Paper-plastic lamination adhesive and method for preparing same
A laminating adhesive and paper-plastic technology, applied in the direction of surface covering paper, adhesive type, ester copolymer adhesive, etc., can solve the problems of poor aging resistance, low sticking force, low cohesive force, etc. Achieve the effect of improving heat resistance and aging resistance, improving cohesive strength and heat resistance, improving cohesive force and bonding strength
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Embodiment 1
[0079] Preparation of Laminating Adhesive 1
[0080] (1) Weigh 3.0g of composite emulsifier, 35g of water, place in a pre-emulsification kettle, stir, weigh 2g of acrylic acid, 4g of methacrylic acid, 8g of styrene, 36g of butyl acrylate, 45g of isooctyl acrylate, and 5g of hydroxyethyl acrylate and 1g of N-hydroxyacrylamide are mixed and added to the pre-emulsification kettle, pre-emulsified for 30-40min, and set aside.
[0081] (2) Take 0.6g of sodium bicarbonate and 38g of water, put them in a 500ml four-neck flask equipped with an electric stirrer, a thermometer, and a condensing reflux device, raise the temperature of the water bath heating device to 75-85°C while stirring, and put 0.2g Potassium persulfate was dissolved in 4g of water and added to a four-neck flask.
[0082] (3) drop the emulsion prepared in step (1), dissolve 0.5g potassium persulfate in 25g water, add dropwise at the same time, the time of dropping is controlled at 2~4h, then 70~85°C is incubated for ...
Embodiment 2
[0091] Preparation of laminating glue 2
[0092] (1) Weigh 2.5g of compound emulsifier, 30g of water, place in a pre-emulsification kettle, stir, weigh 2g of acrylic acid, 4g of methacrylic acid, 29g of styrene, 20g of butyl acrylate, 40g of isooctyl acrylate, and 5g of hydroxyethyl acrylate and 1g of N-hydroxyacrylamide are mixed and added to the pre-emulsification kettle, pre-emulsified for 30-40min, and set aside.
[0093] (2) Take 0.6g of sodium bicarbonate, 0.5g of compound emulsifier, and 43g of water, place them in a 500ml four-neck flask with an electric stirrer, a thermometer, and a condensing reflux device, and raise the temperature of the water bath heating device to 75-75% while stirring. At 85°C, dissolve 0.2g of potassium persulfate in 4g of water and add it to a four-neck flask.
[0094] (3) drop the emulsion prepared in step (1), dissolve 0.5g potassium persulfate in 25g water, add dropwise at the same time, the time of dropping is controlled at 2~4h, then 70~...
Embodiment 3
[0103] Preparation of Laminating Adhesive 3
[0104] (1) Weigh 0.3g of composite emulsifier, 5g of water, place in a pre-emulsification kettle, stir, weigh 0.2g of acrylic acid, 0.8g of methacrylic acid, 6g of styrene, 6g of butyl acrylate, and 7g of isooctyl acrylate and mix Then slowly add to the pre-emulsification kettle, pre-emulsify for 30-40 minutes, and set aside.
[0105] (2) Weigh 2.7g of composite emulsifier, 30g of water, place in a pre-emulsification kettle, stir, weigh 0.8g of acrylic acid, 3.2g of methacrylic acid, 20g of styrene, 28g of butyl acrylate, 25g of isooctyl acrylate, 1g of hydroxyethyl methacrylate and 4g of N-hydroxyacrylamide are mixed and added to the pre-emulsification kettle, pre-emulsified for 30-40min, and set aside.
[0106](3) Take 0.6g of sodium bicarbonate and 38g of water, put them in a 500ml four-necked flask equipped with an electric stirrer, a thermometer, and a condensing reflux device, raise the temperature of the water bath heating ...
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