Superfine chromium-supported chromium-replenishing feedstuff addictive, its preparation and application method
A feed additive and loaded technology, which is applied to the chromium-supplemented feed additive of loaded ultra-fine chromium and its preparation and application fields, can solve the problems such as the reduction of anti-oxidation, achieve the effect of convenient use and solve the problems of agglomeration and stability
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[0023] Due to the very high specific surface energy of nanoparticles, if they are not treated during the preparation process, the obtained nanoparticles often lose many of the properties of nanoparticles due to agglomeration, which limits their research and application. In order to overcome the agglomeration of nanoparticles, stabilizers, such as polymers and surfactants, are generally added to coat the surface of nanoparticles during the reaction process to reduce their surface energy. In recent years, using the confinement effect of nano-reactors, such as the nano-water center in the center of capsules and microemulsion droplets as the reaction medium, uniformly dispersed nanoparticles with smaller particle sizes can be obtained. Similarly, some porous mineral materials with nanopores in their structure also have a confinement effect and can be used as a carrier and medium for manufacturing nanostructure assembly materials. The present invention utilizes the nanopore structu...
Embodiment 1
[0032] 1) Grinding the montmorillonite produced in Inner Mongolia to 300 mesh, adding water and stirring evenly to make a suspension slurry with a concentration of 10%;
[0033] 2) Pre-configure chromium chloride containing 0.05% chromium by weight of montmorillonite into 0.1mol / L chromium chloride aqueous solution, slowly add it into the suspension slurry in step 1) under stirring, and then slowly add the molar ratio Sodium borohydride 3 times that of chromium chloride was reacted at 40°C for 15 hours;
[0034] 3) centrifugal dehydration of the suspension slurry in step 2);
[0035] 4) Drying and crushing the filter cake obtained in step 3) to 300 meshes to obtain a chromium-replenishing feed additive of loaded superfine chromium.
[0036] The transmission electron microscope observation shows that the average particle size of the ultrafine chromium powder supported by montmorillonite is 10nm, and the particle size distribution is between 5nm and 25nm. The content of chromi...
Embodiment 2
[0038] 1) Grinding the clinoptilolite produced in Jinyun, Zhejiang to 400 mesh, adding water and stirring evenly to make a suspension slurry with a concentration of 1%;
[0039] 2) Pre-configure chromium nitrate with a chromium content of 0.1% by weight of the zeolite into a 1 mol / L chromium nitrate aqueous solution, slowly add it into the suspension slurry in step 1) under stirring, and then slowly add a molar ratio of 6 times that of chromium nitrate Potassium borohydride, reacted at 80°C for 10 hours;
[0040] 3) the suspension slurry in step 2) is filtered and dehydrated;
[0041] 4) Drying and crushing the filter cake obtained in step 3) to 500 meshes to obtain a chromium-replenishing feed additive of loaded superfine chromium.
[0042] The transmission electron microscope observation shows that the average particle size of the zeolite-loaded ultrafine chromium powder is 18nm, and the particle size distribution is between 12 and 28nm. The content of chromium in the zeol...
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