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Flame-retardant anti-poison high-temperature-resistant polypropylene co-extrusion film and preparation method thereof

A technology of co-extruded film and polypropylene, applied in the field of polypropylene film, can solve the problem that polypropylene cannot take into account flame retardancy, anti-virus, high temperature resistance and flexibility at the same time, and the excellent performance of polypropylene film cannot be exerted, affecting the appearance of equipment and reliable use. It can achieve good hand feel and physical and mechanical properties, improve product value and market potential, and achieve excellent heat aging resistance.

Active Publication Date: 2020-07-14
北京邦维高科新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the usability requirements of protective equipment, the film needs to be soft. Usually, the method of adding toughening resin to the resin formula reduces the hardness of polypropylene and improves toughness, but the potential harm is that the temperature resistance of polypropylene film is significantly reduced. Performance, especially if it is placed continuously in a high temperature environment, the surface of the polypropylene film will appear discoloration, stickiness, and brittleness, which will affect the appearance and reliability of the equipment
[0006] Therefore, when polypropylene is used as a barrier film in protective equipment, polypropylene cannot take into account flame retardancy, anti-virus, high temperature resistance and flexibility at the same time, resulting in the failure of the excellent performance of polypropylene film, which limits its application range

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The thickness of the outer layer of the co-extrusion film is 25um, the thickness of the adhesive layer is 5um, the thickness of the middle layer is 10um, and the thickness of the inner layer is 25um.

[0033] The raw material formula of the outer layer is composed of 100 parts by weight of polyolefin resin, 13 parts by weight of a mixture of decabromodiphenyl ether and antimony oxide, and 5 parts by weight of color masterbatch. Wherein: the polyolefin resin is composed of 100 parts by weight of polypropylene homopolymer resin and 60 parts by weight of polyolefin plastomer.

[0034] The raw material formula of the adhesive layer is maleic anhydride modified polypropylene polymer.

[0035] The raw material formula of the middle layer is polyvinylidene chloride.

[0036] The raw material formula of the inner layer is composed of 100 parts by weight of toughening resin, 13 parts by weight of a mixture of decabromodiphenyl ether and antimony oxide, and 5 parts by weight of ...

Embodiment 2

[0045] The thickness of the outer layer of the co-extrusion film is 60um, the thickness of the adhesive layer is 5um, the thickness of the middle layer is 10um, and the thickness of the inner layer is 60um.

[0046] The raw material formula of the outer layer is composed of 100 parts by weight of polyolefin resin, 22 parts by weight of intumescent flame retardant and 7 parts by weight of color masterbatch. Wherein: the polyolefin resin is composed of 100 parts by weight of polypropylene homopolymer resin and 300 parts by weight of polypropylene copolymer resin.

[0047] The raw material formula of the adhesive layer is ethylene-vinyl acetate copolymer.

[0048] The raw material formula of the middle layer is ethylene-vinyl alcohol copolymer.

[0049] The raw material formula of the inner layer is composed of 100 parts by weight of toughening resin, 22 parts by weight of intumescent flame retardant and 7 parts by weight of color masterbatch. Wherein: the toughening resin is c...

Embodiment 3

[0058] The thickness of the outer layer of the co-extrusion film is 30um, the thickness of the adhesive layer is 13um, the thickness of the middle layer is 30um, and the thickness of the inner layer is 100um.

[0059] The raw material formula of the outer layer is composed of 100 parts by weight of polyolefin resin, 18 parts by weight of phosphate ester flame retardant and 4 parts by weight of color masterbatch. Wherein: the polyolefin resin is composed of 100 parts by weight of polypropylene homopolymer resin and 100 parts by weight of polyolefin elastomer.

[0060] The raw material formula of the adhesive layer is linear low density polyethylene.

[0061] The raw material formula of the middle layer is polyamide.

[0062] The raw material formula of the inner layer is composed of 100 parts by weight of toughening resin, 18 parts by weight of phosphate ester flame retardant and 4 parts by weight of color masterbatch. Wherein: the toughening resin is composed of 20 parts by ...

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PUM

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Abstract

The invention discloses a flame-retardant anti-poison high-temperature-resistant polypropylene co-extrusion film and a preparation method thereof. The co-extrusion film comprises an outer layer, a bonding layer, a middle layer, a bonding layer and an inner layer from outside to inside, the outer layer is made of a blend of polyolefin resin, a flame retardant and color master batch; the bonding layer is made of any one of a maleic anhydride modified polypropylene polymer, an ethylene-methacrylic acid copolymer, linear low-density polyethylene or an ethylene-vinyl acetate copolymer; the middle layer is made of any one of polyvinylidene chloride, ethylene-vinyl alcohol copolymer or polyamide; and the inner layer is made of a blend of toughened resin, a flame retardant and color master batch.According to the method, the five-layer co-extrusion film is prepared from all layers of raw materials through multi-layer co-extrusion compounding equipment by adopting a multi-layer co-extrusion compounding process. The flame-retardant, anti-poison and high-temperature-resistant polypropylene film integrates flame retardance, poison prevention and high-temperature resistance, is excellent in flame retardance, thermal aging resistance, barrier property and tear resistance and soft in hand feeling, and is suitable for the field of protective equipment and biochemical packaging materials.

Description

technical field [0001] The invention relates to a polypropylene film, in particular to a flame-retardant, anti-toxic, high-temperature-resistant polypropylene co-extruded film and a preparation method thereof. Background technique [0002] Polypropylene film is widely used in packaging, chemical, construction, textile and other industries because of its low cost, high barrier, easy molding and stability. In the prior art, functional polypropylene films include flame-retardant polypropylene films, barrier polypropylene films, and low-temperature resistant polypropylene films. [0003] Due to its own structural characteristics, the limiting oxygen index of polypropylene is about 18%. It is a flammable material, and its flame retardancy is generally improved by adding flame retardants and synergists. The existing polypropylene flame retardant technology is mostly used in the fields of automobiles, parts of mechanical equipment, and electrical wires and cables. Polypropylene p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B7/12B32B27/08B32B27/20B32B27/30B32B27/32B32B27/34B32B33/00C08J5/18C08L23/12C08L23/02C08L23/14C08L23/08C08L23/06C08K3/22C08K5/06B29C48/18
CPCB32B27/32B32B7/12B32B27/20B32B27/08B32B27/34B32B27/306B32B27/304B32B33/00B32B37/153C08J5/18B29C48/18C08J2323/12C08J2423/02C08J2323/02C08J2323/14C08J2423/12C08J2323/08C08J2323/06C08K3/2279C08K5/06B32B2250/24B32B2307/3065B32B2307/5825B32B2307/546B32B2307/306
Inventor 张杰陈祯张婷婷任玮韩德孝孙红月肖大君楚鑫鑫
Owner 北京邦维高科新材料科技股份有限公司
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