Cobalt-molybdenum sulfide composite flame retardant, fireproof coating and preparation methods of cobalt-molybdenum sulfide composite flame retardant and fireproof coating

A composite flame retardant and fire-resistant coating technology, applied in fire-resistant coatings, epoxy resin coatings, coatings, etc., can solve problems such as single structure and poor charring effect, and achieve increased stability, stable structure, and rich cells Effect

Active Publication Date: 2021-11-12
JIANGSU CHAMPION TECHNOLOGY GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] Aiming at the problem that existing flame retardants have a single structure and poor char formation effect, the present invention provides a fireproof coating based on a cobalt-molybdenum sulfide composite flame retardant and their preparation method. The synthesized cobalt-molybdenum sulfide composite flame retardant can It achieves the three-in-one effect of carbon source, gas source and acid source, and has a larger specific surface area and excellent catalytic carbonization effect, which improves the flame retardant efficiency

Method used

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  • Cobalt-molybdenum sulfide composite flame retardant, fireproof coating and preparation methods of cobalt-molybdenum sulfide composite flame retardant and fireproof coating
  • Cobalt-molybdenum sulfide composite flame retardant, fireproof coating and preparation methods of cobalt-molybdenum sulfide composite flame retardant and fireproof coating
  • Cobalt-molybdenum sulfide composite flame retardant, fireproof coating and preparation methods of cobalt-molybdenum sulfide composite flame retardant and fireproof coating

Examples

Experimental program
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Effect test

Embodiment 1

[0053] A fireproof coating based on a cobalt-molybdenum sulfide composite flame retardant, comprising the following components in parts by mass: 80 parts of epoxy resin, 2 parts of cobalt-molybdenum sulfide composite flame retardant, 10 parts of other flame retardant A, other 10 parts of flame retardant B, 2 parts of glass fiber, 10 parts of dispersant, 2 parts of titanium dioxide.

[0054] The other flame retardant A includes ammonium polyphosphate, melamine, and melamine pyrophosphate, wherein, 2 parts of ammonium polyphosphate, 2 parts of melamine, and 6 parts of melamine pyrophosphate.

[0055] The other flame retardant B includes quaternary dipentaerythritol hexahydroxystearate.

[0056] The preparation method of described cobalt-molybdenum sulfide composite flame retardant comprises the following steps:

[0057] a. Add 0.1mmol of cobalt nitrate hexahydrate and 0.05mmol of 2,5-dihydroxy-1,4-terephthalic acid to a solution containing 4mL of N,N-dimethylformamide, 3mL of e...

Embodiment 2

[0067] A fireproof coating based on cobalt-molybdenum sulfide composite flame retardant, comprising the following components in parts by mass: 90 parts of epoxy resin, 6 parts of cobalt-molybdenum sulfide composite flame retardant, 8 parts of other flame retardant A, other 15 parts of flame retardant B, 6 parts of glass fiber, 10 parts of dispersant, 5 parts of titanium dioxide.

[0068] The other flame retardant A includes melamine cyanurate.

[0069] The other flame retardant B includes pentaerythritol and poly-dipentaerythritol hexaacrylate, wherein 4 parts of pentaerythritol and 4 parts of poly-dipentaerythritol hexaacrylate.

[0070] The preparation method of described cobalt-molybdenum sulfide composite flame retardant comprises the following steps:

[0071] a. Add 0.13mmol of cobalt nitrate hexahydrate and 0.06mmol of 2,5-dihydroxy-1,4-terephthalic acid to a solution containing 5mL of N,N-dimethylformamide, 5mL of ethanol and 5mL of deionized water in the mixed solven...

Embodiment 3

[0081] A fireproof coating based on a cobalt-molybdenum sulfide composite flame retardant, comprising the following components in parts by mass: 120 parts of epoxy resin, 8 parts of cobalt-molybdenum sulfide composite flame retardant, 13 parts of other flame retardants A, other flame retardants Fuel B 14 parts, glass fiber 5 parts, dispersant 14 parts, titanium dioxide 8 parts.

[0082] The other flame retardants A include ammonium polyphosphate, melamine, melamine pyrophosphate and melamine polyphosphate, wherein 5 parts of ammonium phosphate, 5 parts of melamine, 1 part of melamine pyrophosphate and 2 parts of melamine polyphosphate.

[0083] The other flame retardant B includes pentaerythritol, poly-dipentaerythritol hexaacrylate and poly-dipentaerythritol pentaacrylate, wherein, 4 parts of pentaerythritol, 4 parts of poly-dipentaerythritol hexaacrylate, and 6 parts of poly-dipentaerythritol pentaacrylate.

[0084] The preparation method of described cobalt-molybdenum sulfi...

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PUM

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Abstract

The invention discloses a cobalt-molybdenum sulfide composite flame retardant, a fireproof coating and preparation methods of the cobalt-molybdenum sulfide composite flame retardant and the fireproof coating, and belongs to the technical field of fireproof coatings. The cobalt-molybdenum sulfide composite flame retardant comprises Co-MOF and MoS2, the MoS2 is embedded in holes and combined with open positions of Co2+ ions to form a CoMoS phase, and a molybdenum sulfide modified organic framework material synthesized on the basis of the Co-MOF by the flame retardant has a larger specific surface area and a larger catalytic effect, has more active sites, can be used for preparing a high-performance flame retardant, and facilitates the combination with oxygen to form a complete combustion product.

Description

technical field [0001] The invention belongs to the technical field of fireproof coatings, and more specifically relates to a cobalt-molybdenum sulfide composite flame retardant, fireproof coatings and their preparation methods. Background technique [0002] Although steel is non-combustible, it has the characteristics of heat resistance and high temperature resistance, and it is easy to conduct heat. Heating of steel structures can cause harm in the following two aspects: on the one hand, due to the high thermal expansion coefficient of steel, it is easy to cause deformation of the structure or elongation of components at high temperature, and it is easy to cause bending of components when the two sides of the steel are heated unevenly; on the other hand, The mechanical properties of steel, such as: yield stress, elastic modulus, etc., gradually decrease with the increase of temperature. When the critical temperature (540°C) is reached, the steel structure will lose its su...

Claims

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Application Information

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IPC IPC(8): C09D5/18C09D163/00
CPCC09D5/18C09D163/00C08K2003/3009C08K2003/323C08L2201/02C08L87/00C08K9/12C08K3/30C08K3/32C08K5/34922C08K5/34928C08K5/103
Inventor 谢海程家骥唐帆
Owner JIANGSU CHAMPION TECHNOLOGY GROUP CO LTD
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