Efficient energy-saving biodiesel catalyst and preparation method thereof
A biodiesel, high-efficiency and energy-saving technology, used in physical/chemical process catalysts, chemical instruments and methods, organic compound/hydride/coordination complex catalysts, etc. Green chemistry, easy to produce saponification and other problems, to achieve the effect of low production cost, easy separation and convenient processing
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Embodiment 1
[0024] Weigh 40 parts of methanesulfonic acid, 10 parts of chlorosulfonic acid, 4 parts of modified alumina, 5 parts of glycerol, 15 parts of fatty sulfonic acid, 12 parts of phosphoric acid monoester, 3 parts of tin tetrachloride, 12 parts of polyether acid phosphate, 4 parts of propargyl alcohol, the preparation method of the modified alumina is as follows: the alumina and deionized water are mixed and stirred evenly, and then dried at 120 ° C for 12 hours; Mix the aluminum oxide with ethanol and stir evenly, dry at 120°C for 12 hours, and then treat it at 250°C for 2 hours, mix the alumina, additives, and deionized water obtained above, stir evenly, and then directly filter, separate and dry ; The above-mentioned obtained material was roasted at 450° C. for 3 hours under an argon atmosphere, and then modified alumina was obtained, and the mass ratio of the alumina to deionized water was 1:6. The preparation of the modified alumina In the method, ethanol is absolute ethanol,...
Embodiment 2
[0026] Weigh in turn 42 parts of methanesulfonic acid, 12 parts of chlorosulfonic acid, 5 parts of modified alumina, 6 parts of glycerol, 17 parts of fat sulfonic acid, 13 parts of phosphoric acid monoester, 4 parts of tin tetrachloride, 13 parts of polyether acid phosphate and 5 parts of propargyl alcohol. The preparation method of the modified alumina is as follows: mix the alumina with deionized water and stir evenly, then dry at 130°C for 13 hours; Mix the aluminum oxide with ethanol and stir evenly, dry at 130°C for 13 hours, then treat at 260°C for 3 hours, mix the alumina, additives, and deionized water obtained above, stir evenly, and then directly filter, separate and dry ; The above-mentioned obtained material was roasted at 460° C. for 4 hours under an argon atmosphere, and then modified alumina was obtained, and the mass ratio of the alumina to deionized water was 2:7. The preparation of the modified alumina In the method, ethanol is absolute ethanol, and the mass ...
Embodiment 5
[0032] Weigh 42 parts of methanesulfonic acid, 12 parts of chlorosulfonic acid, 6 parts of modified alumina, 8 parts of glycerol, 17 parts of fat sulfonic acid, 14 parts of phosphoric acid monoester, 3 parts of tin tetrachloride, 13 parts of polyether acid phosphate and 7 parts of propargyl alcohol. The preparation method of the modified alumina is as follows: mix the alumina with deionized water and stir evenly, then dry at 130°C for 15 hours; Mix the aluminum oxide with ethanol and stir evenly, dry at 130°C for 15 hours, and then treat it at 250°C for 2 hours, mix the alumina, additives, and deionized water obtained above, stir evenly, and then directly filter, separate and dry ; The above-mentioned obtained material was roasted at 490° C. for 3 hours under an argon atmosphere, and then modified alumina was obtained, and the mass ratio of the alumina to deionized water was 2:9. The preparation of the modified alumina In the method, ethanol is absolute ethanol, and the mass r...
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