Methods for Casting By a Float Process and Associated Apparatuses

Abstract

A method for producing a solid layer material (42), comprising providing (70) a first layer (30); providing (72) a second liquid layer (32) on the first layer (30); providing (74) a third liquid layer (34) on the second liquid layer (32), wherein the third liquid layer has a melting point that is higher than a melting point of the second liquid layer, and wherein the second liquid layer is between the first and third layers; cooling (76) a surface of the third liquid layer to a temperature less than the melting point of the third liquid layer; forming (78) the solid layer from the third liquid layer while cooling the third layer liquid; and removing (80) the solid layer.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application claims priority from U.S. Provisional Patent Application No. 61 / 199,238, filed Nov. 14, 2008, which is incorporated herein by reference.FIELD OF THE INVENTION[0002]The present invention is directed generally to methods for casting by a float process and for associated apparatuses and, for example, to such methods and apparatuses related to the production of silicon and solar cells.BACKGROUND OF THE INVENTION[0003]Many industries and products process semiconductors and semiconductor wafers into other products, such as microprocessors, computer memory, solar cells, and other devices. Semiconductor wafer have become a commodity in many cases, but the process of making wafers is still largely inefficient.[0004]In the conventional wafering process, multi-crystalline (mc) and single-crystalline (sc) Silicon (Si) wafers are obtained by unidirectional slicing of Silicon ingots. Such processes currently account for more than 90% o...

AI Technical Summary

Benefits of technology

The present invention is about methods and apparatuses for casting silicon and solar cells using a float process. The invention allows for the production of high-quality silicon with useful properties for solar cells and other applications. The invention also offers advantages such as the use of cheap raw materials, rapid scale-up, and reduced costs relative to current methods. The invention uses a molten layer of modified aluminosilicate glass as a dielectric layer, which helps to purify the silicon and minimize chemical interactions. The invention can control the thickness of the silicon sheets and produce them continuously with even surfaces. The invention also involves the use of a glassy slag layer to support the molten substrate and minimize entrainment. The invention offers a more efficient and cost-effective way to produce high-quality silicon and solar cells.

Problems solved by technology

Semiconductor wafer have become a commodity in many cases, but the process of making wafers is still largely inefficient.

Making solar cells from single and multi-crystalline ingots of high purity Silicon is energy and capital intensive.

The process is difficult to scale up due to the batch nature of many of the processing steps and the wafer process is inefficient.

The wires used to cut the slabs into wafers are as thick as the wafers themselves and half of the material is therefore lost in the sawing process.

This cutting material is difficult to recycle since it is mixed with iron from the wire and cutting oil.

These issues make it difficult and inefficient to make very thin wafers.

These deficiencies are particularly problematic in the production of solar cells where production cost is one factor which limits widespread acceptance.

Due to the polycrystalline nature of the seed layer, heavily defective grains always remain present in the epitaxial layer.

As observed in the float glass process, defects arise when the voltatilized materials from the molten surface are advected and diffused in the gas flow followed by their dropping on the top surface glass.

These polysilicon films are limited by the non-uniformity and low electron mobility.

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