PVC glove with strong ductility and preparation method thereof

A technology of ductility and gloves, which is applied in the direction of gloves, protective clothing, coatings, etc., can solve the problems of limited market share, poor scalability, and affecting operations, etc., and achieve the effects of facilitating heat transfer, fast polymerization rate, and convenient pipeline transportation

Inactive Publication Date: 2021-01-15
安徽和佳医疗用品科技有限公司
View PDF4 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, latex gloves, nitrile gloves, and PVC gloves are stable in quality, good in protection, and have a wide range of applications, occupying most of the market share; although PE gloves are cheap, they have disadvantages such as poor stretchability, easy damage, and affect operation after wearing. It is a low-end product, mainly used in the catering field, with a limited market share, and it is difficult to develop into a mainstream product of disposable gloves

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • PVC glove with strong ductility and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A preparation method of PVC gloves with strong ductility;

[0029] Step 1. Add 0.1g of sodium lauryl sulfate into 80g of water and stir to dissolve evenly, then add 100g of VCM and mix evenly, add 0.1g of oxidation-reduction initiator and mix evenly, adjust the pH value to 9, and react for polymerization at 45°C After 5 hours, the reaction resulted in a white emulsion, which was then spray-dried to obtain a white powder.

[0030] Step 2, 100g of PVC paste resin, 30g of acetyl citrate, 0.5g of calcium zinc stabilizer, 15g of D70, 5g of sodium carbonate aqueous solution and 0.5g of isopropyl triisostearyl titanate were mixed at 50°C Mix for 2 hours, after the slurry is obtained, vacuum defoaming at 25°C, the time of vacuum defoaming is 4 hours, and the pressure value of vacuum defoaming is -0.01MPa;

[0031] Step 3, dipping the glove model in the slurry at 70°C for 6 seconds, baking and plasticizing it under a nitrogen atmosphere at 220°C for 5 minutes, to obtain gloves ...

Embodiment 2

[0034] A preparation method of PVC gloves with strong ductility;

[0035] Step 1. Add 10g of emulsifier sodium lauryl sulfate into 104g of water and stir to dissolve evenly, then add 130g of VCM and mix evenly, add 3g of oxidation-reduction initiator calcium peroxide and 1-aminobutanol, mix evenly, and adjust the pH The value was 9, and the reaction polymerization was carried out at 45° C. for 5 hours to obtain a white emulsion, which was then spray-dried to obtain a white powder.

[0036] Step 2. Blend 100g of PVC paste resin, 40g of acetyl citrate, 1g of calcium zinc stabilizer, 20g of D70, 5g of sodium carbonate aqueous solution and 1g of isopropyl triisostearyl titanate at 50°C for 2h , after obtaining the slurry, vacuum defoaming at 25°C, the time of vacuum defoaming is 4h, and the pressure value of vacuum defoaming is -0.01MPa;

[0037] Step 3, dipping the glove model in the slurry at 70°C for 6 seconds, baking and plasticizing for 5 minutes under a nitrogen atmosphere ...

Embodiment 3

[0040] A preparation method of PVC gloves with strong ductility;

[0041] Step 1. Add 0.5g of emulsifier sodium lauryl sulfate into 80g of water and stir to dissolve evenly, then add 100g of VCM and mix evenly, then add 0.5g of oxidation-reduction initiator calcium peroxide and 1-aminobutanol and mix evenly. Adjust the pH value to 9, react and polymerize at 45° C. for 5 hours to obtain a white emulsion, which is further spray-dried to obtain a white powder.

[0042] Step 2. Blend 100g of PVC paste resin, 40g of acetyl citrate, 1g of calcium zinc stabilizer, 20g of D70, 5g of sodium carbonate aqueous solution and 1g of isopropyl triisostearyl titanate at 50°C for 2h , after obtaining the slurry, vacuum defoaming at 25°C, the time of vacuum defoaming is 4h, and the pressure value of vacuum defoaming is -0.01MPa;

[0043] Step 3, dipping the glove model in the slurry at 70°C for 6 seconds, baking and plasticizing for 5 minutes under a nitrogen atmosphere at 180-220°C, to obtain ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a PVC glove with strong ductility and a preparation method thereof. The PVC glove is prepared by taking high-dispersity powder PVC paste resin as a raw material, when the PVC paste resin is prepared, induced decomposition of a water-soluble redox initiator is adopted, and the initiator not only contains amino and hydroxyl, but also can directly introduce a ductile group forimproving the material on the premise of not specially treating the material; calcium peroxide serving as a reducing agent reacts with sodium carbonate to generate calcium carbonate serving as a filling agent in a blending system, so that the cost can be saved, the tensile property of PVC resin is further changed, an environment-friendly plasticizer without benzene rings is adopted, environmentalpollution is reduced, the plasticizer serving as a raw material for preparing the glove is cost-saving and environment-friendly, and the PVC glove with strong ductility can prolong the service life of the glove and meet the use requirements of high-requirement industries.

Description

technical field [0001] The invention belongs to the field of plastic glove production, in particular to a PVC glove with strong ductility and a preparation method thereof. Background technique [0002] Disposable PVC gloves are an emerging industry and have gradually entered the public's field of vision in recent years. Disposable gloves mainly include latex gloves, nitrile gloves, PVC gloves and PE gloves. Among them, latex gloves, nitrile gloves, and PVC gloves are stable in quality, good in protection, and have a wide range of applications, occupying most of the market share; although PE gloves are cheap, they have disadvantages such as poor scalability, easy damage, and affect operation after wearing. It is a low-end product, mainly used in the catering field, with a limited market share, and it is difficult to develop into a mainstream product of disposable gloves. Compared with nitrile gloves, PVC gloves have more prominent cost advantages, and are comfortable to wea...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08J5/02C08J7/04A41D19/015C08F114/06C08F4/40C08L27/06C08K3/26
CPCC08J5/02C08J7/04A41D19/0058C08F114/06C08F4/40C08J2327/06C08J2475/04C08K3/26
Inventor 张伯侯马万青张天柱董松
Owner 安徽和佳医疗用品科技有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap