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Efficient energy-saving biodiesel catalyst and preparation method thereof

A biodiesel, high-efficiency and energy-saving technology, used in physical/chemical process catalysts, chemical instruments and methods, organic compound/hydride/coordination complex catalysts, etc. Green chemistry, easy to produce saponification and other problems, to achieve the effect of low production cost, easy separation and convenient processing

Inactive Publication Date: 2021-06-04
郝一男
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Biodiesel is an environmentally friendly green fuel, but the biodiesel preparation process uses an unfriendly catalyst, which itself is not in line with the design of green chemistry, especially after the reaction, the product must be neutralized and washed with water. It is easy to produce saponification phenomenon, and discharge a large amount of waste acid and waste lye to pollute the environment, which makes post-processing troublesome. However, in the process of preparing biodiesel, the excessive use of traditional catalysts with strong acid and strong alkali will still cause serious pollution to the environment. , the emergence of these phenomena seriously violated our original design of biodiesel

Method used

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  • Efficient energy-saving biodiesel catalyst and preparation method thereof
  • Efficient energy-saving biodiesel catalyst and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Weigh 40 parts of methanesulfonic acid, 10 parts of chlorosulfonic acid, 4 parts of modified alumina, 5 parts of glycerol, 15 parts of fatty sulfonic acid, 12 parts of phosphoric acid monoester, 3 parts of tin tetrachloride, 12 parts of polyether acid phosphate, 4 parts of propargyl alcohol, the preparation method of the modified alumina is as follows: the alumina and deionized water are mixed and stirred evenly, and then dried at 120 ° C for 12 hours; Mix the aluminum oxide with ethanol and stir evenly, dry at 120°C for 12 hours, and then treat it at 250°C for 2 hours, mix the alumina, additives, and deionized water obtained above, stir evenly, and then directly filter, separate and dry ; The above-mentioned obtained material was roasted at 450° C. for 3 hours under an argon atmosphere, and then modified alumina was obtained, and the mass ratio of the alumina to deionized water was 1:6. The preparation of the modified alumina In the method, ethanol is absolute ethanol,...

Embodiment 2

[0026] Weigh in turn 42 parts of methanesulfonic acid, 12 parts of chlorosulfonic acid, 5 parts of modified alumina, 6 parts of glycerol, 17 parts of fat sulfonic acid, 13 parts of phosphoric acid monoester, 4 parts of tin tetrachloride, 13 parts of polyether acid phosphate and 5 parts of propargyl alcohol. The preparation method of the modified alumina is as follows: mix the alumina with deionized water and stir evenly, then dry at 130°C for 13 hours; Mix the aluminum oxide with ethanol and stir evenly, dry at 130°C for 13 hours, then treat at 260°C for 3 hours, mix the alumina, additives, and deionized water obtained above, stir evenly, and then directly filter, separate and dry ; The above-mentioned obtained material was roasted at 460° C. for 4 hours under an argon atmosphere, and then modified alumina was obtained, and the mass ratio of the alumina to deionized water was 2:7. The preparation of the modified alumina In the method, ethanol is absolute ethanol, and the mass ...

Embodiment 5

[0032] Weigh 42 parts of methanesulfonic acid, 12 parts of chlorosulfonic acid, 6 parts of modified alumina, 8 parts of glycerol, 17 parts of fat sulfonic acid, 14 parts of phosphoric acid monoester, 3 parts of tin tetrachloride, 13 parts of polyether acid phosphate and 7 parts of propargyl alcohol. The preparation method of the modified alumina is as follows: mix the alumina with deionized water and stir evenly, then dry at 130°C for 15 hours; Mix the aluminum oxide with ethanol and stir evenly, dry at 130°C for 15 hours, and then treat it at 250°C for 2 hours, mix the alumina, additives, and deionized water obtained above, stir evenly, and then directly filter, separate and dry ; The above-mentioned obtained material was roasted at 490° C. for 3 hours under an argon atmosphere, and then modified alumina was obtained, and the mass ratio of the alumina to deionized water was 2:9. The preparation of the modified alumina In the method, ethanol is absolute ethanol, and the mass r...

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Abstract

The invention discloses an efficient energy-saving biodiesel catalyst and a preparation method thereof, and relates to the technical field of catalysts. The catalyst is prepared from the following raw materials: methanesulfonic acid, chlorosulfonic acid, modified aluminum oxide, glycerol, fatty sulfonic acid, phosphoric acid monoester, stannic chloride, polyether acid type phosphate and propargyl alcohol. Aluminum oxide is modified, the aluminum oxide is modified mainly by utilizing an auxiliary agent, and the auxiliary agent can accurately and highly selectively react with an alkaline site of the aluminum oxide; therefore, the alkalinity of the aluminum oxide is reduced; the catalyst does not perform physical or chemical action with other active sites of the alumina, so the crystal structure, pore structure and other physical and chemical properties of the alumina are not changed, only the alkali property can be adjusted, other characteristics of the alumina are not changed basically, and the application stability of the alkali in a catalyst is effectively improved; the environment is not polluted, the corrosion and saponification phenomena are avoided, the synthesis process is simple, and the production cost is low.

Description

technical field [0001] The invention relates to the technical field of catalysts, in particular to a high-efficiency and energy-saving biodiesel catalyst and a preparation method thereof. Background technique [0002] With the rapid development of the global economy, the sharp reduction of oil reserves while the demand for energy continues to grow, and the environmental pollution caused by the combustion of fossil fuels is becoming more and more serious. Therefore, the development of new green renewable fuel resources has become the most important It is an issue of widespread concern and a hot topic in the research of new energy production technology. Biodiesel is a kind of biomass energy, which has the advantages of biodegradability, complete combustion, and less harmful substance emissions. It is currently the only renewable and clean fuel that can replace petrochemical diesel in the world. It is known as "green gold". Due to its advantages of simple degradation, no emiss...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J31/06B01J31/26C10G3/00
CPCB01J31/06B01J31/26C10G3/00Y02P30/20Y02E50/10
Inventor 郝一男王喜明丁立军薛振华
Owner 郝一男
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