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Superfine chromium-supported chromium-replenishing feedstuff addictive, its preparation and application method

A feed additive and loaded technology, which is applied to the chromium-supplemented feed additive of loaded ultra-fine chromium and its preparation and application fields, can solve the problems such as the reduction of anti-oxidation, achieve the effect of convenient use and solve the problems of agglomeration and stability

Inactive Publication Date: 2006-09-06
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, as the particle size of metal copper powder and metal iron powder decreases, their oxidation resistance also decreases. Therefore, how to solve the contradiction between particle size and stability is a major problem in the practical application of ultrafine powder.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach

[0023] Due to the very high specific surface energy of nanoparticles, if they are not treated during the preparation process, the obtained nanoparticles often lose many of the properties of nanoparticles due to agglomeration, which limits their research and application. In order to overcome the agglomeration of nanoparticles, stabilizers, such as polymers and surfactants, are generally added to coat the surface of nanoparticles during the reaction process to reduce their surface energy. In recent years, using the confinement effect of nano-reactors, such as the nano-water center in the center of capsules and microemulsion droplets as the reaction medium, uniformly dispersed nanoparticles with smaller particle sizes can be obtained. Similarly, some porous mineral materials with nanopores in their structure also have a confinement effect and can be used as a carrier and medium for manufacturing nanostructure assembly materials. The present invention utilizes the nanopore structu...

Embodiment 1

[0032] 1) Grinding the montmorillonite produced in Inner Mongolia to 300 mesh, adding water and stirring evenly to make a suspension slurry with a concentration of 10%;

[0033] 2) Pre-configure chromium chloride containing 0.05% chromium by weight of montmorillonite into 0.1mol / L chromium chloride aqueous solution, slowly add it into the suspension slurry in step 1) under stirring, and then slowly add the molar ratio Sodium borohydride 3 times that of chromium chloride was reacted at 40°C for 15 hours;

[0034] 3) centrifugal dehydration of the suspension slurry in step 2);

[0035] 4) Drying and crushing the filter cake obtained in step 3) to 300 meshes to obtain a chromium-replenishing feed additive of loaded superfine chromium.

[0036] The transmission electron microscope observation shows that the average particle size of the ultrafine chromium powder supported by montmorillonite is 10nm, and the particle size distribution is between 5nm and 25nm. The content of chromi...

Embodiment 2

[0038] 1) Grinding the clinoptilolite produced in Jinyun, Zhejiang to 400 mesh, adding water and stirring evenly to make a suspension slurry with a concentration of 1%;

[0039] 2) Pre-configure chromium nitrate with a chromium content of 0.1% by weight of the zeolite into a 1 mol / L chromium nitrate aqueous solution, slowly add it into the suspension slurry in step 1) under stirring, and then slowly add a molar ratio of 6 times that of chromium nitrate Potassium borohydride, reacted at 80°C for 10 hours;

[0040] 3) the suspension slurry in step 2) is filtered and dehydrated;

[0041] 4) Drying and crushing the filter cake obtained in step 3) to 500 meshes to obtain a chromium-replenishing feed additive of loaded superfine chromium.

[0042] The transmission electron microscope observation shows that the average particle size of the zeolite-loaded ultrafine chromium powder is 18nm, and the particle size distribution is between 12 and 28nm. The content of chromium in the zeol...

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PUM

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Abstract

The invention discloses feed addictive carrying super fine chromium and the preparing and usage method. The super fine chromium is carried by porous mineral material, the average grain size of chromium is smaller than100 nanometer, and the chromium content in the porous mineral material is 0.05-0.5% by weight percent. The invention employs porous mineral material as microreactor, and adds reducer to reduce chromate salt to chromium. The bore diameter of porous material is uniform, and so the distribution of grain size of chromium is narrow. The chromium powder is characterized by low toxicity and high effective, and can be used for cow, sheep, poultry and aquatic creature, and the powder is easy to mix with feed stuff.

Description

technical field [0001] The invention relates to a chromium-supplementing feed additive loaded with superfine chromium and a preparation and use method thereof, in particular to a chromium-supplementing feed additive loaded with ultrafine chromium powder by a porous mineral material and a preparation and use method thereof. Background technique [0002] Chromium is a transition metal element first discovered in 1797 by a French chemist (Louis Vanquelin). In 1957, Mertz and Schwarz first proposed the glucose tolerance factor (glucose tolerance factor, GTF) hypothesis, and in 1959 it was confirmed that chromium is an essential element for the growth and maintenance of GTF in rats. The biological function of chromium: [0003] (1) Improving the immunity of animals: Adding chromium to the feed can stimulate lymphocytes to produce immune stress products to improve the immunity of animals. [0004] (2) Improve animal carcass quality: A large number of studies have shown that chro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A23K1/16A23K20/20
Inventor 胡彩虹夏枚生赵文艳
Owner ZHEJIANG UNIV
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