters in diameter The grinding medium is sanded, and then the zirconia beads are separated to obtain a uniform dispersion of 7 wt% antimony-doped tin oxide nanoparticles, wherein the average particle size of the antimony-doped tin oxide particles is 50 nanometers. Mix the above-mentioned antimony-doped tin oxide nanoparticles uniformly dispersed solution, polystyrene, vinyltrimethoxysilane, and epoxy soybean oil in a weight ratio of 15:100:2:2:1.5, and then vacuum Remove the volatile small molecule solvent in the oven to obtain the masterbatch, the composition of which is shown in Table 3-2. The weight percent in Table 3-2 refers to the proportion of each component in the masterbatch.

[0071] Table 3-1

[0072] comp...

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Abstract

This invention relates to a method for preparing low-radiation heat-insulating transparent film for controlling sunlight. The film is composed of: organic polymer 70-99.9 wt. %, doping metal oxide nanoparticles 0.1-30 wt. % and adjuvant 0-29.9 wt. %. The method comprises: (1) uniformly dispersing the doping metal oxide nanoparticles into a dispersing medium, mixing with the organic polymer and the adjuvant, and drying to obtain master batches; (2) plasticizing, smelting or extruding and blowing, calendaring, stretching, extruding and casting to obtain the film. The film can be used as the coating film for architecture glass, automobile window and ship window, and has such advantages as high visible-light permeability, good sunlight obstructing effect, good anti-electrostatic effect, and good electromagnetic radiation resistance.

Description

technical field [0001] The invention relates to a composite film of organic macromolecules and nano-inorganic particles, in particular to a sunlight-controlling, low-radiation, heat-preserving, energy-saving transparent film and a preparation method and use thereof. Background technique [0002] 98% of the solar energy projected on the surface of the earth has a wavelength in the range of 0.3-2.5 μm, which can be divided into three parts according to its wavelength, namely ultraviolet light, visible light and infrared light. Ultraviolet light (accounting for 3%) is invisible light with a wavelength of less than 380nm; visible light (accounting for 45%) has a wavelength of 380-780nm; infrared light (accounting for 49%) is also invisible and its wavelength is higher than 780nm. The thermal insulation and energy-saving effect of glass or windows is usually characterized by the value of shading coefficient (Sc) and heat transfer coefficient (U), and these two parameters can be u...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J5/18C08L25/06C08L23/00C08K3/22
Inventor 曹新宇韩勇江雷
Owner 长春迪高实业有限公司
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