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A method for preparing silver oxide-doped manganese oxide nanowire network based on electrospinning and its application in catalytic decomposition of formaldehyde

A manganese oxide nanometer and electrospinning technology, which is applied in the field of nanomaterial manufacturing, can solve the problems of inconspicuous catalytic effect and low long diameter of formaldehyde, and achieve the effects of improved catalytic effect, simple equipment, and safe and convenient connection process

Active Publication Date: 2022-01-25
HARBIN INST OF TECH
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Problems solved by technology

The manganese oxide nanowire network obtained by pure electrospinning method often has a low long-diameter ratio, resulting in insignificant catalytic effect on formaldehyde. However, how to improve the catalytic effect of manganese oxide on formaldehyde has become the focus of research by researchers in this field.

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  • A method for preparing silver oxide-doped manganese oxide nanowire network based on electrospinning and its application in catalytic decomposition of formaldehyde
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  • A method for preparing silver oxide-doped manganese oxide nanowire network based on electrospinning and its application in catalytic decomposition of formaldehyde

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Embodiment Construction

[0025] The technical solution of the present invention will be further described below in conjunction with the accompanying drawings, but it is not limited thereto. Any modification or equivalent replacement of the technical solution of the present invention without departing from the spirit and scope of the technical solution of the present invention should be covered by the present invention. within the scope of protection.

[0026] The present invention provides a method for preparing silver oxide-doped manganese oxide nanowire network based on electrospinning. The method uses polyvinyl alcohol (Polyvinyl Alcohol, PVA) solution and Mn(CH 3 COO) 2 Solution configuration electrospinning precursor solution, and then after high temperature calcination and KMnO 4 solution soaking, and finally silver nanowires are dispersed in manganese oxide nanowires, and doping is achieved by oxygen plasma treatment. The specific implementation steps are as follows:

[0027] (1) Spinning so...

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Abstract

The invention discloses a method for preparing silver oxide-doped manganese oxide nanowire network based on electrospinning and its application in catalytic decomposition of formaldehyde. The method comprises the following steps: Step 1: Mn(CH 3 COO) 2 The solution is added to the PVA solution at room temperature, and magnetically stirred at room temperature to obtain an electrospinning precursor solution; Step 2: Use the electrospinning precursor solution to push the syringe piston through a syringe pump to perform electrospinning; Step 3: Spinning The finished samples are first placed in high-temperature air for high-temperature calcination, and then KMnO 4 Soak the nanowire network obtained by solution immersion method; step 4: drop the silver nanowire dispersion liquid on the nanowire network, then dry it, and use oxygen plasma to treat the sample after the silver nanowire is dropped, and then realize the silver oxide nanowire network. line doping. The invention requires simple equipment, safe and convenient connection process, short preparation period, realizes the doping of silver oxide, and improves the catalytic effect.

Description

technical field [0001] The invention belongs to the field of nanomaterial manufacturing, and relates to a method for preparing silver oxide-doped manganese oxide nanowire network based on electrospinning and its application in catalytic decomposition of formaldehyde. Background technique [0002] The problem of indoor air pollution caused by formaldehyde is becoming more and more serious, and how to efficiently remove formaldehyde has become a major research hotspot. Nowadays, a series of studies on catalytic degradation of formaldehyde have been carried out in the world, mainly including two categories: recovery method and decomposition and purification method. Among them, the recovery method separates formaldehyde from the gas to obtain a higher concentration of formaldehyde, which is then used in industrial production, but the cost of the recovery method is high and it is easy to cause secondary pollution during the treatment process. The decomposition and purification m...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/68B01J35/10B01D53/86B01D53/72
CPCB01J23/688B01J35/1004B01D53/8668
Inventor 王晨曦方慧厉道远黄博妍周诗承田艳红
Owner HARBIN INST OF TECH
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