A preparation method of temperature-sensitive flow pattern regulator for deepwater water-based drilling fluid

A flow regulator, deep-water water-based technology, applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of poor temperature response, low-temperature viscosity increase, poor temperature resistance, etc., and achieve hydrophobic association Strong effect, improved high temperature resistance, strong hydrophobic association effect

Active Publication Date: 2021-07-23
CHINA UNIV OF PETROLEUM (EAST CHINA)
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Problems solved by technology

For example: Chinese patent document CN109054782A provides a temperature-sensitive polymer rheology regulator, the temperature-sensitive polymer rheology regulator is made of alkenyl amide and alkenyl sulfonic acid as reactants, after the pH value is adjusted to 7.0 , a copolymer initiated by an initiator at 55°C; the alkenylamide is selected from acrylamide, N,N-dimethylacrylamide, N,N-diethylacrylamide, N,N-dimethacrylamide Methylbisacrylamide, vinylcaprolactam and N-isopropylacrylamide; the alkenylsulfonic acid is selected from vinylsulfonic acid, vinylbenzenesulfonic acid, 2-acrylamido dodecylsulfonic acid and 2-methyl-2-acrylamidopropanesulfonic acid, but the above temperature-sensitive polymer rheology modifier has a temperature resistance of 130°C, which is difficult to meet higher temperature resistance requirements
[0005] The existing conventional deepwater water-based drilling fluid flow pattern regulators have the following disadvantages: (1) The temperature response effect is poor, the flow pattern regulation effect of the drilling fluid in the low temperature range is insufficient, and the viscosity increase is serious at low temperature; (2) The performance is affected by external conditions Seriously, the performance is unstable under different salt concentrations and pH; (3) The temperature resistance is insufficient and cannot adapt to the downhole high temperature formation environment
[0006] Therefore, there is an urgent need to develop a temperature-sensitive flow pattern regulator for deepwater water-based drilling fluids, so as to overcome the shortcomings of existing flow pattern regulators, such as poor temperature response, performance that is seriously affected by external conditions, and poor temperature resistance.

Method used

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  • A preparation method of temperature-sensitive flow pattern regulator for deepwater water-based drilling fluid
  • A preparation method of temperature-sensitive flow pattern regulator for deepwater water-based drilling fluid
  • A preparation method of temperature-sensitive flow pattern regulator for deepwater water-based drilling fluid

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Embodiment 1

[0045] A method for preparing a temperature-sensitive flow pattern regulator for deepwater water-based drilling fluids, comprising the following steps:

[0046] (1) Add 20 g of N-isopropylacrylamide, 4 g of acrylic acid, 2 g of caprolactam, and 2 g of acrylamide into 200 mL of deionized water, mix well, and then use a sodium hydroxide solution with a mass concentration of 30 wt % to adjust the pH of the system to 7.0, to obtain a mixture.

[0047] (2) Add 5 g of butyl acrylate, 5 g of lauryl acrylate, 8 g of 2-acrylamido-2-methylpropanesulfonic acid, and 2 g of emulsifier MS-1 to the mixed solution obtained in step (1), mix well, and use Shear emulsification machine emulsification, rotation speed 3000r / min, emulsification time 20min, to obtain the pre-emulsion.

[0048] (3) Place the pre-emulsion obtained in step (2) in a three-necked flask, heat it to 60°C, add 4 mL of 0.05 g / mL potassium persulfate aqueous solution dropwise under stirring, and add 8 mL of 0.05 g / mL potassiu...

Embodiment 2

[0050] A method for preparing a temperature-sensitive flow pattern regulator for deepwater water-based drilling fluids, comprising the following steps:

[0051] (1) Add 20g of N-vinylpyrrolidone, 4g of methacrylic acid, 2g of caprolactam, 1g of acrylamide, and 1g of N-methylolacrylamide into 200mL of deionized water, mix well, and then oxidize The sodium solution adjusted the pH of the system to 7.0 to obtain a mixed solution.

[0052] (2) Add 5g of lauryl acrylate, 5g of stearyl acrylate, 8g of styrene, and 2g of emulsifier MS-1 to the mixed solution obtained in step (1), mix well, and emulsify with a shear emulsifier at a speed of 3000r / min , and the emulsification time was 20min to obtain a pre-emulsion.

[0053] (3) Place the pre-emulsion obtained in step (2) in a three-necked flask, heat it to 60°C, add 4 mL of 0.05 g / mL potassium persulfate aqueous solution dropwise under stirring, and add 8 mL of 0.05 g / mL potassium persulfate solution dropwise after stirring for 10 mi...

Embodiment 3

[0055] A method for preparing a temperature-sensitive flow pattern regulator for deepwater water-based drilling fluids, comprising the following steps:

[0056] (1) Add 10g of N-isopropylacrylamide, 10g of N-vinylcaprolactam, 2g of acrylic acid, 2g of methacrylic acid, and 4g of N-methylolacrylamide into 200mL of deionized water, mix well, and then use a mass concentration of The pH of the system was adjusted to 7.0 with 30 wt% sodium hydroxide solution to obtain a mixed solution.

[0057] (2) Add 6 g of octadecyl acrylate, 4 g of methyl methacrylate, 4 g of sodium styrene sulfonate, 4 g of sodium 4-hydroxybenzene sulfonate, 2 g of emulsifier MS-1 into the mixed solution obtained in step (1), and mix Evenly, use a shear emulsifier to emulsify with a rotation speed of 3000r / min and an emulsification time of 20min to obtain a pre-emulsion.

[0058] (3) Place the pre-emulsion obtained in step (2) in a three-necked flask, heat it to 60°C, add 4 mL of 0.05 g / mL potassium persulfat...

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Abstract

The invention provides a method for preparing a temperature-sensitive flow pattern regulator for deepwater water-based drilling fluid, comprising the steps of: adding temperature-sensitive monomers, acrylic monomers, and amide monomers into deionized water, mixing evenly, Then adjust the pH of the system to 6.0-8.0 to obtain a mixed solution; add acrylate monomers, temperature-resistant monomers, and emulsifiers to the mixed solution, mix evenly, and then shear and emulsify to obtain a pre-emulsion; heat the obtained pre-emulsion To 55‑65°C, add the aqueous solution of the initiator drop by drop under the condition of stirring, and then add the aqueous solution of the crosslinking agent drop by drop to carry out the reaction; after filtering, washing, drying and pulverizing, it is obtained. The flow pattern regulator of the invention has good temperature response effect, can effectively adjust the low-temperature rheology of drilling fluid, meets the flow pattern regulation requirements in a large temperature span range, and has certain high temperature resistance.

Description

technical field [0001] The invention relates to a preparation method of a temperature-sensitive flow pattern regulator for deep-water water-based drilling fluid, belonging to the field of oilfield chemistry in the petroleum industry. Background technique [0002] With the continuous increase of domestic demand for oil and gas resources, the smooth exploitation of oil and gas resources in deep ocean areas has become an important guarantee for the sustainable development of my country's oil industry. my country's South China Sea oil and gas geological reserves are extremely rich, with about 24 billion tons of oil resources and about 1.4×10 natural gas hydrate resources. 5 It is one of the world's four major marine oil and gas enrichment areas, 70% of which are stored in deep water areas. Therefore, the efficient drilling and exploitation of deepwater oil and gas resources is an important guarantee for the sustainable development of my country's petroleum industry. [0003] H...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F220/54C08F220/06C08F220/56C08F220/18C08F220/60C08F222/38C08F226/10C08F220/58C08F212/08C08F226/06C08F220/14C08F212/14C09K8/035
CPCC08F220/54C08F226/10C09K8/035C08F220/06C08F220/56C08F220/1804C08F220/1812C08F220/606C08F222/385C08F220/58C08F220/1818C08F212/08C08F226/06C08F220/14C08F212/30
Inventor 吕开河王中义黄贤斌孙金声王金堂刘敬平白英睿金家锋
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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