Novel high-strength phosphorus magnesium silicate cement and preparation method thereof
A magnesium phosphosilicate, high-strength technology, applied in the field of new building materials, can solve the problems of short setting and hardening time, inability to pour and form, and high price of magnesium phosphate cement, achieve good mechanical properties and water resistance, and enhance mechanical properties and resistance. Water performance, the effect of reducing production energy consumption and production costs
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[0019] Another aspect of the embodiments of the present invention also provides a method for preparing a novel high-strength phospho-magnesium silicate cement, comprising: mixing a first active magnesium oxide, a second active magnesium oxide, an active silica-containing raw material, and phosphoric acid. A new type of high-strength magnesium silicate cement is prepared by mixing monohydrogen salt and basic magnesium sulfate whiskers.
[0020] In some embodiments, the preparation method specifically includes: mixing the first active magnesium oxide, the second active magnesium oxide, the raw material containing active silicon dioxide and basic magnesium sulfate whiskers to obtain mixed powder; After the mixed powder and the monohydrogen phosphate solution are mixed, the cement hardens to obtain the novel high-strength magnesium phosphosilicate cement.
[0021] In some more specific embodiments, the preparation process of the novel high-strength magnesium phosphosilicate cement...
Embodiment 1
[0040] 50g light calcined powder magnesia was calcined at 1000 ℃ for 2 hours to obtain the first active magnesia; 50g light calcined powder magnesia and 2.5g potassium dihydrogen phosphate were mixed and ground, and calcined at 1000 ℃ for 2 hours to obtain the second active oxidation Magnesium, then two kinds of active magnesium oxide are mixed uniformly according to the mass ratio of 1:1 to obtain mixed powder. Calculated according to a certain water-cement ratio, the active magnesium oxide is mixed with 40% mass fraction of silica fume, 1 g of basic magnesium sulfate whiskers, and mixed with 50 g of potassium monohydrogen phosphate to prepare a slurry, shape, at 20 ± 3 ° C and relative humidity of 50 After curing at ±5% for 24 hours, a cement-based material, that is, a new type of high-strength magnesium phosphosilicate cement is obtained. The setting time is 92min, the compressive strength is 28.6Mpa after 1 day, 76.3Mpa after 3 days, 103Mpa after 7 days, 110.5Mpa after 28 ...
Embodiment 2
[0042] 50g light calcined powder magnesia was calcined at 1000 ℃ for 2 hours to obtain the first active magnesia; 50g light calcined powder magnesia and 2.5g potassium dihydrogen phosphate were mixed and ground, and calcined at 1000 ℃ for 2 hours to obtain the second active oxidation Magnesium, then two kinds of active magnesium oxide are mixed uniformly according to the mass ratio of 1:1 to obtain mixed powder. According to the calculation of a certain water-cement ratio, the active magnesium oxide was mixed with 40% mass fraction of silica fume, 1g of basic magnesium sulfate whiskers, and mixed with 33.3g of potassium monohydrogen phosphate to prepare a slurry, and molded at 20±3°C and relative humidity. After curing at 50±5% for 24 hours, a cement-based material, that is, a new type of high-strength magnesium phosphosilicate cement is obtained. The setting time is 115min, the compressive strength is 18.5Mpa after 1 day, 46.8Mpa after 3 days, 79.5Mpa after 7 days, 85.0Mpa af...
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